Abstract: Atomic chemisorption on simple metals: Chemical trends and core‐hole relaxation effects

1978 ◽  
Vol 15 (2) ◽  
pp. 510-510 ◽  
Author(s):  
N. D. Lang ◽  
A. R. Williams
Keyword(s):  
Core Hole ◽  
Relaxation Effects ◽  
Chemical Trends

Polarization and site dependence of interatomic relaxation effects in double core hole states

2013 ◽  
Vol 46 (16) ◽  
pp. 164012 ◽  
Author(s):  
Motomichi Tashiro ◽  
Nikolai V Kryzhevoi ◽  
Lorenz S Cederbaum ◽  
Masahiro Ehara
Keyword(s):  
Core Hole ◽  
Relaxation Effects ◽  
Site Dependence

Effect of Lattice Relaxation on the Soft X-Ray Spectra of Metals

1971 ◽  
Vol 49 (24) ◽  
pp. 3155-3165 ◽  
Author(s):  
B. Bergersen ◽  
T. McMullen ◽  
J. P. Carbotte
Keyword(s):  
Harmonic Approximation ◽  
Lattice Relaxation ◽  
Linear Response Theory ◽  
Scattering Data ◽  
Core Hole ◽  
X Ray ◽  
The Core ◽  
Relaxation Effects ◽  
Order Of Magnitude ◽  
Lifetime Effects

The effect of relaxation of the lattice around the core hole on the soft X-ray spectra of metals near the Fermi edge, with particular application to Li and Na, is investigated. Neglecting lifetime effects, linearizing the core-hole phonon coupling and making a harmonic approximation for the phonons, the problem is exactly solvable by a generalization of a method previously proposed by Langreth to finite temperatures. Numerical calculations are carried out within the framework of linear response theory using the Thomas–Fermi, R.P.A., and Singwi et al. dielectric functions, and realistic phonon spectra obtained from neutron inelastic scattering data. The calculations give rise to lattice relaxation effects of similar magnitude in both metals. The results are considerably smaller than would be necessary to explain the shape of the Li spectra (contrary to a previous suggestion), while in Na the contribution is calculated to be of the same order of magnitude, but with a different temperature dependence, than the other factors influencing the shape of the absorption edge.

CORE-HOLE SCREENING IN LIGHT RARE-EARTH INSULATING COMPOUNDS

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-961-C8-964
Author(s):  
E. BEAUREPAIRE ◽  
F. LE NORMAND ◽  
G. KRILL
Keyword(s):  
Rare Earth ◽  
Light Rare Earth ◽  
Core Hole
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