Arsenic sulfide layers for dielectric reflection mirrors prepared from solution

Author(s):  
Vlastimil Matejec ◽  
Jitka Pedlikova ◽  
Ondrej Podrazky ◽  
Ivo Bartoň
Keyword(s):  
2019 ◽  
Vol 268 ◽  
pp. 06002 ◽  
Author(s):  
Kensuke Seno ◽  
Ilhwan Park ◽  
Carlito Tabelin ◽  
Kagehiro Magaribuchi ◽  
Mayumi Ito ◽  
...  

Arsenopyrite (FeAsS) is the most common primary arsenic-sulfide mineral in nature, and its oxidation causes the release of toxic arsenic (As). To mitigate these problems, carrier-microencapsulation (CME), a technique that passivates sulfide minerals by covering their surfaces with a protective coating, has been developed. In the previous study of authors on CME, Al-catecholate complex significantly suppressed arsenopyrite oxidation via electron donating effects of the complex and the formation of an Al-oxyhydroxide coating. For the application of this technique to real tailings, however, further study should be carried out to elucidate long-term effectiveness of the coating to suppress arsenopyrite oxidation. This study investigates the stability of the coating formed on arsenopyrite by Al-based CME using weathering tests. The Al-oxyhydroxide coating suppressed arsenopyrite oxidation until about 50 days of the experiment, but after this, the amounts of oxidation products like dissolved S and As increased due to the gradual dissolution of the coating with time as a result of the low pH of leachate. This suggests that co-disposal of Al-based CME-treated arsenopyrite with minerals that have appropriate neutralization potentials, so that the pH is maintained at around 5 to 8 where Al-oxyhydroxide is stable.


2021 ◽  
Vol 12 (19) ◽  
pp. 2551-2563
Author(s):  
Wei Tian ◽  
Yinping Sun ◽  
Yuping Cheng ◽  
Xiao Ma ◽  
Weina Du ◽  
...  

2012 ◽  
Vol 524-527 ◽  
pp. 1997-2003
Author(s):  
Hai Yun Xie ◽  
Zhuo Yue Lan ◽  
Shu Ming He ◽  
Li Kun Gao ◽  
Xiong Tong

The usage of high-arsenic sulfide copper concentrate were limited because the arsenic in the concentrate harms the qualities of copper product and pollutes the environment. In this paper an innovative process for high-arsenic copper sulfide concentrate with with bio-oxidation respectively Thiobacillus ferrooxidans and moderate thermophile Sulfobacillus thermosulfidooxidans has been studied out, and the influencing factors have been comparative studied during the leaching process, such as concentration particle size, leaching methods, pulp concentration, leaching time and the initial concentration of Fe3+, etc. Under the suitable leaching conditions, the experiments results show that the concentrate is leached 47.13% of Cu,50.09% of As and 52.46% of Fe by Thiobacillus ferrooxidans and 82.39% of Cu,78.21% of As and 40.38% of Fe by moderate thermophile Sulfobacillus thermosulfidooxidans. The high concentration initial Fe3+ has speeded leaching process up in the presence of moderate thermophile Sulfobacillus thermosulfidooxidans, and when the pulp initial concentration of Fe3+ is in the range of 0.08~0.32mol/L, the leaching rate of Cu is 86.34~97.06%, As 89.22~94.13%. It is concluded that Sulfobacillus thermosulfidooxidans have a better effect on bioleaching high-arsenic sulfide copper concentrate than Thiobacillus ferrooxidans.


2018 ◽  
Vol 83 (3) ◽  
pp. 519-530 ◽  
Author(s):  
Shudan Wang ◽  
Chao Zhang ◽  
Yumei Li ◽  
Ping Li ◽  
Dafang Zhang ◽  
...  
Keyword(s):  

2018 ◽  
Vol 52 (1) ◽  
pp. 015203 ◽  
Author(s):  
Leonid Mochalov ◽  
Alexander Logunov ◽  
Roman Kornev ◽  
Sergey Zelentsov ◽  
Andrey Vorotyntsev ◽  
...  

2018 ◽  
Vol 256 (2) ◽  
pp. 1800298 ◽  
Author(s):  
Yuriy M. Azhniuk ◽  
Dmytro Solonenko ◽  
Volodymyr M. Dzhagan ◽  
Ashutosh Mukherjee ◽  
Vasyl Y. Loya ◽  
...  

2016 ◽  
Vol 9 (19) ◽  
Author(s):  
Dong Won Lee ◽  
Jung-Yeul Yun ◽  
Da-Hee Park ◽  
Jei-Pil Wang

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