scholarly journals Performance of salt impreganted matrix materials for the long term thermochemical storage of low grade solar thermal energy

2019 ◽  
Author(s):  
Robert J. Sutton ◽  
Jonathon Elvins ◽  
Eifion Jewell ◽  
Justin R. Searle
Keyword(s):  
Thermal Energy ◽  
Solar Thermal ◽  
Low Grade ◽  
Solar Thermal Energy

scholarly journals Energy Analysis of a Novel Ejector-Compressor Cooling Cycle Driven by Electricity and Heat (Waste Heat or Solar Energy)

2020 ◽  
Vol 12 (19) ◽  
pp. 8178
Author(s):  
Fahid Riaz ◽  
Kah Hoe Tan ◽  
Muhammad Farooq ◽  
Muhammad Imran ◽  
Poh Seng Lee
Keyword(s):  
Low Temperature ◽  
Thermal Energy ◽  
Waste Heat ◽  
Solar Thermal ◽  
Coefficient Of Performance ◽  
Condensation Temperature ◽  
Low Grade ◽  
Solar Thermal Energy ◽  
Temperature Heat ◽  
Vapour Compression

Low-grade heat is abundantly available as solar thermal energy and as industrial waste heat. Non concentrating solar collectors can provide heat with temperatures 75–100 °C. In this paper, a new system is proposed and analyzed which enhances the electrical coefficient of performance (COP) of vapour compression cycle (VCC) by incorporating low-temperature heat-driven ejectors. This novel system, ejector enhanced vapour compression refrigeration cycle (EEVCRC), significantly increases the electrical COP of the system while utilizing abundantly available low-temperature solar or waste heat (below 100 °C). This system uses two ejectors in an innovative way such that the higher-pressure ejector is used at the downstream of the electrically driven compressor to help reduce the delivery pressure for the electrical compressor. The lower pressure ejector is used to reduce the quality of wet vapour at the entrance of the evaporator. This system has been modelled in Engineering Equation Solver (EES) and its performance is theoretically compared with conventional VCC, enhanced ejector refrigeration system (EERS), and ejection-compression system (ECS). The proposed EEVCRC gives better electrical COP as compared to all the three systems. The parametric study has been conducted and it is found that the COP of the proposed system increases exponentially at lower condensation temperature and higher evaporator temperature. At 50 °C condenser temperature, the electrical COP of EEVCRC is 50% higher than conventional VCC while at 35 °C, the electrical COP of EEVCRC is 90% higher than conventional VCC. For the higher temperature heat source, and hence the higher generator temperatures, the electrical COP of EEVCRC increases linearly while there is no increase in the electrical COP for ECS. The better global COP indicates that a small solar collector will be needed if this system is driven by solar thermal energy. It is found that by using the second ejector at the upstream of the electrical compressor, the electrical COP is increased by 49.2% as compared to a single ejector system.

scholarly journals Hydrophobised carbon foams for improved long-term seasonal solar thermal energy storage

2021 ◽  
Vol 220 ◽  
pp. 110849
Author(s):  
P. Jana ◽  
E. Palomo del Barrio ◽  
M. Dubois ◽  
M. Duquesne ◽  
A. Godin ◽  
...  
Keyword(s):  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Solar Thermal ◽  
Solar Thermal Energy ◽  
Carbon Foams

Mechanism of Upgrading Low-Grade Solar Thermal Energy and Experimental Validation

2008 ◽  
Vol 130 (2) ◽  
Author(s):  
Hui Hong ◽  
Hongguang Jin ◽  
Jun Sui ◽  
Jun Ji
Keyword(s):  
Energy Level ◽  
Thermal Energy ◽  
Power Plants ◽  
Thermal Power ◽  
Chemical Energy ◽  
Solar Thermal ◽  
Low Grade ◽  
Thermal Power Plants ◽  
Solar Thermal Energy ◽  
Middle Temperature

