Column densities of trace gases from FTIR solar absorption spectrometry at different spectral resolutions in the station Zugspitze

1995 ◽  
Author(s):  
Klaus Schaefer ◽  
Andreas Haak ◽  
Rainer Haus ◽  
Joerg Heland ◽  
Ralf Sussmann
Keyword(s):  
Trace Gases ◽  
Absorption Spectrometry ◽  
Solar Absorption

scholarly journals Ground-based Measurements of Atmospheric Trace Gases in Beijing during the Olympic Games

Sci ◽  
2018 ◽  
Vol 1 (1) ◽  
pp. 6
Author(s):  
Jie Cheng
Keyword(s):  
Olympic Games ◽  
Trace Gases ◽  
Fourier Transform Spectrometer ◽  
Atmospheric Trace Gases ◽  
Validation Data ◽  
Solar Absorption ◽  
The Mean ◽  
The City ◽  
Total Column ◽  
The Olympic Games

A portable Fourier Transform Spectrometer (B3M-IR) is built and used to measure atmospheric trace gases in the city of Beijing during Olympic Games in 2008. A short description of the instrument is first provided in this paper. A detailed spectral analysis is then presented. The total columns of ozone (O3), carbon monoxide (CO), methane (CH4) and nitrous oxide (N2O) are retrieved from the ground-based solar absorption spectra recorded by the B3M-IR during the Olympic Games. Lacking validation data, only the retrieved total column of O3 is compared with that retrieved by MAX-DOAS, which is deployed at the same station. The mean difference between the two methods of measurement is 6.5%, demonstrating the performance and reliability of B3M-IR.

scholarly journals Remote sensing of CO<sub>2</sub> and CH<sub>4</sub> using solar absorption spectrometry with a low resolution spectrometer

2012 ◽  
Vol 5 (7) ◽  
pp. 1627-1635 ◽  
Author(s):  
C. Petri ◽  
T. Warneke ◽  
N. Jones ◽  
T. Ridder ◽  
J. Messerschmidt ◽  
...  
Keyword(s):  
High Resolution ◽  
A Priori ◽  
Absorption Spectrometry ◽  
Total Carbon ◽  
High Spectral Resolution ◽  
Low Resolution ◽  
Average Deviation ◽  
Solar Absorption ◽  
Fourier Transform Spectrometry ◽  
The Difference

Abstract. Throughout the last few years solar absorption Fourier Transform Spectrometry (FTS) has been further developed to measure the total columns of CO2 and CH4. The observations are performed at high spectral resolution, typically at 0.02 cm−1. The precision currently achieved is generally better than 0.25%. However, these high resolution instruments are quite large and need a dedicated room or container for installation. We performed these observations using a smaller commercial interferometer at its maximum possible resolution of 0.11 cm−1. The measurements have been performed at Bremen and have been compared to observations using our high resolution instrument also situated at the same location. The high resolution instrument has been successfully operated as part of the Total Carbon Column Observing Network (TCCON). The precision of the low resolution instrument is 0.32% for XCO2 and 0.46% for XCH4. A comparison of the measurements of both instruments yields an average deviation in the retrieved daily means of &amp;leq;0.2% for CO2. For CH4 an average bias between the instruments of 0.47% was observed. For test cases, spectra recorded by the high resolution instrument have been truncated to the resolution of 0.11 cm−1. This study gives an offset of 0.03% for CO2 and 0.26% for CH4. These results indicate that for CH4 more than 50% of the difference between the instruments results from the resolution dependent retrieval. We tentatively assign the offset to an incorrect a-priori concentration profile or the effect of interfering gases, which may not be treated correctly.

scholarly journals Quality assessment of ozone total column amounts as monitored by ground-based solar absorption spectrometry in the near infrared (> 3000 cm<sup>−1</sup>)

2014 ◽  
Vol 7 (3) ◽  
pp. 2071-2106
Author(s):  
O. E. García ◽  
M. Schneider ◽  
F. Hase ◽  
T. Blumenstock ◽  
E. Sepúlveda ◽  
...  
Keyword(s):  
Near Infrared ◽  
Absorption Spectrometry ◽  
Systematic Difference ◽  
Total Carbon ◽  
Atmospheric Composition ◽  
Solar Absorption ◽  
Annual Cycles ◽  
Long Term Stability ◽  
Total Column

