Scalable Manufacturing of Metal Nanoparticles by Thermal Fiber Drawing

2016 ◽  
Author(s):  
Jingzhou Zhao ◽  
Abdolreza Javadi ◽  
Ting-Chiang Lin ◽  
Injoo Hwang ◽  
Yingchao Yang ◽  
...  
Keyword(s):  
Metal Nanoparticles ◽  
High Surface ◽  
Continuous Manufacturing ◽  
Molten Metals ◽  
Fiber Drawing ◽  
Energy Applications ◽  
Low Viscosity ◽  
Thermal Drawing ◽  
Scalable Production ◽  
Glass Metal

Thermal fiber drawing has emerged as a novel process for the continuous manufacturing of semiconductor and polymer nanoparticles. Yet a scalable production of metal nanoparticles by thermal drawing is not reported due to the low viscosity and high surface tension of molten metals. Here we present a generic method for the scalable nanomanufacturing of metal nanoparticles via thermal drawing based on droplet break-up emulsification of immiscible glass/metal systems. We experimentally show the scalable manufacturing of metal Sn nanoparticles (<100 nm) in Polyethersulfone (PES) fibers as a model system. This process opens a new pathway for scalable manufacturing of most metal nanoparticles as well as composites with embedded metal nanoparticles, which may find exciting photonic, electrical, or energy applications.

scholarly journals Scalable Manufacturing of Metal Nanoparticles by Thermal Fiber Drawing

2016 ◽  
Vol 4 (4) ◽  
Author(s):  
Jingzhou Zhao ◽  
Abdolreza Javadi ◽  
Ting-Chiang Lin ◽  
Injoo Hwang ◽  
Yingchao Yang ◽  
...  
Keyword(s):  
Metal Nanoparticles ◽  
High Surface ◽  
Particle Diameter ◽  
Underlying Mechanism ◽  
Continuous Manufacturing ◽  
Molten Metals ◽  
Fiber Drawing ◽  
Energy Applications ◽  
Low Viscosity ◽  
Thermal Drawing

Thermal fiber drawing has emerged as a novel process for the continuous manufacturing of semiconductor and polymer nanoparticles. Yet a scalable production of metal nanoparticles by thermal drawing is not reported due to the low viscosity and high surface tension of molten metals. Here, we present a generic method for the scalable nanomanufacturing of metal nanoparticles via thermal drawing based on droplet break-up emulsification of immiscible polymer/metal systems. We experimentally show the scalable manufacturing of metal Sn nanoparticles (<100 nm) in polyethersulfone (PES) fibers as a model system. The underlying mechanism for the particle formation is revealed, and a strategy for the particle diameter control is proposed. This process opens a new pathway for scalable manufacturing of metal nanoparticles from liquid state facilitated solely by the hydrodynamic forces, which may find exciting photonic, electrical, or energy applications.

Fabrication of Metal–Polymer Nanocomposites by In-Fiber Instability

2016 ◽  
Vol 4 (4) ◽  
Author(s):  
Ting-Chiang Lin ◽  
Jingzhou Zhao ◽  
Chezheng Cao ◽  
Abdolreza Javadi ◽  
Yingchao Yang ◽  
...  
Keyword(s):  
High Surface ◽  
Polymer Nanocomposite ◽  
Metal Nanoparticle ◽  
Molten Metals ◽  
Metal Core ◽  
Fiber Drawing ◽  
Low Viscosity ◽  
Submicron Scale ◽  
Characterization Procedure ◽  
Metal Polymer

Thermal fiber drawing process has emerged as a promising nanomanufacturing process to generate high-throughput, well aligned, and indefinitely long micro/nanostructures. However, scalable fabrication of metal–polymer nanocomposite is still a challenge, since it is still very difficult to control metal core geometry at nanoscale due to the low-viscosity and high-surface energy of molten metals in cladding materials (e.g., polymer or glass). Here, we show that a scalable nanomanufacture of metal–polymer nanocomposite via thermal fiber drawing is possible. Polyethersulfone (PES) fibers embedded with Sn nanoparticles (<200 nm) were produced by the iterative size reduction thermal fiber drawing. A post-characterization procedure was developed to successfully reveal the metal core geometry at submicron scale. A three-stage control mechanism is proposed to realize the possible control of the metal nanoparticle morphology. This thermal drawing approach promises a scalable production of metal–polymer nanocomposite fibers with unique physicochemical properties for exciting new functionalities.