Solar thermochemical processes inherently included the conversion of solar thermal energy into chemical energy. In this paper, a new mechanism of upgrading the energy level of solar thermal energy at around 200°C was revealed based on the second law thermodynamics and was then experimentally proven. An expression was derived to describe the upgrading of the energy level from low-grade solar thermal energy to high-grade chemical energy. The resulting equation explicitly reveals the interrelations of energy levels between middle-temperature solar thermal energy and methanol fuel, and identifies the interactions of mean solar flux and the reactivity of methanol decomposition. The proposed mechanism was experimentally verified by using the fabricated 5kW prototype of the receiver∕reactor. The agreement between the theoretical and the experimental results proves the validity of the mechanism for upgrading the energy level of low-grade solar thermal energy by integrating clean synthetic fuel. Moreover, the application of this new middle-temperature solar∕methanol hybrid thermochemical process into a combined cycle is expected to have a net solar-to-electric efficiency of about 27.8%, which is competitive with other solar-hybrid thermal power plants using high-temperature solar thermal energy. The results obtained here indicate the possibility of utilizing solar thermal energy at around 200°C for electricity generation with high efficiency by upgrading the energy level of solar thermal energy, and provide an enhancement to solar thermal power plants with the development of this low-grade solar thermochemical technology in the near future.

A Novel Solar-Hybrid Gas Turbine Combined Cycle With Inherent CO2 Separation Using Chemical-Looping Combustion by Solar Heat Source

2006 ◽  
Vol 128 (3) ◽  
pp. 275-284 ◽  
Author(s):  
Hui Hong ◽  
Hongguang Jin ◽  
Baiqian Liu
Keyword(s):  
Metal Oxide ◽  
Thermal Energy ◽  
Combined Cycle ◽  
Solar Thermal ◽  
Chemical Looping Combustion ◽  
Co2 Separation ◽  
Inlet Temperature ◽  
Low Grade ◽  
Chemical Looping ◽  
Solar Thermal Energy

In this paper we propose a novel CO2-recovering hybrid solar-fossil combined cycle with the integration of methane-fueled chemical-looping combustion, and investigate the system with the aid of the Energy-Utilization Diagram (EUD). Chemical-looping combustion (CLC) consists of two successive reactions: first, methane fuel is oxidized by metal oxide(NiO)as an oxygen carrier (reduction of metal oxide); and second, the reduced metal (Ni) is successively oxidized by combustion air (the oxidation of metal). The oxidation of methane with NiO requires a relative low-grade thermal energy at 300°C-500°C. Then concentrated solar thermal energy at approximately 450°C-550°C can be utilized to provide the process heat for this reaction. By coupling solar thermal energy with methane-fueled chemical-looping combustion, the energy level of solar thermal energy at around 450°C-550°C can be upgraded to the chemical energy of solid fuel Ni for better utilization of solar energy to generate electricity. The synergistic integration of solar thermal energy and chemical-looping combustion could make the exergy efficiency and the net solar-to-electric efficiency of the solar hybrid system more than 60% and 30%, respectively, at a turbine inlet temperature (TIT) of 1200°C. At the same time, this new system has an extremely important advantage of directly suppressing the environmental impact due to lack of energy penalty for CO2 recovery. Approximately 9–15 percentage points higher efficiency can be achieved compared to the conventional natural gas-fired combined cycle with CO2 separation. The results obtained here are promising and indicate that this novel solar hybrid combined cycle offers the new possibility of CO2 mitigation using both green energy and fossil fuels. These results also provide a new approach for highly efficient use of solar thermal energy to generate electricity.

