Relationship between optical property and nanoparticle morphology in silver deposition-based multicolor electrochromic device (Conference Presentation)

Author(s):  
Norihisa Kobayashi ◽  
Kazuki Nakamura ◽  
Tomoko Sugita
1998 ◽  
Vol 540 ◽  
Author(s):  
N. Kishimoto ◽  
N. Umeda ◽  
Y. Takeda ◽  
C.G. Lee ◽  
V.T. Gritsyna

AbstractNegative Cu ions of 60 keV have been applied to generate metal nanocrystals embedded in insulators. Crystalline (c-), amorphous (a-)SiO2 and a spinel oxide, MgO·2(Al2O3), were irradiated at various dose rates up to about 100 µA/cm2, at a total dose of 3.O×1016 ions/cm2. In a-Sio2, morphology of nanoparticles and the resultant optical property changed with dose rate and, at a critical condition, showed in-plane arrangement of nanocrystals. The optical property of c-Si0 2 (a-quartz) was qualitatively similar to that of a-SiO2, but the implanted region of c-SiO2 showed different irradiation responses. The c-SiO2 was susceptible to radiation-induced amorphization but the nanoparticle morphology was still different from a-SiO2, suggesting a stronger depth-oriented driving force. Unlike SiO2, the spinel oxide showed good structural stability against the implantation and no tendency of the long-range atomic rearrangement. The results indicate that the crystallinity and the relevant interactions may play an important role in the nanoparticle growth during the implantation.


2020 ◽  
Vol 9 (4) ◽  
pp. e27942662
Author(s):  
Patrícia Capellato ◽  
Cláudia Eliana Bruno Marino ◽  
Gilbert Silva ◽  
Lucas Victor Benjamim Vasconcelos ◽  
Rodrigo Perito Cardoso ◽  
...  

During the last decades, researchers have been growing the interest in surface treatment with an antimicrobial agent. Silver nanoparticles (AgNPs) are widely used in biomedical fields due to their potent antimicrobial activity. So, in this study was investigated silver particles (isles) coated on titanium surface for dental and orthopedic application. Silver particles coating process on titanium surface were performed via sputtering that is a plasma-assisted deposition technique with and titanium without treatment was applied as comparing standard. Plasma treatment parameters were optimized so that the result was not a thin film of Ag but dispersed particles of Ag on the Ti-cp surface. The alloy surfaces were investigated using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). In order to investigate antibacterial potential Staphylococcus aureus and Escherichia coli have been used at Agar diffusion assay. The results were analyzed by analysis of variance (ANOVA) in order to verify significant difference antimicrobial activity between samples that have shown no difference between the surfaces studied treatments. For silver deposition scattered particles (isles) over titanium surface for a 10-minute treatment, EDS revealed by silver clusters that the particles were not properly scattered onto surface, hence, the low effectiveness in antibacterial activity.


2004 ◽  
Vol 9 (4) ◽  
pp. 363-372 ◽  
Author(s):  
T. Lukaszewicz ◽  
A. Ravinski ◽  
I. Makoed

A new multilayer electrochromic device has been constructed according to the following pattern: glass1/ITO/WO3/gel electrolyte/BP/ITO/glass2, where ITO is a transparent conducting film made of indium and tin oxide and with the surface resistance equal 8–10 Ω/cm2 . The electrochromic devices obtained in the research are characterized by great (considerable) transmittance variation between coloration and bleaching state (25–40% at applied voltage of 1.5 to 3 V), and also high coloration efficiency (above 100 cm2 /C). Selfconsistent energy bands, dielectric permittivity and optical parameters are calculated using a full-potential linear muffin-tin orbital method. The numerical solution of the Debye-Smoluchowski equations is developed for simulating recombination probability of Li+ ions in amorphous electrolyte.


2000 ◽  
Author(s):  
S. Woll ◽  
V. Loebs ◽  
C. Phelps ◽  
H. Pippin ◽  
D. Grandall ◽  
...  

2016 ◽  
Vol 27 (8) ◽  
pp. 7809-7821 ◽  
Author(s):  
N. Usha ◽  
R. Sivakumar ◽  
C. Sanjeeviraja ◽  
R. Balasubramaniam ◽  
Y. Kuroki

Author(s):  
Yuan Ma ◽  
Haiqin Su ◽  
Zhijun Zhang ◽  
Rui Wan ◽  
Shengwu Li ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Sean Swetledge ◽  
Renee Carter ◽  
Rhett Stout ◽  
Carlos E. Astete ◽  
Jangwook P. Jung ◽  
...  

AbstractPolymeric nanoparticles have been investigated as potential delivery systems for therapeutic compounds to address many ailments including eye disease. The stability and spatiotemporal distribution of polymeric nanoparticles in the eye are important regarding the practical applicability and efficacy of the delivery system in treating eye disease. We selected poly(lactic-co-glycolic acid) (PLGA) nanoparticles loaded with lutein, a carotenoid antioxidant associated with eye health, as our model ophthalmic nanodelivery system and evaluated its stability when suspended in various conditions involving temperature and light exposure. We also assessed the ocular biodistribution of the fluorescently labeled nanoparticle vehicle when administered topically. Lutein-loaded nanoparticles were stable in suspension when stored at 4 °C with only 26% lutein release and no significant lutein decay or changes in nanoparticle morphology. When stored at 25 °C and 37 °C, these NPs showed signs of bulk degradation, had significant lutein decay compared to 4 °C, and released over 40% lutein after 5 weeks in suspension. Lutein-loaded nanoparticles were also more resistant to photodegradation compared to free lutein when exposed to ultraviolet (UV) light, decaying approximately 5 times slower. When applied topically in vivo, Cy5-labled nanoparticles showed high uptake in exterior eye tissues including the cornea, episcleral tissue, and sclera. The choroid was the only inner eye tissue that was significantly higher than the control group. Decreased fluorescence in all exterior eye tissues and the choroid at 1 h compared to 30 min indicated rapid elimination of nanoparticles from the eye.


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