scholarly journals Self-powered multifunctional sensing based on super-elastic fibers by soluble-core thermal drawing

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Mengxiao Chen ◽  
Zhe Wang ◽  
Qichong Zhang ◽  
Zhixun Wang ◽  
Wei Liu ◽  
...  
Keyword(s):  
Polymer Fibers ◽  
Elastic Fibers ◽  
Triboelectric Nanogenerator ◽  
Large Area ◽  
Manufacturing Method ◽  
Low Viscosity ◽  
Ion Movements ◽  
Self Powered ◽  
Thermal Drawing ◽  
Viscosity Polymer

AbstractThe well-developed preform-to-fiber thermal drawing technique owns the benefit to maintain the cross-section architecture and obtain an individual micro-scale strand of fiber with the extended length up to thousand meters. In this work, we propose and demonstrate a two-step soluble-core fabrication method by combining such an inherently scalable manufacturing method with simple post-draw processing to explore the low viscosity polymer fibers and the potential of soft fiber electronics. As a result, an ultra-stretchable conductive fiber is achieved, which maintains excellent conductivity even under 1900% strain or 1.5 kg load/impact freefalling from 0.8-m height. Moreover, by combining with triboelectric nanogenerator technique, this fiber acts as a self-powered self-adapting multi-dimensional sensor attached on sports gears to monitor sports performance while bearing sudden impacts. Next, owing to its remarkable waterproof and easy packaging properties, this fiber detector can sense different ion movements in various solutions, revealing the promising applications for large-area undersea detection.

scholarly journals Identifying Critical Binder Attributes to Facilitate Binder Selection for Efficient Formulation Development in a Continuous Twin Screw Wet Granulation Process

Pharmaceutics ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 210
Author(s):  
Lise Vandevivere ◽  
Maxine Vangampelaere ◽  
Christoph Portier ◽  
Cedrine de Backere ◽  
Olaf Häusler ◽  
...  
Keyword(s):  
Dissolution Kinetics ◽  
Wet Granulation ◽  
Continuous Manufacturing ◽  
Formulation Development ◽  
Granulation Process ◽  
Low Viscosity ◽  
Twin Screw ◽  
Poorly Soluble ◽  
Selection For ◽  
The Impact

The suitability of pharmaceutical binders for continuous twin-screw wet granulation was investigated as the pharmaceutical industry is undergoing a switch from batch to continuous manufacturing. Binder selection for twin-screw wet granulation should rely on a scientific approach to enable efficient formulation development. Therefore, the current study identified binder attributes affecting the binder effectiveness in a wet granulation process of a highly soluble model excipient (mannitol). For this formulation, higher binder effectiveness was linked to fast activation of the binder properties (i.e., fast binder dissolution kinetics combined with low viscosity attributes and good wetting properties by the binder). As the impact of binder attributes on the granulation process of a poorly soluble formulation (dicalcium phosphate) was previously investigated, this enabled a comprehensive comparison between both formulations in current research focusing on binder selection. This comparison revealed that binder attributes that are important to guide binder selection differ in function of the solubility of the formulation. The identification of critical binder attributes in the current study enables rational and efficient binder selection for twin-screw granulation of well soluble and poorly soluble formulations. Binder addition proved especially valuable for a poorly soluble formulation.

scholarly journals One-Dimensional (1D) Nanostructured Materials for Energy Applications

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2609
Author(s):  
Abniel Machín ◽  
Kenneth Fontánez ◽  
Juan C. Arango ◽  
Dayna Ortiz ◽  
Jimmy De León ◽  
...  
Keyword(s):  
Nanostructured Materials ◽  
Fossil Fuels ◽  
High Surface ◽  
High Surface Area ◽  
Future Research ◽  
One Dimensional ◽  
Progressive Movement ◽  
1D Nanostructures ◽  
Energy Applications ◽  
Energy Processes

