scholarly journals Model photo-responsive elastomers based on the self-assembly of side group liquid crystal triblock copolymers (Presentation Recording)

2015 ◽  
Author(s):  
Zuleikha Kurji ◽  
Julia A. Kornfield ◽  
Mark G. Kuzyk
2019 ◽  
Vol 4 (4) ◽  
pp. 921-928 ◽  
Author(s):  
Jiawei Li ◽  
Junfeng Wang ◽  
Qiang Yao ◽  
Yan Zhang ◽  
Youguo Yan ◽  
...  

ABA triblock copolymers have been demonstrated to be able to produce a biphasic effect on the self-assembly of surfactants.


2016 ◽  
Vol 52 (48) ◽  
pp. 7564-7567 ◽  
Author(s):  
Keren Zhang ◽  
Samantha J. Talley ◽  
Ya Peng Yu ◽  
Robert B. Moore ◽  
Mitsuhiro Murayama ◽  
...  

ABC triblock copolymers bearing adenine- and thymine-functionalized external blocks self-assembled into long-range, ordered lamellar microphase-separated morphologies on non-patterned substrates.


2020 ◽  
Vol 98 (7) ◽  
pp. 379-385
Author(s):  
Carson O. Zellman ◽  
Danielle Vu ◽  
Vance E. Williams

Although the impact of individual functional groups on the self-assembly of columnar liquid crystal phases has been widely studied, the effect of varying multiple substituents has received much less attention. Herein, we report a series of dibenzo[a,c]phenazines containing an alcohol or ether adjacent to an electron-withdrawing ester or acid. With one exception, these difunctional mesogens form columnar phases. The phase behavior appeared to be dominated by the electron-withdrawing substituent; transition temperatures were similar to derivatives with these groups in isolation. In most instances, the addition of an electron-donating group ortho to an ester or acid suppressed the melting temperature and elevated the clearing temperature, leading to broader liquid crystal thermal ranges. This effect was more pronounced for derivatives functionalized with longer chain hexyloxy groups. These results suggest a potential strategy for controlling the phase ranges of columnar liquid crystals and achieving room temperature mesophases.


Soft Matter ◽  
2015 ◽  
Vol 11 (4) ◽  
pp. 680-691 ◽  
Author(s):  
Anna Akinshina ◽  
Martin Walker ◽  
Mark R. Wilson ◽  
Gordon J. T. Tiddy ◽  
Andrew J. Masters ◽  
...  

Molecular dynamics simulations of non-ionic triphenylene-based chromonic liquid crystal molecules demonstrate self-assembly of the molecules into stacks and “quasi-isodesmic” aggregation behaviour.


2008 ◽  
Vol 41 (7) ◽  
pp. 2459-2466 ◽  
Author(s):  
Wei Deng ◽  
Pierre-Antoine Albouy ◽  
Emmanuelle Lacaze ◽  
Patrick Keller ◽  
Xiaogong Wang ◽  
...  

2013 ◽  
Vol 1 (44) ◽  
pp. 7321 ◽  
Author(s):  
Susana Castelar ◽  
Joaquín Barberá ◽  
Mercedes Marcos ◽  
Pilar Romero ◽  
José-Luis Serrano ◽  
...  

2007 ◽  
Vol 21 (28n29) ◽  
pp. 4961-4966
Author(s):  
HUI-RU MA ◽  
JIAN-GUO GUAN ◽  
RUN-ZHANG YUAN

The self-assembly properties and ER effects of the Polyaniline-Poly(ethylene glycol)-Polyaniline (PAn-PEG-PAn) triblock copolymers were studied in this paper. The results indicate that with the increase of solubility parameter of the solvent, PAn-PEG-PAn copolymers form into different morphologies of spheriods, vesicles and rods. PAn-PEG-PAn copolymers with vesicles morphology show the highest polarization strength, while those with rods have the most rapid polarization rate. Among the PAn-PEG-PAn copolymers of different morphologies, the PAn-PEG-PAn copolymer vesicles show the strongest ER effect.


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