Fuel Property Effects on the Fate of Volume Distributed Combustion

Author(s):  
Ahmed E. E. Khalil ◽  
Ashwani K. Gupta

Colorless Distributed Combustion (CDC) has been shown to provide singular benefits on ultra-low pollutants emission, enhanced stability and thermal field uniformity. To achieve CDC conditions, fuel-air mixture must be properly prepared and mixed with hot reactive gases from within the combustor prior to the mixture ignition. Hot reactive gases reduce the oxygen concentration in the mixture while increasing its temperature. In this paper, the impact of fuel type (methane, propane, and hydrogen enriched methane) on achieving distributed combustion is investigated. A mixture of nitrogen and carbon dioxide was mixed to simulate the hot recirculated gases at different temperatures using normal air upstream of the combustor. Increasing the amounts of nitrogen and carbon dioxide reduced the oxygen concentration within the combustor. Distributed combustion was identified through OH* chemiluminescence distribution across the combustor. For methane, this oxygen concentration varied between 13.8% and 11.2% (depending on the mixture temperature) with some 85% reduction in NO emissions as compared to that without entrainment. Similar behavior was demonstrated with propane and hydrogen enriched methane, albeit at a lower oxygen concentration (13.7%–11.6% and 12.2%–10.5%), to result in 94% and 92% reduction in NO emission, respectively. The inlet gas temperature was varied between 300K and 750K. Experimental data using a variety of fuels showed NO emissions of 1 PPM or less. Analysis and extrapolation of obtained data suggest that distributed combustion can be achieved at an oxygen concentration of 9.5% for hot reactive entrained gases having a temperature of 1800K. This value may be used as a guideline to achieve distributed combustion with ultra-low emission.

Author(s):  
Ahmed E. E. Khalil ◽  
Ashwani K. Gupta

Colorless Distributed Combustion (CDC) has been shown to provide ultra-low emissions and enhanced combustion performance of high intensity gas turbine combustors in terms of efficiency and stability. To achieve distributed combustion, the flowfield needs to be carefully tailored for adequate mixing between reactants and hot reactive species from within the combustor to result in high temperature low oxygen concentration environment prior to ignition. Such distributed reactions result in uniform thermal field and also eliminates any hot spots for mitigating NOx emission. Though Distributed Combustion have been extensively studied using a variety of geometries, injection velocities, heat release intensities, and fuels, the role of hot reactive internally recirculated gases requires further examination. In this paper, the impact of internal entrainment of reactive gases on flame structure and behavior is investigated with focus on fostering distributed combustion and providing guidelines for designing high intensity combustors operating in distributed combustion mode. A mixture of nitrogen and carbon dioxide, used to simulate the recirculated gases, is introduced to the air stream prior to mixing with the fuel and subsequent combustion. Increase in the amounts of nitrogen and carbon dioxide (simulating increased entrainment), led to volume distributed reaction over a larger volume in the combustor with enhanced and uniform distribution of the OH* chemiluminescence intensity. At the same time, the bluish flame stabilized by the swirler is replaced with a more uniform almost invisible bluish flame. The increased recirculation also reflected on the pollutants emission, where NO emissions were significantly decreased for the same amount of fuel burned. Lowering oxygen concentration from 21% to 15% (due to increased entrainment) resulted in 80∼90% reduction in NO with no impact on CO emission with sub PPM NO emission achieved at an equivalence ratio of 0.7. The same trend was seen at higher diluents injection temperature as well, with significant pollutants emission reduction down to an oxygen concentration of 10%.


Author(s):  
Ahmed E. E. Khalil ◽  
Ashwani K. Gupta

Colorless Distributed Combustion (CDC) has been shown to provide unique benefits on ultra-low pollutants emission, enhanced combustion stability, and thermal field uniformity. To achieve CDC conditions, fuel-air mixture must be properly prepared and mixed with hot reactive gases from within the combustor prior to the mixture ignition. The hot reactive gases reduce the oxygen concentration in the mixture while increasing its temperature, resulting in a reaction zone that is distributed across the reactor volume, with lower reaction rate to result in the same fuel consumption. The conditions to achieve distributed combustion were previously studied using methane and other fuels with focus on pollutants emission and thermal field uniformity. In this paper, the impact of distributed combustion on noise reduction and increased stability is investigated. Such reduced noise is critical in mitigating the coupling between flame and heat release perturbations and acoustic signal to enhance the overall flame stability and reduce the propensity of flame instabilities which can cause equipment failure. Nitrogen-carbon dioxide mixture is used to simulate the reactive entrained gases from with the combustor. Increasing the amounts of nitrogen and carbon dioxide reduced the oxygen concentration within the oxidizing mixture, fostering distributed combustion. Upon achieving distributed combustion, the overall flame noise signature decreased from 80 dB to only 63 dB, as the flame transitioned from traditional swirl flame to distributed combustion. The flow noise under these conditions was 54 dB, indicating that distributed combustion has only 9 dB increase over isothermal case as compared to 26 dB for standard swirl flame. In addition, the dominant flame frequency around 490Hz disappeared under distributed combustion. For the traditional swirl flame, both the acoustic signal and heat release fluctuations (detected through CH∗ chemiluminescence) had a peak around 150Hz, indicating coupling between the heat release fluctuations and pressure variation. However, upon transitioning to distributed combustion, this common peak disappeared, outlining the enhanced stability of distributed combustion as there is no feedback between the heat release fluctuations and the recorded acoustic signal.


