Interactions and penetration at metal/self‐assembled organic monolayer interfaces

1996 ◽  
Vol 14 (3) ◽  
pp. 1779-1787 ◽  
Author(s):  
D. R. Jung ◽  
A. W. Czanderna ◽  
G. C. Herdt
1995 ◽  
Vol 385 ◽  
Author(s):  
D. R. Jung ◽  
A. W. Czanderna ◽  
G. C. Herdt

ABSTRACTThe purpose of research on metals (M) deposited onto self-assembled monolayers (SAMs) is to understand the interactions between the metal and eventually metal oxide overlayers on well-ordered organic substrates. Applications of M/SAM and inorganic/SAM research results to the understanding of real inorganic/organic interfaces in vacuum and under environmental conditions can potentially play a key role in the development of advanced devices with stable interfacial properties. The results of selected M/SAM studies to date are reviewed, and MISAM combinations ranked according to reactivity and penetration. Specific examples of reactive interfaces (Cu/COOH, Cr/several groups) and nonreactive interfaces with penetration (Ag/CH3, Ag/COOH) are used to illustrate the extremes.


2018 ◽  
Vol 677 ◽  
pp. 68-77 ◽  
Author(s):  
Annika Venäläinen ◽  
Kristoffer Meinander ◽  
Minna Räisänen ◽  
Vladimir Tuboltsev ◽  
Jyrki Räisänen

2020 ◽  
Vol 45 (15) ◽  
pp. 4244
Author(s):  
Andre Kovach ◽  
Arynn Gallegos ◽  
Jinghan He ◽  
Hyungwoo Choi ◽  
Andrea M. Armani

Langmuir ◽  
2017 ◽  
Vol 33 (13) ◽  
pp. 3170-3177 ◽  
Author(s):  
Fan Wu ◽  
De-Wen Zhang ◽  
Jian Wang ◽  
Michael Watkinson ◽  
Steffi Krause

1996 ◽  
Vol 451 ◽  
Author(s):  
G. K. Jennings ◽  
P. E. Laibinis

ABSTRACTThis paper describes a new family of organized molecular assemblies that are produced by the spontaneous adsorption of alkanethiols onto gold surfaces that have been modified by the underpotential deposition of copper or silver. The system has the flexibility associated with the formation of self-assembled monolayers by the adsorption of thiols onto gold with the advantage of improved stability. The use of these systems as modified electrodes is also addressed.


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