The Effect of Magnetic Fields on Corrosion in Pipeline Steel

2007 ◽  
Author(s):  
Joshua E. Jackson ◽  
Angelique N. Lasseigne-Jackson ◽  
David L. Olson ◽  
Brajendra Mishra ◽  
Meredith S. Heilig ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Magnetic Fields ◽  
Hydrogen Content ◽  
Electrochemical Impedance ◽  
Pipeline Steel ◽  
Cold Work ◽  
Passive Layer ◽  
Laboratory Research ◽  
Electromagnetic Current

Measurements performed in earlier research have indicated a strong effect of magnetization on hydrogen content (thermodynamics) as well as cracking, and pitting (kinetics) in pipeline steels as described in Sanchez (2005) and Sanchez et al. (2005). The effect of cold work, further increasing hydrogen content, cracking, and pitting, was also assessed. Theoretical descriptions of both thermodynamic and kinetic interpretations of the observed effect is described and correlated to observed results. There are two ways that electromagnetic current influences corrosion: (1) D/C currents (under applied or Remanent magnetic fields) and A/C electric currents (which create electromagnetic fields through Lenz’s Law) may influence magnetocorrosion as described in this paper, and (2) A/C currents also have the potential to strip the protective passive layer from materials and greatly accelerate corrosion. Electrochemical charging is currently being performed at varied magnetic field strengths to assess the nature of the observed influence of magnetization on both hydrogen content (thermodynamic) and cracking/pitting (kinetic), including the role of controlled-roll cold working. Naval and maritime use of A/C and D/C electric-powered systems including propulsion drives, servos, and controls, is increasing rapidly in sea-going operation and potential for stray currents is an increasing risk. Magnetic flux leakage inspection, using saturating magnetic fields, is widely used for reliable and accurate inspection of pipeline corrosion and wall thickness. Previous laboratory research shows a significant increase in both pipeline steel hydrogen content in steel and pitting and cracking after electrochemical hydrogen charging under an applied two Tesla magnetic field. Cold work was observed to further increase the observed effects. The thermodynamic auxiliary functions, using a derivation of Helmholtz free energy, are examined to assess the thermodynamic effects of magnetization on hydrogen content. The effect of magnetization on the thermodynamics of electron spin configurations, interstitial solute-induced strain, magnetostriction (directional strain induced in steel from an applied magnetic field) are considered. Kinetic interpretations of possible interactions with the Helmholtz Double (capacitor-like) Layer and the Gouy-Chapman (diffuse) layer that may lead to increased diffusion and thus to hydrogen supersaturation are described. Electrochemical impedance measurements are being performed to assess the influence of applied magnetic fields on the Helmholtz and Gouy-Chapman layers.

scholarly journals Modeling of magneto-conductivity of bismuth selenide: a topological insulator

2021 ◽  
Vol 3 (4) ◽  
Author(s):  
Yogesh Kumar ◽  
Rabia Sultana ◽  
Prince Sharma ◽  
V. P. S. Awana
Keyword(s):  
Magnetic Field ◽  
Magnetic Fields ◽  
Single Crystal ◽  
Single Crystals ◽  
X Ray Diffraction ◽  
Field Range ◽  
X Ray ◽  
Bulk Carriers ◽  
Different Temperatures

AbstractWe report the magneto-conductivity analysis of Bi2Se3 single crystal at different temperatures in a magnetic field range of ± 14 T. The single crystals are grown by the self-flux method and characterized through X-ray diffraction, Scanning Electron Microscopy, and Raman Spectroscopy. The single crystals show magnetoresistance (MR%) of around 380% at a magnetic field of 14 T and a temperature of 5 K. The Hikami–Larkin–Nagaoka (HLN) equation has been used to fit the magneto-conductivity (MC) data. However, the HLN fitted curve deviates at higher magnetic fields above 1 T, suggesting that the role of surface-driven conductivity suppresses with an increasing magnetic field. This article proposes a speculative model comprising of surface-driven HLN and added quantum diffusive and bulk carriers-driven classical terms. The model successfully explains the MC of the Bi2Se3 single crystal at various temperatures (5–200 K) and applied magnetic fields (up to 14 T).