Author(s):  
Ahmed E. E. Khalil ◽  
Ashwani K. Gupta

Colorless Distributed Combustion (also referred to as CDC) has been shown to provide ultra-low emissions and enhanced performance of high intensity gas turbine combustors. To achieve distributed combustion, the flowfield needs to be tailored for adequate mixing between reactants and hot reactive species from within the combustor to result in high temperature low oxygen concentration environment prior to ignition. Such reaction distribution results in uniform thermal field and also eliminates any hot spots for mitigating NOx emission. Though CDC have been extensively studied using a variety of geometries, heat release intensities, and fuels, the role of internally recirculated hot reactive gases needs to be further investigated and quantified. In this paper, the impact of internal entrainment of reactive gases on flame structure and behavior is investigated with focus on fostering distributed combustion and providing guidelines for designing future gas turbine combustors operating in distributed combustion mode. To simulate the recirculated gases from within the combustor, a mixture of nitrogen and carbon dioxide is introduced to the air stream prior to mixing with fuel and subsequent combustion. Increase in the amounts of nitrogen and carbon dioxide (simulating increased entrainment), led to volume distributed reaction over a larger volume in the combustor with enhanced and uniform distribution of the OH* chemiluminescence intensity. At the same time, the bluish flame stabilized by the swirler is replaced with a more uniform almost invisible bluish flame. The increased recirculation also reflected on the pollutants emission, where NO emissions were significantly decreased for the same amount of fuel burned. Lowering oxygen concentration from 21% to 15% (due to increased recirculation) resulted in 80∼90% reduction in NO with no impact on CO emission with sub PPM NO emission achieved at an equivalence ratio of 0.7. Flame stabilization at excess recirculation can be achieved using preheated nitrogen and carbon dioxide, achieving true distributed conditions with oxygen concentration below 13%.


Author(s):  
Francislene Angelotti ◽  
Laise Guerra Barbosa ◽  
Juliane Rafaele Alves Barros ◽  
Carlos Antonio Fernandes dos Santos

ABSTRACT The increase of CO2 concentrations and temperatures may affect the plant development and production. This study aimed to evaluate the impact of the increased temperature and carbon dioxide concentration on the development of cowpea cultivars. The experiment was conducted in growth chambers, with control of CO2 and temperature. A completely randomized design was carried out, in a 4 x 3 x 2 factorial arrangement [cultivar x temperature (day/night) x CO2], with three replicates. The duration of the cowpea vegetative and reproductive phases was evaluated and, at the end of the experiment, the number of pods per plant, number of grains per pod, seed weight, shoot fresh and dry matter weight were quantified. Temperature affects the development of cowpea cultivars, and the temperatures of 29 ºC (day)/23 ºC (night) lead to a higher seed weight. The increase of CO2 leads to a higher number of pods and seeds and seed weight. The BRS Tapaihum cultivar presented the highest number of pods and seeds and seed weight. In addition, the temperatures of 32 ºC (day)/29 ºC (night) lead to a greater flower abortion in the BRS Pujante and BRS Tapaihum cultivars.


2013 ◽  
Vol 12 (7) ◽  
pp. 451-459
Author(s):  
Ashraf Yehia El-Naggar ◽  
Mohamed A. Ebiad

Gasoline come primarily from petroleum cuts, it is the preferred liquid fuel in our lives. Two gasoline samples of octane numbers 91 and 95 from Saudi Arabia petrol stations were studied. This study was achieved at three different temperatures 20oC, 30oC and 50oC representing the change in temperatures of the different seasons of the year. Both the evaporated gases of light aromatic hydrocarbons (BTEX) of gasoline samples inside the tank were subjected to analyze qualitatively and quantitatively via capillary gas chromatography. The detailed hydrocarbon composition and the octane number of the studied gasoline samples were determined using detailed hydrocarbon analyzer. The idea of research is indicating the impact of light aromatic compounds in gasoline on the toxic effect of human and environment on the one hand, and on octane number of gasoline on the other hand. Although the value of octane number will be reduced but this will have a positive impact on the environment as a way to produce clean fuel.