Abstract. This study examines the possibility of ground-based remote sensing ozone total column amounts (OTC) from spectral signatures at 3040 and 4030 cm−1. These spectral regions are routinely measured by the NDACC (Network for the Detection of Atmospheric Composition Change) ground-based FTIR (Fourier Transform InfraRed) experiments. In addition, they are potentially detectable by the TCCON (Total Carbon Column Observing Network) FTIR instruments. The ozone retrieval strategy presented here estimates the OTC from NDACC FTIR high resolution spectra with a theoretical precision of about 2% and 5% in the 3040 cm−1 and 4030 cm−1 regions, respectively. Empirically, these OTC products are validated by inter-comparison to FTIR OTC reference retrievals in the 1000 cm−1 spectral region (standard reference for NDACC ozone products), using a 8 year FTIR time series (2005–2012) taken at the subtropical ozone super-site of the Izaña Observatory (Tenerife, Spain). Associated with the weaker ozone signatures at the higher wavenumber regions, the 3040 cm−1 and 4030 cm−1 retrievals show lower vertical sensitivity than the 1000 cm−1 retrievals. Nevertheless, we observe that the rather consistent variations are detected: the variances of the 3040 cm−1 and the 4030 cm−1 retrievals agree within 90% and 75%, respectively, with the variance of the 1000 cm−1 standard retrieval. Furthermore, all three retrievals show very similar annual cycles. However, we observe a large systematic difference of about 7% between the OTC obtained at 1000 cm−1 and 3040 cm−1, indicating a significant inconsistency between the spectroscopic ozone parameters (HITRAN 2012) of both regions. Between the 1000 cm−1 and the 4030 cm−1 retrieval the systematic difference is only 2–3%. Finally, the long-term stability of the OTC retrievals has also been examined, observing that both near infrared retrievals can monitor the long-term OTC evolution in consistency to the 1000 cm−1reference data.

scholarly journals Variations in the tropical uplift following the Pinatubo eruption studied by infrared solar absorption spectrometry

2000 ◽  
Vol 27 (17) ◽  
pp. 2609-2612 ◽  
Author(s):  
J. Notholt ◽  
G. C. Toon ◽  
B. Sen ◽  
N. B. Jones ◽  
C. P. Rinsland ◽  
...  
Keyword(s):  
Absorption Spectrometry ◽  
Solar Absorption ◽  
Pinatubo Eruption

scholarly journals Remote sensing of CO<sub>2</sub> and CH<sub>4</sub> using solar absorption spectrometry with a commercial low resolution spectrometer

2012 ◽  
Vol 5 (1) ◽  
pp. 245-269 ◽  
Author(s):  
C. Petri ◽  
T. Warneke ◽  
N. Jones ◽  
T. Ridder ◽  
J. Messerschmidt ◽  
...  
Keyword(s):  
High Resolution ◽  
A Priori ◽  
Absorption Spectrometry ◽  
Total Carbon ◽  
High Spectral Resolution ◽  
Low Resolution ◽  
Average Deviation ◽  
Solar Absorption ◽  
Fourier Transform Spectrometry ◽  
The Difference

Abstract. Throughout the last few years solar absorption Fourier Transform Spectrometry (FTS) has been further developed to measure the total columns of CO2 and CH4. The observations are performed at high spectral resolution, typically at 0.02 cm−1. The precision achieved is actually generally better than 0.25%. However, these high resolution instruments are quite large and need a dedicated room or container for installation. We performed these observations using a smaller commercial interferometer at its maximum possible resolution of 0.11 cm−1. The measurements have been performed at Bremen and have been compared to observations using our high resolution instrument also situated at the same location. The high resolution instrument has been successfully operated as part of the Total Carbon Column Observing Network (TCCON). The precision of the low resolution instrument is 0.32% for XCO2 and 0.46% for XCH4. A comparison of the measurements of both instruments yields an average deviation in the retrieved daily means of &amp;leq;0.2% for CO2. For CH4 an average bias between the instruments of 0.46% was observed. For test cases, spectra recorded by the high resolution instrument have been truncated to the resolution of 0.11 cm−1. This study gives an offset of 0.03% for CO2 and 0.26% for CH4. These results indicate that for CH4 more than 50% of the difference between the instruments results from the resolution dependant retrieval. We tentatively assign the offset to an incorrect a-priori concentration profile or the effect of interfering gases, which may not be treated correctly.

scholarly journals Pointing errors in solar absorption spectrometry – correction scheme and its validation

2015 ◽  
Vol 8 (6) ◽  
pp. 6179-6215
Author(s):  
A. Reichert ◽  
P. Hausmann ◽  
R. Sussmann
Keyword(s):  
Near Infrared ◽  
Rotation Axis ◽  
Solar Rotation ◽  
Absorption Spectrometry ◽  
Time Interval ◽  
A Posteriori ◽  
Vertical Column ◽  
Solar Absorption ◽  
Pointing Errors ◽  
Correction Scheme

