Hydrogen atom detection by H− conversion

1993 ◽  
Vol 11 (5) ◽  
pp. 2700-2706 ◽  
Author(s):  
E. C. Samano ◽  
W. E. Carr
Keyword(s):  
1970 ◽  
Vol 41 (9) ◽  
pp. 1282-1283 ◽  
Author(s):  
R. H. McKnight ◽  
D. H. Crandall ◽  
D. H. Jaecks

Author(s):  
Maria Ruchkina ◽  
Pengji Ding ◽  
Andreas Ehn ◽  
Marcus Aldén ◽  
Joakim Bood

1982 ◽  
Vol 138 (10) ◽  
pp. 347 ◽  
Author(s):  
Yurii L. Sokolov ◽  
V.P. Yakovlev
Keyword(s):  

2019 ◽  
Author(s):  
Shiori Date ◽  
Kensei Hamasaki ◽  
Karen Sunagawa ◽  
Hiroki Koyama ◽  
Chikayoshi Sebe ◽  
...  

<div>We report here a catalytic, Markovnikov selective, and scalable synthetic method for the synthesis of saturated sulfur heterocycles, which are found in the structures of pharmaceuticals and natural products, in one step from an alkenyl thioester. Unlike a potentially labile alkenyl thiol, an alkenyl thioester is stable and easy to prepare. The powerful Co catalysis via a cobalt hydride hydrogen atom transfer and radical-polar crossover mechanism enabled simultaneous cyclization and deprotection. The substrate scope was expanded by the extensive optimization of the reaction conditions and tuning of the thioester unit.</div>


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