Author(s):  
S. A. Lysenko

The spatial and temporal particularities of Normalized Differential Vegetation Index (NDVI) changes over territory of Belarus in the current century and their relationship with climate change were investigated. The rise of NDVI is observed at approximately 84% of the Belarus area. The statistically significant growth of NDVI has exhibited at nearly 35% of the studied area (t-test at 95% confidence interval), which are mainly forests and undeveloped areas. Croplands vegetation index is largely descending. The main factor of croplands bio-productivity interannual variability is precipitation amount in vegetation period. This factor determines more than 60% of the croplands NDVI dispersion. The long-term changes of NDVI could be explained by combination of two factors: photosynthesis intensifying action of carbon dioxide and vegetation growth suppressing action of air warming with almost unchanged precipitation amount. If the observed climatic trend continues the croplands bio-productivity in many Belarus regions could be decreased at more than 20% in comparison with 2000 year. The impact of climate change on the bio-productivity of undeveloped lands is only slightly noticed on the background of its growth in conditions of rising level of carbon dioxide in the atmosphere.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Aiyan Guan ◽  
Inge Van Damme ◽  
Frank Devlieghere ◽  
Sarah Gabriël

AbstractAnisakidae, marine nematodes, are underrecognized fish-borne zoonotic parasites. Studies on factors that could trigger parasites to actively migrate out of the fish are very limited. The objective of this study was to assess the impact of different environmental conditions (temperature, CO2 and O2) on larval motility (in situ movement) and mobility (migration) in vitro. Larvae were collected by candling or enzymatic digestion from infected fish, identified morphologically and confirmed molecularly. Individual larvae were transferred to a semi-solid Phosphate Buffered Saline agar, and subjected to different temperatures (6 ℃, 12 ℃, 22 ℃, 37 ℃) at air conditions. Moreover, different combinations of CO2 and O2 with N2 as filler were tested, at both 6 °C and 12 °C. Video recordings of larvae were translated into scores for larval motility and mobility. Results showed that temperature had significant influence on larval movements, with the highest motility and mobility observed at 22 ℃ for Anisakis spp. larvae and 37 ℃ for Pseudoterranova spp. larvae. During the first 10 min, the median migration of Anisakis spp. larvae was 10 cm at 22 ℃, and the median migration of Pseudoterranova spp. larvae was 3 cm at 37 ℃. Larval mobility was not significantly different under the different CO2 or O2 conditions at 6 °C and 12 ℃. It was concluded that temperature significantly facilitated larval movement with the optimum temperature being different for Anisakis spp. and Pseudoterranova spp., while CO2 and O2 did not on the short term. This should be further validated in parasite-infected/spiked fish fillets.


2021 ◽  
Vol 21 (2) ◽  
Author(s):  
Hadi Torkamani ◽  
Shahram Raygan ◽  
Carlos Garcia Mateo ◽  
Yahya Palizdar ◽  
Jafar Rassizadehghani ◽  
...  

AbstractIn this study, dual-phase (DP, ferrite + martensite) microstructures were obtained by performing intercritical heat treatments (IHT) at 750 and 800 °C followed by quenching. Decreasing the IHT temperature from 800 to 750 °C leads to: (i) a decrease in the volume fraction of austenite (martensite after quenching) from 0.68 to 0.36; (ii) ~ 100 °C decrease in martensite start temperature (Ms), mainly due to the higher carbon content of austenite and its smaller grains at 750 °C; (iii) a reduction in the block size of martensite from 1.9 to 1.2 μm as measured by EBSD. Having a higher carbon content and a finer block size, the localized microhardness of martensite islands increases from 380 HV (800 °C) to 504 HV (750 °C). Moreover, despite the different volume fractions of martensite obtained in DP microstructures, the hardness of the steels remained unchanged by changing the IHT temperature (~ 234 to 238 HV). Applying lower IHT temperature (lower fraction of martensite), the impact energy even decreased from 12 to 9 J due to the brittleness of the martensite phase. The results of the tensile tests indicate that by increasing the IHT temperature, the yield and ultimate tensile strengths of the DP steel increase from 493 to 770 MPa, and from 908 to 1080 MPa, respectively, while the total elongation decreases from 9.8 to 4.5%. In contrast to the normalized sample, formation of martensite in the DP steels could eliminate the yield point phenomenon in the tensile curves, as it generates free dislocations in adjacent ferrite.


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