Experimental Study of Dissolution Rate of a CO2 Droplet and CO2 Solubility in High Pressure and Low Temperature Seawater With Hydrate Free

2004 ◽  
Author(s):  
Yongchen Song ◽  
Baixin Chen ◽  
Masahiro Nishio ◽  
Makato Akai
Keyword(s):  
Hydrate Formation ◽  
Co2 Concentration ◽  
Co2 Solubility ◽  
Dual Nature ◽  
Thermodynamic State ◽  
Complete Condition ◽  
Fundamental Relationship ◽  
Co2 Ocean Sequestration ◽  
Carbon Dioxide Co2 ◽  
Ocean Sequestration

Against the background of carbon dioxide (CO2) ocean sequestration technology, we investigated the solubility of CO2 in seawater at a thermodynamic state similar to that at an ocean depth of 1000 m. The experiment was performed in two steps. In the first step, we reexamined and modified the fundamental relationship between Sherwood (Sh) number and Rayleigh (Ra) number in a natural convective flow over an up-down CO2 droplet. We derived a new expression of the Grashof number for CO2 dissolution in water and seawater with the aid of the relation between the density of CO2 solution and CO2 concentration. In the second step, this new expression was applied to the estimation of solubility of CO2 from experiments examining the dissolution of an individual CO2 droplet in seawater at hydrate-formable pressure and temperature states. We found from our experiments: that (1) at hydrate-formable conditions (step two), no hydrate appeared at interface between liquid CO2 and seawater throughout the experiments within 5 hours, which suggested that a thermodynamic state (pressure and temperature) is indispensable but not a complete condition for hydrate formation; and (2) associated with this dual nature, the data of CO2 solubility estimated from this experiment are much larger than those obtained by Kimuro et al [1] from experiments of hydrate coexistence. Our data ranged from 0.052 to 0.062 in mass fraction.

scholarly journals Determination of Dissolved CO2 Concentration in Culture Media: Evaluation of pH Value and Mathematical Data

Processes ◽  
2020 ◽  
Vol 8 (11) ◽  
pp. 1373
Author(s):  
Amir Izzuddin Adnan ◽  
Mei Yin Ong ◽  
Saifuddin Nomanbhay ◽  
Pau Loke Show
Keyword(s):  
Carbon Dioxide ◽  
Ph Value ◽  
Culture Media ◽  
Co2 Concentration ◽  
Co2 Solubility ◽  
Greenhouse Gasses ◽  
Dipotassium Phosphate ◽  
The Difference ◽  
Carbon Dioxide Co2

Carbon dioxide is the most influential gas in greenhouse gasses and its amount in the atmosphere reached 412 µmol/mol in August 2020, which increased rapidly, by 48%, from preindustrial levels. A brand-new chemical industry, namely organic chemistry and catalysis science, must be developed with carbon dioxide (CO2) as the source of carbon. Nowadays, many techniques are available for controlling and removing carbon dioxide in different chemical processes. Since the utilization of CO2 as feedstock for a chemical commodity is of relevance today, this study will focus on how to increase CO2 solubility in culture media used for growing microbes. In this work, the CO2 solubility in a different medium was investigated. Sodium hydroxide (NaOH) and monoethanolamine (MEA) were added to the culture media (3.0 g/L dipotassium phosphate (K2HPO4), 0.2 g/L magnesium chloride (MgCl2), 0.2 g/L calcium chloride (CaCl2), and 1.0 g/L sodium chloride (NaCl)) for growing microbes in order to observe the difference in CO2 solubility. Factors of temperature and pressure were also studied. The determination of CO2 concentration in the solution was measured by gas analyzer. The result obtained from optimization revealed a maximum CO2 concentration of 19.029 mol/L in the culture media with MEA, at a pressure of 136.728 kPa, operating at 20.483 °C.

scholarly journals The Synergistic Effect of PM2.5 and CO2 Concentrations on Occupant Satisfaction and Work Productivity in a Meeting Room

2021 ◽  
Vol 18 (8) ◽  
pp. 4109
Author(s):  
Jindong Wu ◽  
Jiantao Weng ◽  
Bing Xia ◽  
Yujie Zhao ◽  
Qiuji Song
Keyword(s):  
Air Quality ◽  
Synergistic Effect ◽  
Work Productivity ◽  
Co2 Concentration ◽  
Human Beings ◽  
Meeting Room ◽  
Negative Effect ◽  
Carbon Dioxide Co2 ◽  
Occupant Satisfaction ◽  
Pm2.5 Concentration