scholarly journals Temperature-Induced Plasmon Excitations for the α–T3 Lattice in Perpendicular Magnetic Field

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1720
Author(s):  
Antonios Balassis ◽  
Godfrey Gumbs ◽  
Oleksiy Roslyak
Keyword(s):  
Magnetic Field ◽  
Magnetic Fields ◽  
Zeeman Splitting ◽  
Mass Term ◽  
Energy Dispersive Spectrum ◽  
Wave Functions ◽  
Transition Energies ◽  
Gap Opening ◽  
Quantizing Magnetic Field

We have investigated the α–T3 model in the presence of a mass term which opens a gap in the energy dispersive spectrum, as well as under a uniform perpendicular quantizing magnetic field. The gap opening mass term plays the role of Zeeman splitting at low magnetic fields for this pseudospin-1 system, and, as a consequence, we are able to compare physical properties of the the α–T3 model at low and high magnetic fields. Specifically, we explore the magnetoplasmon dispersion relation in these two extreme limits. Central to the calculation of these collective modes is the dielectric function which is determined by the polarizability of the system. This latter function is generated by transition energies between subband states, as well as the overlap of their wave functions.

Role of chromium in anomalous behaviour of the passive layer in Ni-Cr-Mo alloys in 1M HCl solution

CORROSION ◽  
10.5006/3767 ◽  
2022 ◽  
Author(s):  
Malvika Karri ◽  
Amit Verma ◽  
J.B. Singh ◽  
Sunil Kumar Bonagani ◽  
U.K. Goutam
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Corrosion Behaviour ◽  
Underlying Mechanism ◽  
Passive Layer ◽  
X Ray ◽  
Superior Corrosion Resistance ◽  
Hcl Solution ◽  
Cr2o3 Layer

This work seeks to understand the underlying mechanism involved in passivity of Ni-Cr-Mo alloys in a less concentrated HCl solution (1M) by systematically varying contents of Cr and Mo solutes in model Ni-Cr-Mo alloys. Corrosion behaviour was evaluated based on potentiodynamic polarisation tests carried out in conjunction with electrochemical impedance and x-ray photoelectron spectroscopies of passive films that formed on alloys during their exposure to the HCl solution. Results have shown that an increase in Mo alone is not sufficient to improve the corrosion resistance of the alloys at lower concentrations of HCl. Optimum concentrations of Cr and Mo solutes have been found to be in the vicinity of ~17 wt.% Cr and ~19 wt.% Mo for superior corrosion resistance of the alloys. This was attributed to the protection of the Cr2O3 layer as a consequence of the enrichment of Mo6+ ions in the passive film in 1M HCl solution.

scholarly journals Doppler Images of Rapidly Rotating Ap Stars

1988 ◽  
Vol 132 ◽  
pp. 199-204
Author(s):  
Artie P. Hatzes
Keyword(s):  
Magnetic Field ◽  
Magnetic Fields ◽  
Stellar Surface ◽  
Surface Distribution ◽  
Distribution Of Elements ◽  
Local Equivalent ◽  
Field Geometry ◽  
A New Technique ◽  
Ap Stars

The magnetic Ap stars are characterized by the presence of large magnetic fields which undergo periodic variations. These magnetic field variations are accompanied by spectral variations caused by the inhomogeneous distribution of elements on the stellar surface. It is believed that the magnetic field plays an important role in determining this distribution. Accurate maps of the surface distribution of elements would provide valuable probes as to the field geometry as well as provide clues to the role of the magnetic fields in the atmospheres of these stars. We have developed a new technique for mapping the local equivalent width on a stellar surface from the observed spectral line variations.