Pyrazolium Phase Change Materials for Solar-Thermal and Wind Energy Storage

2019 ◽  
Author(s):  
Karolina Matuszek ◽  
R. Vijayaraghavan ◽  
Craig Forsyth ◽  
Surianarayanan Mahadevan ◽  
Mega Kar ◽  
...  
Keyword(s):  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Phase Change Materials ◽  
High Efficiency ◽  
Scale Up ◽  
Solar Thermal ◽  
Energy Storage Materials ◽  
Solar Thermal Energy ◽  
Storage Materials

Renewable energy has the ultimate capacity to resolve the environmental and scarcity challenges of the world’s energy supplies. However, both the utility of these sources and the economics of their implementation are strongly limited by their intermittent nature; inexpensive means of energy storage therefore needs to be part of the design. Distributed thermal energy storage is surprisingly underdeveloped in this context, in part due to the lack of advanced storage materials. Here, we describe a novel family of thermal energy storage materials based on pyrazolium cation, that operate in the 100-220°C temperature range, offering safe, inexpensive capacity, opening new pathways for high efficiency collection and storage of both solar-thermal energy, as well as excess wind power. We probe the molecular origins of the high thermal energy storage capacity of these ionic materials and demonstrate extended cycling that provides a basis for further scale up and development.

Efficient Co-Harvesting of Solar Energy and Low-Grade Heat by Molecular Photoswitches for High Energy Density, Long-Term Stable Solar Thermal Battery

2019 ◽  
Author(s):  
Zhao-Yang Zhang ◽  
Tao LI
Keyword(s):  
Energy Density ◽  
Solar Energy ◽  
High Performance ◽  
High Energy ◽  
Solar Thermal ◽  
High Energy Density ◽  
Low Grade ◽  
Thermal Battery ◽  
Low Grade Heat

Solar energy and ambient heat are two inexhaustible energy sources for addressing the global challenge of energy and sustainability. Solar thermal battery based on molecular switches that can store solar energy and release it as heat has recently attracted great interest, but its development is severely limited by both low energy density and short storage stability. On the other hand, the efficient recovery and upgrading of low-grade heat, especially that of the ambient heat, has been a great challenge. Here we report that solar energy and ambient heat can be simultaneously harvested and stored, which is enabled by room-temperature photochemical crystal-to-liquid transitions of small-molecule photoswitches. The two forms of energy are released together to produce high-temperature heat during the reverse photochemical phase change. This strategy, combined with molecular design, provides high energy density of 320-370 J/g and long-term storage stability (half-life of about 3 months). On this basis, we fabricate high-performance, flexible film devices of solar thermal battery, which can be readily recharged at room temperature with good cycling ability, show fast rate of heat release, and produce high-temperature heat that is >20<sup> o</sup>C higher than the ambient temperature. Our work opens up a new avenue to harvest ambient heat, and demonstrate a feasible strategy to develop high-performance solar thermal battery.

Efficient Co-Harvesting of Solar Energy and Low-Grade Heat by Molecular Photoswitches for High Energy Density, Long-Term Stable Solar Thermal Battery

2019 ◽  
Author(s):  
Zhao-Yang Zhang ◽  
Tao LI
Keyword(s):  
Energy Density ◽  
Solar Energy ◽  
High Performance ◽  
High Energy ◽  
Solar Thermal ◽  
High Energy Density ◽  
Low Grade ◽  
Thermal Battery ◽  
Low Grade Heat

Solar energy and ambient heat are two inexhaustible energy sources for addressing the global challenge of energy and sustainability. Solar thermal battery based on molecular switches that can store solar energy and release it as heat has recently attracted great interest, but its development is severely limited by both low energy density and short storage stability. On the other hand, the efficient recovery and upgrading of low-grade heat, especially that of the ambient heat, has been a great challenge. Here we report that solar energy and ambient heat can be simultaneously harvested and stored, which is enabled by room-temperature photochemical crystal-to-liquid transitions of small-molecule photoswitches. The two forms of energy are released together to produce high-temperature heat during the reverse photochemical phase change. This strategy, combined with molecular design, provides high energy density of 320-370 J/g and long-term storage stability (half-life of about 3 months). On this basis, we fabricate high-performance, flexible film devices of solar thermal battery, which can be readily recharged at room temperature with good cycling ability, show fast rate of heat release, and produce high-temperature heat that is >20<sup> o</sup>C higher than the ambient temperature. Our work opens up a new avenue to harvest ambient heat, and demonstrate a feasible strategy to develop high-performance solar thermal battery.

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