Excited state absorption (ESA) spectroscopy measurement of charge transfer bands in doped ionic crystals

1995 ◽  
Author(s):  
B. K. Sevastyanov
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Excited State Absorption ◽  
Ionic Crystals ◽  
Spectroscopy Measurement

Fourier Transform Techniques for Measuring Absorption of Transient Species Inoptical Limiting Materials

1999 ◽  
Vol 597 ◽  
Author(s):  
Yanong Han ◽  
Wendi Sonnenberg ◽  
Kurt W. Short ◽  
Amy Hyfield ◽  
Lee H. Spangler
Keyword(s):  
Fourier Transform ◽  
Excited State ◽  
Charge Transfer ◽  
Ultrafast Lasers ◽  
Excited State Absorption ◽  
Spectral Information ◽  
Transient Species ◽  
Rapid Scan ◽  
Wide Range ◽  
Incoherent Source

AbstractWe have developed methods of measuring absorption of transient species utilizing both rapid scan and stepped-scan Fourier transform interferometery that allows a combination of broad spectral coverage (10,000 – 15,000 cm-1 per spectrum), good spectral resolution, and the ability to cover temporal ranges from minutes to nanoseconds. A wide range of pump sources are used including continuous, modulated, ns pulsed, and ultrafast lasers. The probe is provided by a broadband, incoherent source providing large spectral information in each experiment. This capability enables investigation of phenomena such as excited state absorption, charge transfer, formation of metastable species, and others. Extension of the technique to the ps realm is underway and will be discussed.

Photo-Induced Effects in Mn4+:YAG. Observation of Unusually Efficient Excited State Absorption and a Long–Lived Metastable State

1999 ◽  
Vol 597 ◽  
Author(s):  
Yanong Han ◽  
Lee H. Spangler ◽  
Ralph Hutcheson ◽  
Randy W. Equall
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Excited State Absorption ◽  
Wavelength Region ◽  
Optical Storage ◽  
Electron Configuration ◽  
Valence States ◽  
Wide Range ◽  
Potential Applications ◽  
Long Lifetime

AbstractThe Mn4+ ion has the same d3 electron configuration as Cr3+, but is less stable and can transform to other valence states. Both ions are known to occupy several sites in garnet hosts, giving rise to rather complicated optical spectra and photo-induced phenomena. Here, the spectra of the transient, photo-induced absorption and the emission of Mn4+,:YAG are analyzed over a broad wavelength region (from 450 to 1200nm) and over a wide range of time scales (from ns to minutes). Very large amplitude and extremely broadband excited state absorption are observed. Additionally, a long lifetime, photo-induced species was detected that is likely formed via charge transfer. The demonstrated behavior of this material shows it has potential applications for optical limiting and optical storage.

Intramolecular Charge Transfer with the Planarized 4-Cyanofluorazene and Its Flexible Counterpart 4-Cyano-N-phenylpyrrole. Picosecond Fluorescence Decays and Femtosecond Excited-State Absorption

2008 ◽  
Vol 112 (36) ◽  
pp. 8238-8253 ◽  
Author(s):  
Sergey I. Druzhinin ◽  
Sergey A. Kovalenko ◽  
Tamara A. Senyushkina ◽  
Attila Demeter ◽  
Reinhard Machinek ◽  
...  
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Intramolecular Charge Transfer ◽  
Excited State Absorption

Dynamic adjustment of emission from both singlets and triplets: the role of excited state conformation relaxation and charge transfer in phenothiazine derivates

2021 ◽  
Author(s):  
Weidong Qiu ◽  
Xinyi Cai ◽  
Mengke Li ◽  
Liangying Wang ◽  
Yanmei He ◽  
...  
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Intramolecular Charge Transfer ◽  
Dynamic Adjustment ◽  
Twisted Intramolecular Charge Transfer

Dynamic adjustment of emission behaviours by controlling the extent of twisted intramolecular charge transfer character in excited state.

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