Magnetic Fields and Disks in Star-forming Regions

1993 ◽  
Vol 10 (3) ◽  
pp. 247-249 ◽  
Author(s):  
C.M. Wright ◽  
D.K. Aitken ◽  
C.H. Smith ◽  
P.F. Roche
Keyword(s):  
Magnetic Field ◽  
Magnetic Fields ◽  
Transverse Component ◽  
Young Stellar Objects ◽  
Stellar Objects ◽  
Star Forming ◽  
Star Forming Regions ◽  
Molecular Outflow ◽  
The Magnetic Field

AbstractThe star-formation process is an outstanding and largely unsolved problem in astrophysics. The role of magnetic fields is unclear but is widely considered to be important at all stages of protostellar evolution, from cloud collapse to ZAMS. For example, in some hydromagnetic models, the field may assist in removing angular momentum, thereby driving accretion and perhaps bipolar outflows.Spectropolarimetry between 8 and 13μm provides information on the direction of the transverse component of a magnetic field through the alignment of dust grains. We present results of 8–13μm spectropolarimetric observations of a number of bipolar molecular outflow sources, and compare the field directions observed with the axes of the outflows and putative disk-like structures observed to be associated with some of the objects. There is a strong correlation, though so far with limited statistics, between the magnetic field and disk orientations. We compare our results with magnetic field configurations predicted by current models for hydromagnetically driven winds from the disks around Young Stellar Objects (YSOs). Our results appear to argue against the Pudritz and Norman model and instead seem to support the Uchida and Shibata model.

scholarly journals Oscillatory convection in strong magnetic fields and origin of active regions

1968 ◽  
Vol 35 ◽  
pp. 127-130 ◽  
Author(s):  
S. I. Syrovatsky ◽  
Y. D. Zhugzhda
Keyword(s):  
Magnetic Field ◽  
Magnetic Fields ◽  
Active Regions ◽  
Oscillatory Convection ◽  
Strong Magnetic Fields ◽  
Various Boundary Conditions ◽  
Convective Cells ◽  
The Magnetic Field ◽  
Polytropic Atmosphere

The convection in a compressible inhomogeneous conducting fluid in the presence of a vertical uniform magnetic field has been studied. It is shown that a new mode of oscillatory convection occurs, which exists in arbitrarily strong magnetic fields. The convective cells are stretched along the magnetic field, their horizontal dimensions are determined by radiative cooling. Criteria for convective instability in a polytropic atmosphere are obtained for various boundary conditions in the case when the Alfvén velocity is higher compared with the velocity of sound.The role of oscillatory convection in the origin of sunspots and active regions is discussed.

scholarly journals The Role of Magnetic Fields in Star Forming Regions

1990 ◽  
Vol 140 ◽  
pp. 259-267
Author(s):  
L Mestel
Keyword(s):  
Magnetic Field ◽  
Star Formation ◽  
Magnetic Fields ◽  
The Self ◽  
Galactic Magnetic Field ◽  
Star Forming ◽  
Star Forming Regions

The flux from the galactic magnetic field alters radically the appropriate description of the equilibrium, collapse and fragmentation of the self-gravitating gas clouds that are the locale of star formation.

scholarly journals Studies on Pitting Corrosion of Al–Cu–Li Alloys Part III: Passivation Kinetics of AA2098–T851 Based on the Point Defect Model

Materials ◽  
2019 ◽  
Vol 12 (12) ◽  
pp. 1912 ◽  
Author(s):  
Elmira Ghanbari ◽  
Alireza Saatchi ◽  
Xiaowei Lei ◽  
Digby D. Macdonald
Keyword(s):  
Barrier Layer ◽  
Potential Model ◽  
Electrochemical Impedance ◽  
Passive Layer ◽  
Charge Carriers ◽  
Theoretical Interpretation ◽  
Defect Model ◽  
Kinetics Of Formation ◽  
Kinetics Of

