Designing organic-inorganic hybrid semiconductors for curved x-ray detectors

Author(s):  
Maheshani Prabodhi Alwis Nanayakkara ◽  
Mateus Gallucci Masteghin ◽  
Laura Basiricò ◽  
Ilaria Fratelli ◽  
Andrea Ciavatti ◽  
...  
2021 ◽  
Vol 9 (12) ◽  
pp. 4338-4343
Author(s):  
Hong-Yi Shen ◽  
Lei He ◽  
Ping-Ping Shi ◽  
Qiong Ye

Two organic–inorganic hybrid materials exhibit functional regulation by introducing homochiral cations and different reagent ratios.


2015 ◽  
Vol 1105 ◽  
pp. 335-338
Author(s):  
Qiong Wu ◽  
Jing Lu ◽  
Xiao Lin Ji ◽  
Tao Yu Zou ◽  
Zhen Fang Qiao ◽  
...  

Modifying polyoxometalates with organic and/or metal-organic moieties is a widely adopted method for broading the range of properties. In this work a new polyoxometalate constructed from Anderson-type polyoxoanions and L-arginine (Arg =L-arginine) molecules Na [CrMo6(OH)6O18]}(H2Arg)2·8H2O(1) has been synthesized via conventional method and characterized by routine techniques. Single-crystal X-Ray diffraction analysis shows that compound 1 is constructed by chiralL-arginine grafted Anderson-type clusters, sodium cation and water molecules which are further stabilized by hydrogen bonding interactions constitute 3D supramolecular networks. In addition, both antitumor behavior and photocatalytic activities of compound 1 were investigated.


2018 ◽  
Vol 24 (69) ◽  
pp. 18419-18423 ◽  
Author(s):  
Chia‐Shuo Hsu ◽  
Marek K. Węcławski ◽  
Beata Koszarna ◽  
Daniel T. Gryko ◽  
Hao Ming Chen

2021 ◽  
pp. 1-10
Author(s):  
Xiao-Yu Guo ◽  
Xiao-Jia Wang ◽  
Zhe Liu ◽  
Yue-Yan Liu ◽  
Jie Liu ◽  
...  

In this paper, two novel organic-inorganic hybrid supramolecule compounds {[Cu·L1’·H2O]·(α-Mo8O26)0.5}n 1 and compound {[Cu·L2’·H2O]·(α-Mo8O26)0.5}n 2 have been synthesized [L1’ = 1, 3-bis (4-carboxylpyridine) propane dibromide, L2’ = 1, 4-bis (4-carboxylpyridine) butane dibromide]. Compounds 1 and 2 have been expressly confirmed by PXRD, IR, X-ray single crystal diffraction and TG. Last, the study found that compounds 1 and 2 have obvious adsorption effects on MB and RhB organic dyes, and compound 2 has high adsorption capacity for MB.


2021 ◽  
Author(s):  
Ying Lu ◽  
Tong Zhang ◽  
Yue-Xian Zhang ◽  
Xiao-Jing Sang ◽  
Fang Su ◽  
...  

A new polyoxometalate (POM)-based organic-inorganic hybrid Cu-coordination polymer, namely {((Cu(bipy))2(μ-PhPO3)2Cu(bipy))2H(PCuW11O39)∙3H2O}n (denoted as compound 1, bipy = 2,2'-bipyridine, PhPO3 = phenylphosphonate), was self-assembled hydrothermally. Single-crystal X-ray diffraction (SC-XRD) analysis shows that...


