Tunable band gaps in a compressible dielectric elastomer thin cylinder with periodically applied voltages (Conference Presentation)

Author(s):  
Weiqiu Chen
2017 ◽  
Vol 84 (9) ◽  
Author(s):  
Pavel I. Galich ◽  
Stephan Rudykh

We analyze small amplitude shear waves (SWs) propagating in dielectric elastomer (DE) laminates subjected to finite deformations and electrostatic excitations. First, we derive long wave estimates for phase and group velocities of the shear waves propagating in any direction in DE laminates subjected to any homogenous deformation in the presence of an electric filed. To this end, we utilize a micromechanics-based energy potential for layered media with incompressible phases described by neo-Hookean ideal DE model. The long wave estimates reveal the significant influence of electric field on the shear wave propagation. However, there exists a configuration, for which electric field does not influence shear waves directly, and can only alter the shear waves through deformation. We study this specific configuration in detail, and derive an exact solution for the steady-state small amplitude waves propagating in the direction perpendicular to the finitely deformed DE layers subjected to electrostatic excitation. In agreement with the long wave estimate, the exact dispersion relation and the corresponding shear wave band gaps (SBGs)—forbidden frequency regions—are not influenced by electric field. However, SBGs in DE laminates with highly nonlinear electroelastic phases still can be manipulated by electric field through electrostatically induced deformation. In particular, SBGs in DE laminates with electroelastic Gent phases widen and shift toward higher frequencies under application of an electric field perpendicular to the layers. However, in laminates with neo-Hookean ideal DE phases, SBGs are not influenced either by electric field or by deformation. This is due to the competing mechanisms of two governing factors: changes in geometry and material properties induced by deformation. In this particular case, these two competing factors entirely cancel each other.


1997 ◽  
Vol 7 (3) ◽  
pp. 509-519 ◽  
Author(s):  
R. M. Hornreich ◽  
M. Kugler ◽  
S. Shtrikman ◽  
C. Sommers
Keyword(s):  

2019 ◽  
Author(s):  
Torben Sick ◽  
Niklas Keller ◽  
Nicolai Bach ◽  
Andreas Koszalkowski ◽  
Julian Rotter ◽  
...  

Covalent organic frameworks (COFs), consisting of covalently connected organic building units, combine attractive features such as crystallinity, open porosity and widely tunable physical properties. For optoelectronic applications, the incorporation of heteroatoms into a 2D COF has the potential to yield desired photophysical properties such as lower band gaps, but can also cause lateral offsets of adjacent layers. Here, we introduce dibenzo[g,p]chrysene (DBC) as a novel building block for the synthesis of highly crystalline and porous 2D dual-pore COFs showing interesting properties for optoelectronic applications. The newly synthesized terephthalaldehyde (TA), biphenyl (Biph), and thienothiophene (TT) DBC-COFs combine conjugation in the a,b-plane with a tight packing of adjacent layers guided through the molecular DBC node serving a specific docking site for successive layers. The resulting DBC-COFs exhibit a hexagonal dual-pore kagome geometry, which is comparable to COFs containing another molecular docking site, namely 4,4′,4″,4‴-(ethylene-1,1,2,2-tetrayl)-tetraaniline (ETTA). In this context, the respective interlayer distances decrease from about 4.60 Å in ETTA-COFs to about 3.6 Å in DBC-COFs, leading to well-defined hexagonally faceted single crystals sized about 50-100 nm. The TT DBC-COFs feature broad light absorption covering large parts of the visible spectrum, while Biph DBC-COF shows extraordinary excited state lifetimes exceeding 10 ns. In combination with the large number of recently developed linear conjugated building blocks, the new DBC tetra-connected node is expected to enable the synthesis of a large family of strongly p-stacked, highly ordered 2D COFs with promising optoelectronic properties.


Author(s):  
Edson Jansen Pedrosa de Miranda Junior ◽  
Jose Maria Campos dos Santos

Sign in / Sign up

Export Citation Format

Share Document