In this paper, the passivation kinetics of AA2098–T851 was investigated by a fundamental theoretical interpretation of experimental results based on the mixed potential model (MPM). The steady state passive layer formed on the AA2098–T851 in NaHCO3 solution in a CO2 atmosphere upon potentiostatic stepping in the anodic direction followed by stepping in the opposite direction was explored. Potentials were selected in a way that both anodic passive dissolution of the metal and hydrogen evolution reaction (HER) occur, thereby requiring the MPM for interpretation. Optimization of the MPM on the experimental electrochemical impedance spectroscopy (EIS) data measured after each potentiostatic step revealed the important role of the migration of Al interstitials in determining the kinetics of passive layer formation and dissolution. More importantly, it is shown that the inequalities of the kinetics of formation and dissolution of the passive layer as observed in opposite potential stepping directions lead to the irreversibility of the passivation process. Finally, by considering the Butler–Volmer (B–V) equation for the cathodic reaction (HER) in the MPM, and assuming the quantum mechanical tunneling of the charge carriers across the barrier layer of the passive film, it was shown that the HER was primarily controlled by the slow electrochemical discharge of protons at the barrier layer/solution (outer layer) interface.

scholarly journals ALMA reveals the coherence of the magnetic field geometry in OH 231.8+4.2

2020 ◽  
Vol 495 (4) ◽  
pp. 4297-4305
Author(s):  
L Sabin ◽  
R Sahai ◽  
W H T Vlemmings ◽  
Q Zhang ◽  
A A Zijlstra ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Magnetic Fields ◽  
Dust Emission ◽  
Polarization Data ◽  
Central System ◽  
Emission Analysis ◽  
Intermediate Mass Stars ◽  
Field Geometry ◽  
The Magnetic Field

ABSTRACT In a continuing effort to investigate the role of magnetic fields in evolved low- and intermediate-mass stars (principally regarding the shaping of their envelopes), we present new Atacama Large Millimeter/submillimeter Array (ALMA) high-resolution polarization data obtained for the nebula OH 231.8+4.2. We found that the polarized emission likely arises from aligned grains in the presence of magnetic fields rather than radiative alignment and self-scattering. The ALMA data show well organized electric field orientations in most of the nebula and the inferred magnetic field vectors (rotated by 90°) trace an hourglass morphology centred on the central system of the nebula. One region in the southern part of OH 231.8+4.2 shows a less organized distribution probably due to the shocked environment. These findings, in conjunction with earlier investigations (maser studies and dust emission analysis at other scales and wavelengths) suggest an overall magnetic hourglass located inside a toroidal field. We propose the idea that the magnetic field structure is closely related to the architecture of a magnetic tower and that the outflows were therefore magnetically launched. While the current dynamical effect of the fields might be weak in the equatorial plane principally due to the evolution of the envelope, it would still be affecting the outflows. In that regard, the measurement of the magnetic field at the stellar surface, which is still missing, combined with a full magnetohydrodynamic treatment are required to better understand and constrain the events occurring in OH 231.8+4.2.

V. Heating and Dynamics of Chromosphere and Corona

1988 ◽  
Vol 20 (1) ◽  
pp. 100-102
Author(s):  
G.E. Brueckner
Keyword(s):  
Magnetic Field ◽  
Magnetic Fields ◽  
Acoustic Waves ◽  
Convection Zone ◽  
Flux Tubes ◽  
Magnetic Structures ◽  
Convective Motions ◽  
Field Lines ◽  
The Magnetic Field

The crucial role of magnetic fields in any mechanism to heat the outer solar atmosphere has been generally accepted by all authors. However, there is still no agreement about the detailed function of the magnetic field. Heating mechanisms can be divided up into 4 classes: (I) The magnetic field plays a passive role as a suitable medium for the propagation of Alfvén waves from the convection zone into the corona (Ionson, 1984). (II) In closed magnetic structures the slow random shuffling of field lines by convective motions below the surface induces electric currents in the corona which heat it by Joule dissipation (Heyvaerts and Priest, 1984). (Ill) Emerging flux which is generated in the convection zone reacts with ionized material while magnetic field lines move through the chromosphere, transition zone and corona. Rapid field line annihilation, reconnection and drift currents result in heating and material ejection (Brueckner, 1987; Brueckner et al., 1987; Cook et al., 1987). (IV) Acoustic waves which could heat the corona can be guided by magnetic fields. Temperature distribution, wave motions and shock formation are highly dependent on the geometry of the flux tubes (Ulmschneider and Muchmore, 1986; Ulmschneider, Muchmore and Kalkofen, 1987).

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