Combined effect of plasmonic interaction of nano-particles

2018 ◽  
Author(s):  
Naresh C. Das
Author(s):  
Rudresh B M ◽  
Ravikumar B N ◽  
Madhu D ◽  
Lingesh B V

This article deals with the combined effect of micro and nano fillers on mechanical, thermal and morphological behavior of glass-basalt hybrid composites (GB). Three material systems were selected for the study: glass-basalt fiber reinforced 80 wt. % PA66 – 20 wt. % PTFE blend (GB), GB/Micro fillers (MoS2, SiC, Al2O3) (GBM) and GBM/nano fillers (TiO2) (GBN). It has been revealed from the experimentation that the effect of micro fillers deteriorated the mechanical behavior of micro composites (GBM). But the combined effect of micro and nano fillers slightly impaired the mechanical behavior of nano composites. The synergistic effect of micro and nano fillers constrained the loss of strength of nano composites. But the impact strength of nano composites has been improved due to hybrid fillers effect. The hybrid effect of fillers significantly improved the thermal stability of nano composites. Further, it is observed from the morphology that the fractured surfaces were characterized by fiber pull out and fiber overlapping, severe deformation and agglomeration of nano particles.


2014 ◽  
Vol 21 (4) ◽  
pp. 597-605 ◽  
Author(s):  
Peng Zhang ◽  
Ya-nan Zhao ◽  
Chen-hui Liu ◽  
Peng Wang ◽  
Tian-hang Zhang

AbstractThis paper presents an experimental study to evaluate the combined effect of nano-SiO2 particles and steel fibers on flexural properties of concrete composites containing fly ash. In this study, five different nano-SiO2 contents (1%, 3%, 5%, 7%, and 9%) and five different steel fiber contents (0.5%, 1%, 1.5%, 2%, and 2.5%) were used. The results indicate that addition of nano-SiO2 and steel fibers decreases the workability of the concrete composites containing fly ash, and both the slump and slump flow decrease gradually with the increase in nano-SiO2 and steel fiber content. Besides, the addition of nano-SiO2 can greatly increase the flexural strength and flexural modulus of elasticity of concrete composites containing fly ash. There is a tendency for the increase in the flexural strength flexural modulus of elasticity with an increase in the nano-SiO2 content when the nano-SiO2 content is below 5%, while both of the two flexural parameters begin to decrease after the nano-SiO2 content above 5%. Furthermore, steel fibers have great improvement on the flexural properties of concrete composites containing fly ash and nano-particles. The flexural strength and flexural modulus of elasticity of concrete composites containing fly ash and nano-SiO2 are more than those of the concrete composite without steel fibers. Both of the two flexural parameters increase with the increase in steel fiber content when the steel fiber content is below 2%, while the flexural parameters begin to decrease after the steel fiber content is above 2%.


Author(s):  
A. K. Datye ◽  
D. S. Kalakkad ◽  
L. F. Allard ◽  
E. Völkl

The active phase in heterogeneous catalysts consists of nanometer-sized metal or oxide particles dispersed within the tortuous pore structure of a high surface area matrix. Such catalysts are extensively used for controlling emissions from automobile exhausts or in industrial processes such as the refining of crude oil to produce gasoline. The morphology of these nano-particles is of great interest to catalytic chemists since it affects the activity and selectivity for a class of reactions known as structure-sensitive reactions. In this paper, we describe some of the challenges in the study of heterogeneous catalysts, and provide examples of how electron holography can help in extracting details of particle structure and morphology on an atomic scale.Conventional high-resolution TEM imaging methods permit the image intensity to be recorded, but the phase information in the complex image wave is lost. However, it is the phase information which is sensitive at the atomic scale to changes in specimen thickness and composition, and thus analysis of the phase image can yield important information on morphological details at the nanometer level.


Author(s):  
J. Liu ◽  
M. Pan ◽  
G. E. Spinnler

Small metal particles have peculiar chemical and physical properties as compared to bulk materials. They are especially important in catalysis since metal particles are common constituents of supported catalysts. The structural characterization of small particles is of primary importance for the understanding of structure-catalytic activity relationships. The shape and size of metal particles larger than approximately 5 nm in diameter can be determined by several imaging techniques. It is difficult, however, to deduce the shape of smaller metal particles. Coherent electron nanodiffraction (CEND) patterns from nano particles contain information about the particle size, shape, structure and defects etc. As part of an on-going program of STEM characterization of supported catalysts we report some preliminary results of CEND study of Ag nano particles, deposited in situ in a UHV STEM instrument, and compare the experimental results with full dynamical simulations in order to extract information about the shape of Ag nano particles.


2007 ◽  
Vol 177 (4S) ◽  
pp. 79-80
Author(s):  
Jose A. Karam ◽  
Yair Lotan ◽  
Raheela Ashfaq ◽  
Claus G. Roehrborn ◽  
Arthur I. Sagalowsky ◽  
...  

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