Abstract. A method for quantification of sun-pointing inaccuracies in solar absorption spectrometry is presented along with a correction scheme for the resulting errors in trace gas vertical column or profile retrievals. A posteriori correction of pointing errors requires knowledge of both coordinates of the mispointing vector on the solar disk. In principle, quantitative information on the mispointing can be retrieved from Doppler shifts of solar lines derived from measured spectra. However, this yields only one component of the mispointing vector, namely the one which is perpendicular to the solar rotation axis. Missing information on the second vector component has hindered a posteriori correction of mispointing errors so far. Our idea to overcome this problem is to obtain estimates of both coordinates of the mispointing by combining subsequent measurements with differing orientations of the solar rotation axis relative to the zenith direction. An implementation of this original concept is demonstrated using measurements from the solar absorption Fourier transform infrared (FTIR) spectrometer at the Zugspitze (47.42° N, 10.98° E, 2964 m a.s.l.). Soundings in the September 2012 to September 2014 time interval were impacted by mispointing problems due to a non-optimum solar tracking optics configuration. They show a mean mispointing in zenith direction of −0.063°. This causes biases in vertical soundings of trace gases, e.g. −2.82 ppb in monthly means of dry-air column-averaged mole fractions of methane (XCH4). Measurements made with the more stable pre-September 2012 and post-September 2014 optics configurations show considerably smaller mispointing effects. Applying the mispointing correction, the April 2006–March 2014 XCH4 trend determined from Zugspitze measurements is reduced from 6.45 [5.84, 7.04] to 6.07 [5.55, 6.59] ppb yr−1. The correction thereby restores consistency with results from the nearby Garmisch FTIR site (47.48° N, 11.06° E, 743 m a.s.l.). The mispointing correction is applicable to solar absorption measurements in the mid infrared and near infrared. It will be of particular benefit for refining existing records of high-accuracy-and-precision greenhouse gas soundings for the purpose of improved trend analysis or source-sink inversions.

scholarly journals Atmospheric carbonyl sulfide (OCS) measured remotely by FTIR solar absorption spectrometry

2018 ◽  
Vol 18 (3) ◽  
pp. 1923-1944 ◽  
Author(s):  
Geoffrey C. Toon ◽  
Jean-Francois L. Blavier ◽  
Keeyoon Sung
Keyword(s):  
Carbonyl Sulfide ◽  
Absorption Spectrometry ◽  
Early Summer ◽  
Solar Absorption ◽  
Spectral Fitting ◽  
The Past ◽  
Infra Red ◽  
Ftir Spectrometer ◽  
Balloon Measurements

Abstract. Atmospheric OCS abundances have been retrieved from infrared spectra measured by the Jet Propulsion Laboratory (JPL) MkIV Fourier transform infra-red (FTIR) spectrometer during 24 balloon flights and during nearly 1100 days of ground-based observations since 1985. Our spectral fitting approach uses broad windows to enhance the precision and robustness of the retrievals. Since OCS has a vertical profile similar in shape to that of N2O, and since tropospheric N2O is very stable, we reference the OCS observations to those of N2O, measured simultaneously in the same air mass, to remove the effects of stratospheric transport, allowing a clearer assessment of secular changes in OCS. Balloon measurements reveal less than 5 % change in stratospheric OCS amounts over the past 25 years. Ground-based measurements reveal a springtime peak of tropospheric OCS, followed by a rapid early-summer decrease, similar to the behavior of CO2. This results in a peak-to-peak seasonal cycle of 5–6 % of the total OCS column at northern mid-latitudes. In the long-term tropospheric OCS record, a 5 % decrease is seen from 1990 to 2002, followed by a 5 % increase from 2003 to 2012.

scholarly journals The arctic seasonal cycle of total column CO<sub>2</sub> and CH<sub>4</sub> from ground-based solar and lunar FTIR absorption spectrometry

2017 ◽  
Vol 10 (7) ◽  
pp. 2397-2411 ◽  
Author(s):  
Matthias Buschmann ◽  
Nicholas M. Deutscher ◽  
Mathias Palm ◽  
Thorsten Warneke ◽  
Christine Weinzierl ◽  
...  
Keyword(s):  
Seasonal Cycle ◽  
Model Comparison ◽  
Near Infrared ◽  
Absorption Spectrometry ◽  
Total Carbon ◽  
The Arctic ◽  
Solar Absorption ◽  
Novel Method ◽  
Total Column ◽  
Absorption Measurements

Abstract. Solar absorption spectroscopy in the near infrared has been performed in Ny-Ålesund (78.9° N, 11.9° E) since 2002; however, due to the high latitude of the site, the sun is below the horizon from October to March (polar night) and no solar absorption measurements are possible. Here we present a novel method of retrieving the total column dry-air mole fractions (DMFs) of CO2 and CH4 using moonlight in winter. Measurements have been taken during the polar nights from 2012 to 2016 and are validated with TCCON (Total Carbon Column Observing Network) measurements by solar and lunar absorption measurements on consecutive days and nights during spring and autumn. The complete seasonal cycle of the DMFs of CO2 and CH4 is presented and a precision of up to 0.5 % is achieved. A comparison of solar and lunar measurements on consecutive days during day and night in March 2013 yields non-significant biases of 0. 66 ± 4. 56 ppm for xCO2 and −1. 94 ± 20. 63 ppb for xCH4. Additionally a model comparison has been performed with data from various reanalysis models.

Sign in / Sign up

Export Citation Format

Share Document