Sensors ◽  
2020 ◽  
Vol 20 (23) ◽  
pp. 6872
Author(s):  
Hailiang Liu ◽  
Jehoon Lee ◽  
Jungwon Kang

In this study, we investigated the characteristics of an organic-inorganic hybrid indirect-type X-ray detector with a CH3NH3PbI3 (MAPbI3) perovskite active layer. A layer with a thickness of 192 nm annealed at 100 °C showed higher absorption, higher crystallinity, and lower surface roughness than did perovskite layers made under different conditions. In the indirect X-ray detector, a scintillator coupled with the detector to convert X-ray photons to visible photons, and the converted photons were absorbed by the active layer to generate charge carriers. The detector with the optimized MAPbI3 (192 nm thick and 100 °C annealing condition) active layer was coupled with a CsI(Tl) scintillator which consisted of 400 μm thick CsI and 0.5 mm thick Al, and achieved the highest sensitivity, i.e., 2.84 mA/Gy·cm2. In addition, the highest short-circuit current density (JSC), i.e., 18.78 mA/cm2, and the highest mobility, i.e., 2.83 × 10−4 cm2/V·s, were obtained from the same detector without the CsI(Tl) scintillator.


2011 ◽  
Vol 1319 ◽  
Author(s):  
Catherine Dejoie ◽  
Pauline Martinetto ◽  
Eric Dooryhée ◽  
Ross Brown ◽  
Sylvie Blanc ◽  
...  

ABSTRACTThe search for durable dyes led several past civilizations to develop artificial pigments. Maya Blue (MB), manufactured in pre-Columbian Mesoamerica, is one of the best known examples of an organic-inorganic hybrid material. Its durability is due to the unique association of indigo molecule and palygorskite, a particular fibrous clay occurring in Yucatan. Despite 50 years of sustained interest, the microscopic structure of MB and its relation to the durability remain open questions. Combining new thermogravimetric and synchrotron X-ray diffraction analyses, we show that indigo molecules can diffuse into the channel of the palygorskite during the heating process, replacing zeolitic water and stabilizing the room temperature phases of the clay.


1999 ◽  
Vol 604 ◽  
Author(s):  
Keiichi Kuboyama ◽  
Kazumi Matsushige

AbstractSome transition metal oxides are known to exhibit the reversible coloration phenomena. Tungsten oxide is one of such materials and exhibits the photochromism and the electrochromism. It is known that the coloration phenomena in the tungsten oxide hydrate are caused by the redox reaction. We found that the photochromic efficiency became extremely higher by addition of some organic materials to the tungsten oxide hydrate and we have studied the mechanism of such a remarkable photochromic enhancement. In some spectroscopic measurement as FT-IR (Fourier transform infrared spectroscopy) and XPS (X-ray photoelectron spectroscopy), we obtained interesting features as follows. The addition of an organic material leads to reducing the tungsten oxide hydrate to smaller pieces, that is, the surface area of the pieces that can react with the additive increases. Moreover, it was found that specific sites in the additive are oxidized when the sample colors. The fact suggests that the additives having such specific sites can enhance the photochromism of the tungsten oxide hydrate


2015 ◽  
Vol 34 (4) ◽  
Author(s):  
Esma Ahlatcioǧlu ◽  
Bahire Filiz şenkal ◽  
Mustafa Okutan

AbstractIn this work, synthesis and characterization of composite materials based on NanoClay(NC) and boric acid doped PolyAniline (PANI) is studied. PANI was successfully incorporated into NC to form PANI-NC composites. The resulting organic-inorganic hybrid material, PANI-NC was characterized by various physicochemical techniques. Formation of PANI inside the clay tactoid has been confirmed by X-ray diffraction studies (XRD), scanning electron microscope (SEM) and FT-IR. Also, conductivity and physical properties of the PANI-NC composites were investigated.


2018 ◽  
Vol 54 (39) ◽  
pp. 4939-4942 ◽  
Author(s):  
Sebastian Schmidt ◽  
Sébastien Sallard ◽  
Camelia Borca ◽  
Thomas Huthwelker ◽  
Petr Novák ◽  
...  

When cycling diphosphonate-based organic–inorganic hybrid materials as negative battery electrodes, specific charges exceeding the maximum for a metal redox reaction are recorded.


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