The role of guide stripe chemistry in block copolymer directed self-assembly

Author(s):  
Robert Seidel ◽  
Lance Williamson ◽  
YoungJun Her ◽  
Jihoon Kim ◽  
Guanyang Lin ◽  
...  
Soft Matter ◽  
2016 ◽  
Vol 12 (34) ◽  
pp. 7241-7247 ◽  
Author(s):  
Dan Zhao ◽  
Matteo Di Nicola ◽  
Mohammad M. Khani ◽  
Jacques Jestin ◽  
Brian C. Benicewicz ◽  
...  

2016 ◽  
Vol 49 (21) ◽  
pp. 8187-8197 ◽  
Author(s):  
Michael A. Brady ◽  
Sung-Yu Ku ◽  
Louis A. Perez ◽  
Justin E. Cochran ◽  
Kristin Schmidt ◽  
...  

2021 ◽  
Author(s):  
Shaofei Song ◽  
Jingjie Jiang ◽  
Ehsan Nikbin ◽  
Jane Howe ◽  
Ian Manners ◽  
...  

Self-assembly of crystalline-coil block copolymers (BCPs) in selective solvents is often carried out by heating the mixture until the sample appears to dissolve and then allowing the solution to cool...


2018 ◽  
Vol 220 (3) ◽  
pp. 1800443 ◽  
Author(s):  
Shuo Zhang ◽  
Chunhua Cai ◽  
Zhanwen Xu ◽  
Jiaping Lin ◽  
Xiao Jin

2005 ◽  
Vol 42 (3) ◽  
pp. 180-183 ◽  
Author(s):  
S. G. Schulz ◽  
U. Frieske ◽  
H. Kuhn ◽  
G. Schmid ◽  
F. Müller ◽  
...  

2020 ◽  
Vol 27 (9) ◽  
pp. 923-929
Author(s):  
Gaurav Pandey ◽  
Prem Prakash Das ◽  
Vibin Ramakrishnan

Background: RADA-4 (Ac-RADARADARADARADA-NH2) is the most extensively studied and marketed self-assembling peptide, forming hydrogel, used to create defined threedimensional microenvironments for cell culture applications. Objectives: In this work, we use various biophysical techniques to investigate the length dependency of RADA aggregation and assembly. Methods: We synthesized a series of RADA-N peptides, N ranging from 1 to 4, resulting in four peptides having 4, 8, 12, and 16 amino acids in their sequence. Through a combination of various biophysical methods including thioflavin T fluorescence assay, static right angle light scattering assay, Dynamic Light Scattering (DLS), electron microscopy, CD, and IR spectroscopy, we have examined the role of chain-length on the self-assembly of RADA peptide. Results: Our observations show that the aggregation of ionic, charge-complementary RADA motifcontaining peptides is length-dependent, with N less than 3 are not forming spontaneous selfassemblies. Conclusion: The six biophysical experiments discussed in this paper validate the significance of chain-length on the epitaxial growth of RADA peptide self-assembly.


2019 ◽  
Vol 4 (1) ◽  
pp. 91-102 ◽  
Author(s):  
Ryan T. Shafranek ◽  
Joel D. Leger ◽  
Song Zhang ◽  
Munira Khalil ◽  
Xiaodan Gu ◽  
...  

Directed self-assembly in polymeric hydrogels allows tunability of thermal response and viscoelastic properties.


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