High indoor air quality is crucial for the health of human beings. The purpose of this work is to analyze the synergistic effect of particulate matter 2.5 (PM2.5) and carbon dioxide (CO2) concentration on occupant satisfaction and work productivity. This study carried out a real-scale experiments in a meeting room with exposures of up to one hour. Indoor environment parameters, including air temperature, relative humidity, illuminance, and noise level, were controlled at a reasonable level. Twenty-nine young participants were participated in the experiments. Four mental tasks were conducted to quantitatively evaluate the work productivity of occupants and a questionnaire was used to access participants’ satisfaction. The Spearman correlation analysis and two-way analysis of variance were applied. It was found that the overall performance declined by 1% for every 10 μg/m3 increase in PM2.5 concentration. Moreover, for every 10% increase in dissatisfaction with air quality, productivity performance decreased by 1.1% or more. It should be noted that a high CO2 concentration (800 ppm) has a stronger negative effect on occupant satisfaction towards air quality than PM2.5 concentration in a non-ventilated room. In order to obtain optimal occupant satisfaction and work productivity, low concentrations of PM2.5 (<50 μg/m3) and CO2 (<700 ppm) are recommended.

scholarly journals The Exploitation of Local Vitis vinifera L. Biodiversity as a Valuable Tool to Cope with Climate Change Maintaining Berry Quality

Plants ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 71
Author(s):  
María Carmen Antolín ◽  
María Toledo ◽  
Inmaculada Pascual ◽  
Juan José Irigoyen ◽  
Nieves Goicoechea
Keyword(s):  
Climate Change ◽  
Fruit Quality ◽  
Atmospheric Carbon Dioxide ◽  
Antioxidant Properties ◽  
Co2 Concentration ◽  
Soluble Solids ◽  
Vitis Vinifera L ◽  
Grape Quality ◽  
Berry Quality ◽  
Carbon Dioxide Co2

(1) Background: The associated increase in global mean surface temperature together with raised atmospheric carbon dioxide (CO2) concentration is exerting a profound influence on grapevine development (phenology) and grape quality. The exploitation of the local genetic diversity based on the recovery of ancient varieties has been proposed as an interesting option to cope with climate change and maintaining grape quality. Therefore, this research aimed to characterize the potential fruit quality of genotypes from seven local old grapevine varieties grown under climate change conditions. (2) Methods: The study was carried out on fruit-bearing cuttings (one cluster per plant) that were grown in pots in temperature gradient greenhouses (TGG). Two treatments were applied from fruit set to maturity: (1) ambient CO2 (400 ppm) and temperature (T) (ACAT) and (2) elevated CO2 (700 ppm) and temperature (T + 4 °C) (ECET). (3) Results: Results showed that some of the old genotypes tested remained quite stable during the climate change conditions in terms of fruit quality (mainly, total soluble solids and phenolic content) and of must antioxidant properties. (4) Conclusion: This research underlines the usefulness of exploiting local grapevine diversity to cope with climate change successfully, although further studies under field conditions and with whole plants are needed before extrapolating the results to the vineyard.

Consequences of CO2 solubility for hydrate formation from carbon dioxide containing water and other impurities

2014 ◽  
Vol 16 (18) ◽  
pp. 8623-8638 ◽  
Author(s):  
Bjørn Kvamme ◽  
Tatiana Kuznetsova ◽  
Bjørnar Jensen ◽  
Sigvat Stensholt ◽  
Jordan Bauman ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Water Content ◽  
Upper Bound ◽  
Hydrate Formation ◽  
Pipeline Transport ◽  
Co2 Solubility ◽  
Complex Issue ◽  
Dense Carbon Dioxide

Deciding on the upper bound of water content permissible in a stream of dense carbon dioxide under pipeline transport conditions without facing the risks of hydrate formation is a complex issue.

Correlations among the design factors of the CO2 ocean sequestration system, GLAD

Energy ◽  
2005 ◽  
Vol 30 (11-12) ◽  
pp. 2308-2317 ◽  
Author(s):  
Kentaro Niwa ◽  
Sanai Kosugi ◽  
Takayuki Saito ◽  
Takeo Kajishima ◽  
Kenji Hamaogi
Keyword(s):  
Co2 Ocean Sequestration ◽  
Ocean Sequestration ◽  
Design Factors

scholarly journals Effect of Graphene Nanoplatelet on the Carbonation Depth of Concrete under Changing Climate Conditions

2021 ◽  
Vol 11 (19) ◽  
pp. 9265
Author(s):  
Yingzi Zhang ◽  
Yanze Wang ◽  
Mingqian Yang ◽  
Huatao Wang ◽  
Guofang Chen ◽  
...  
Keyword(s):  
Control Sample ◽  
Co2 Concentration ◽  
Favorable Effect ◽  
Carbonation Depth ◽  
Graphene Nanoplatelet ◽  
Carbonation Reaction ◽  
Climate Conditions ◽  
Ordinary Concrete ◽  
Changing Climate ◽  
Carbon Dioxide Co2

