Field-induced exciton and CT-state dissociation probed by time-resolved luminescence quenching (Conference Presentation)

Author(s):  
Uli Lemmer ◽  
Marina Gerhard ◽  
Andreas P. Arndt ◽  
Martin Koch ◽  
Ian A. Howard
2010 ◽  
Vol 2 (9) ◽  
pp. 1298 ◽  
Author(s):  
Frank Sellrie ◽  
Michael Beck ◽  
Niko Hildebrandt ◽  
Burkhard Micheel

Science ◽  
2020 ◽  
Vol 370 (6520) ◽  
pp. 1072-1077
Author(s):  
Tomoyuki Endo ◽  
Simon P. Neville ◽  
Vincent Wanie ◽  
Samuel Beaulieu ◽  
Chen Qu ◽  
...  

Since the discovery of roaming as an alternative molecular dissociation pathway in formaldehyde (H2CO), it has been indirectly observed in numerous molecules. The phenomenon describes a frustrated dissociation with fragments roaming at relatively large interatomic distances rather than following conventional transition-state dissociation; incipient radicals from the parent molecule self-react to form molecular products. Roaming has been identified spectroscopically through static product channel–resolved measurements, but not in real-time observations of the roaming fragment itself. Using time-resolved Coulomb explosion imaging (CEI), we directly imaged individual “roamers” on ultrafast time scales in the prototypical formaldehyde dissociation reaction. Using high-level first-principles simulations of all critical experimental steps, distinctive roaming signatures were identified. These were rendered observable by extracting rare stochastic events out of an overwhelming background using the highly sensitive CEI method.


2004 ◽  
Vol 110 (4) ◽  
pp. 309-314 ◽  
Author(s):  
R. Schüppel ◽  
T. Dienel ◽  
K. Leo ◽  
M. Hoffmann

2018 ◽  
Vol 148 (7) ◽  
pp. 074306 ◽  
Author(s):  
Yen-Cheng Lin ◽  
Chin Lee ◽  
Shih-Huang Lee ◽  
Yin-Yu Lee ◽  
Yuan T. Lee ◽  
...  

2013 ◽  
Vol 117 (22) ◽  
pp. 4591-4601 ◽  
Author(s):  
T. J. Penfold ◽  
S. Karlsson ◽  
G. Capano ◽  
F. A. Lima ◽  
J. Rittmann ◽  
...  

1996 ◽  
Vol 8 (4) ◽  
pp. 497-504 ◽  
Author(s):  
M A Terekhin ◽  
I A Kamenskikh ◽  
V N Makhov ◽  
V A Kozlov ◽  
I H Munro ◽  
...  

2018 ◽  
Vol 27 (6) ◽  
pp. 060204 ◽  
Author(s):  
Man Zhang ◽  
Zhen-Gang Yang ◽  
Jin-Song Liu ◽  
Ke-Jia Wang ◽  
Jiao-Li Gong ◽  
...  

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