Electron paramagnetic resonance characterization of defects in HfO[sub 2] and ZrO[sub 2] powders and films

2009 ◽  
Vol 27 (1) ◽  
pp. 317 ◽  
Author(s):  
R. C. Barklie ◽  
Sandra Wright
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Paramagnetic Resonance ◽  
Electron Paramagnetic

Electron Paramagnetic Resonance as a Probe for Metal Ions and Radicals in Paper

2015 ◽  
Vol 36 (4) ◽  
Author(s):  
Alfonso Zoleo ◽  
Laura Speri ◽  
Maddalena Bronzato
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Metal Ions ◽  
Chemical Species ◽  
Paramagnetic Species ◽  
Paramagnetic Resonance ◽  
Relevant Role ◽  
Historic Paper ◽  
Electron Paramagnetic ◽  
Identification And Characterization

AbstractElectron Paramagnetic Resonance (EPR) is a technique devoted to the identification and characterization of paramagnetic species, i.e. chemical species with unpaired electrons. Very common paramagnetic species which can be detected through EPR in historic paper are Fe(III), Mn(II), Cu(II) ions and radicals, where Fe(III), Cu(II) and radicals play a relevant role in paper degradation. Specifically, Fe(III) is almost ubiquitous in historic paper. Here we propose an overview of the EPR signals in historic and artificially aged paper, and in particular, we would like to show how a deep analysis of EPR signals from paper could provide useful information about the paper’s origin and unique indications of the degradation and oxidation level of the paper.

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