Climate change has been unprecedented in the past decades or even thousands of years, which has had an adverse impact on the mechanical properties of concrete structures. Many researchers have begun to study new concrete materials. Graphene nanoplatelet (GNP) is an attractive nanomaterial that can change the crystal structure of concrete and improve durability. The aim of the present study was to investigate the effect of GNP (0.05%wt) on the carbonation depth of concrete under simulated changing climate conditions (varying temperature, relative humidity, and carbon dioxide (CO2) concentration), and compare it with ordinary concrete. When the concentration of CO2 is variable, the carbonation depth of graphene concrete is 10% to 20% lower than that of ordinary concrete. When the temperature is lower than 33 °C, the carbonation depth of graphene concrete is less than that of the control sample; however, above 33 °C, the thermal conductivity of GNP increases the carbonation reaction rate of concrete. When the humidity is a variable, the carbonation depth of graphene concrete is less than 15% to 30% of ordinary concrete, and when the humidity is higher than 78%, the difference in the carbonation depth between the ordinary concrete and the graphene concrete decreases gradually. The overall results indicated that GNP has a favorable effect on anti-carbonation performance under changing climate conditions.

scholarly journals Multi-Year Comparison of CO2 Concentration from NOAA Carbon Tracker Reanalysis Model with Data from GOSAT and OCO-2 over Asia

2020 ◽  
Vol 12 (15) ◽  
pp. 2498
Author(s):  
Farhan Mustafa ◽  
Lingbing Bu ◽  
Qin Wang ◽  
Md. Arfan Ali ◽  
Muhammad Bilal ◽  
...  
Keyword(s):  
Time Series ◽  
Spatial Distribution ◽  
Atmospheric Carbon Dioxide ◽  
Carbon Budget ◽  
Co2 Concentration ◽  
Mitigation Strategies ◽  
Spatial Correlations ◽  
Western Asia ◽  
Carbon Dioxide Co2 ◽  
Good Agreement

Accurate knowledge of the carbon budget on global and regional scales is critically important to design mitigation strategies aimed at stabilizing the atmospheric carbon dioxide (CO2) emissions. For a better understanding of CO2 variation trends over Asia, in this study, the column-averaged CO2 dry air mole fraction (XCO2) derived from the National Oceanic and Atmospheric Administration (NOAA) CarbonTracker (CT) was compared with that of Greenhouse Gases Observing Satellite (GOSAT) from September 2009 to August 2019 and with Orbiting Carbon Observatory 2 (OCO-2) from September 2014 until August 2019. Moreover, monthly averaged time-series and seasonal climatology comparisons were also performed separately over the five regions of Asia; i.e., Central Asia, East Asia, South Asia, Southeast Asia, and Western Asia. The results show that XCO2 from GOSAT is higher than the XCO2 simulated by CT by an amount of 0.61 ppm, whereas, OCO-2 XCO2 is lower than CT by 0.31 ppm on average, over Asia. The mean spatial correlations of 0.93 and 0.89 and average Root Mean Square Deviations (RMSDs) of 2.61 and 2.16 ppm were found between the CT and GOSAT, and CT and OCO-2, respectively, implying the existence of a good agreement between the CT and the other two satellites datasets. The spatial distribution of the datasets shows that the larger uncertainties exist over the southwest part of China. Over Asia, NOAA CT shows a good agreement with GOSAT and OCO-2 in terms of spatial distribution, monthly averaged time series, and seasonal climatology with small biases. These results suggest that CO2 can be used from either of the datasets to understand its role in the carbon budget, climate change, and air quality at regional to global scales.

scholarly journals Effect of Greenhouse CO2 Supplementation on Yield and Mineral Element Concentrations of Leafy Greens Grown Using Nutrient Film Technique

Agronomy ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 323 ◽  
Author(s):  
Hardeep Singh ◽  
Megha R. Poudel ◽  
Bruce L. Dunn ◽  
Charles Fontanier ◽  
Gopal Kakani
Keyword(s):  
Dry Weight ◽  
Co2 Concentration ◽  
Greenhouse Production ◽  
Leafy Greens ◽  
Greenhouse Study ◽  
Nutrient Film Technique ◽  
Swiss Chard ◽  
Photosynthetic Assimilation ◽  
Carbon Dioxide Co2 ◽  
Hydroponically Grown

Carbon dioxide (CO2) concentration is reported to be the most important climate variable in greenhouse production with its effect on plant photosynthetic assimilation. A greenhouse study was conducted using a nutrient film technique (NFT) system to quantify the effect of two different levels of CO2 (supplemented at an average of 800 ppm and ambient at ~410 ppm) on growth and nutritional quality of basil (Ocimum basilicum L.) ‘Cardinal’, lettuce (Lactuca sativa L.) ‘Auvona’, and Swiss chard (Beta vulgaris L.) ‘Magenta Sunset’ cultivars. Two identical greenhouses were used: one with CO2 supplementation and the other serving as the control with an ambient CO2 concentration. The results indicate that supplemented CO2 could significantly increase the height and width of hydroponically grown leafy greens. Supplemented CO2 increased the fresh weight of basil ‘Cardinal’, lettuce ‘Auvona’, and Swiss chard ‘Magenta Sunset’ by 29%, 24.7%, and 39.5%, respectively, and dry weight by 34.4%, 21.4%, and 40.1%, respectively. These results correspond to a significant reduction in Soil Plant Analysis Development (SPAD) and atLEAF values, which represent a decrease in leaf chlorophyll content under supplemented CO2 conditions. Chlorophyll, nitrogen (N), phosphorus (P), and magnesium (Mg) concentrations were generally lower in plants grown in supplemented CO2 conditions, but the results were not consistent for each species. Supplemented CO2 reduced tissue N concentration for basil ‘Cardinal’ and lettuce ‘Auvona’ but not Swiss chard, while Mg concentration was reduced in supplemented CO2 for Swiss chard ‘Magenta Sunset’ only. In contrast, Fe concentration was increased under supplemented CO2 for basil ‘Cardinal’ only. These findings suggest CO2 supplementation could increase yield of leafy greens grown with hydroponics and have varying impact on different mineral concentrations among species.

scholarly journals Indoor Environmental Quality Evaluation of Lecture Classrooms in an Institutional Building in a Cold Climate

2019 ◽  
Vol 11 (23) ◽  
pp. 6591 ◽  
Author(s):  
Lexuan Zhong ◽  
Jing Yuan ◽  
Brian Fleck
Keyword(s):  
Environmental Quality ◽  
Co2 Concentration ◽  
Sound Level ◽  
Cold Climate ◽  
Indoor Environmental Quality ◽  
Ann Model ◽  
University Of Alberta ◽  
Artificial Neural Network Ann ◽  
Carbon Dioxide Co2 ◽  
The University

In this paper, ventilation, indoor air quality (IAQ), thermal and acoustic conditions, and lighting were studied to evaluate the indoor environmental quality (IEQ) in an institutional building at the University of Alberta in Edmonton, Canada. This study examined IEQ parameters, including pressure, illuminance, acoustics, carbon dioxide (CO2) concentration, temperature, and humidity, with appropriate monitors allocated during a lecture (duration 50 min or 80 min) in four lecture classrooms repeatedly (N = 99) from October 2018 to March 2019 with the objectives of providing a comprehensive analysis of interactions between IEQ parameters. The classroom environments were maintained at 23 ± 1 °C and 33% ± 3% RH during two-season measurements. Indoor mean CO2 concentrations were 550–1055 ppm, and a mean sound level of 58 ± 3 dBA was observed. The air change rates were configured at 1.3–6.5 per hour based on continuous CO2 measurements and occupant loads in the lectures. A variance analysis indicated that the within-lecture classroom variations in most IEQ parameters exceeded between-lecture classrooms. A multilayer artificial neural network (ANN) model was developed on the basis of feedforward networks with a backpropagation algorithm. ANN results demonstrated the importance of the sequence of covariates on indoor conditions (temperature, RH, and CO2 level): Air change rate (ACR) > room operations (occupant number and light system) > outdoor conditions.

scholarly journals Direct Catalytic Conversion of CO2 to Cyclic Organic Carbonates under Mild Reaction Conditions by Metal—Organic Frameworks

Catalysts ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 34 ◽  
Author(s):  
Seong Huh
Keyword(s):  
Metal Organic Framework ◽  
Cycloaddition Reaction ◽  
Co2 Concentration ◽  
Reaction Conditions ◽  
Catalytic Systems ◽  
Heterogeneous Catalytic ◽  
Electrochemical Conversion ◽  
Modern Chemical ◽  
Metal Organic ◽  
Carbon Dioxide Co2

The reduction of the representative greenhouse gas, carbon dioxide (CO2), is significantly an important theme for the current research in the modern chemical world. For the last two decades, the development of new metal-organic framework (MOF) systems with highly selective capture of CO2, in the presence of other competing gaseous molecules, has flourished to capture or separate CO2 for environmental protection. Nonetheless, the ultimate resolution to lessen the atmospheric CO2 concentration may be in the chemical or electrochemical conversion of CO2 to other compounds. In this context, the catalytic cycloaddition reaction of CO2 into organic epoxides to produce cyclic carbonates is a more attractive method. MOFs are being proven as efficient heterogeneous catalytic systems for this important reaction. In this review, we collected very recent progress in MOF-based catalytic systems, fully operable under very mild reaction conditions (room temperature and 1 atm CO2).

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