At present, the world is at the peak of production of traditional fossil fuels. Much of the resources that humanity has been consuming (oil, coal, and natural gas) are coming to an end. The human being faces a future that must necessarily go through a paradigm shift, which includes a progressive movement towards increasingly less polluting and energetically viable resources. In this sense, nanotechnology has a transcendental role in this change. For decades, new materials capable of being used in energy processes have been synthesized, which undoubtedly will be the cornerstone of the future development of the planet. In this review, we report on the current progress in the synthesis and use of one-dimensional (1D) nanostructured materials (specifically nanowires, nanofibers, nanotubes, and nanorods), with compositions based on oxides, nitrides, or metals, for applications related to energy. Due to its extraordinary surface–volume relationship, tunable thermal and transport properties, and its high surface area, these 1D nanostructures have become fundamental elements for the development of energy processes. The most relevant 1D nanomaterials, their different synthesis procedures, and useful methods for assembling 1D nanostructures in functional devices will be presented. Applications in relevant topics such as optoelectronic and photochemical devices, hydrogen production, or energy storage, among others, will be discussed. The present review concludes with a forecast on the directions towards which future research could be directed on this class of nanostructured materials.

Metal nanoparticles: ligand free approach towards coupling reactions

2021 ◽  
Vol 01 ◽  
Author(s):  
Sharwari K. Mengane ◽  
Ronghui Wu ◽  
Liyun Ma ◽  
Chhaya S. Panse ◽  
Shailesh N. Vajekar ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
Metal Nanoparticles ◽  
Surface Area ◽  
Heterogeneous Catalysts ◽  
High Surface ◽  
High Surface Area ◽  
Reaction Medium ◽  
Coupling Reactions ◽  
Research Activities ◽  
Ligand Free

: Catalysis is the multidisciplinary field involving many areas of chemistry, notably in organometallic chemistry and materials science. It has great applications in synthesis of many industrially applicable compounds such as fuels and fine chemicals. The activity and selectivity are a key issue in catalysis that generally allied to high surface area. The current research activities mainly deal with the homogeneous and heterogeneous catalysis. Homogeneous and heterogeneous catalysis have certain drawbacks which restricts their application to great extent but have their own advantages. Hence, it has a predominant concern of current research to find out an alternate to overcome their drawbacks. Therefore, it is highly desirable to find a catalytic protocol that offers high selectivity and excellent product yield with quick and easy recovery. Along with their various applications as alternatives to conventional bulk materials nanomaterial have established its great role in different industrial and scientific applications. Nanocatalysis has emerged as new alternative to the conventional homogeneous and heterogeneous catalysis. The nanomaterials are responsible to enhance surface area of the catalyst, which ultimately increases the catalyst reactants contacts. In addition, it acts as robust material and has high surface area like heterogeneous catalysts. Insolubility of such nanomaterial in reaction medium makes them easily separable, hence, catalyst can be easily separate from the product. Hence, it has been proven that nanocatalysts behave like homogeneous as well as heterogeneous catalysts which work as a bridge between the conventional catalytic systems. Considering these merits; researchers has paid their attention towards applications of nanocatalyst in several organic reactions. This review article focused on the catalytic applications of metal nanoparticles (MNPs) such as Pd, Ag, Au, Cu, Pt in ligand free coupling reactions. In addition, it covers applications of bimetallic and multimetallic nanoparticles in ligand free coupling reactions.

scholarly journals Metal Nanoparticles as Green Catalysts

Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3602 ◽  
Author(s):  
Neel Narayan ◽  
Ashokkumar Meiyazhagan ◽  
Robert Vajtai
Keyword(s):  
Catalytic Activity ◽  
Composite Materials ◽  
Green Synthesis ◽  
Metal Nanoparticles ◽  
Surface Area ◽  
Significant Role ◽  
High Surface ◽  
High Surface Area ◽  
Catalytic Performance ◽  
Materials Development

Nanoparticles play a significant role in various fields ranging from electronics to composite materials development. Among them, metal nanoparticles have attracted much attention in recent decades due to their high surface area, selectivity, tunable morphologies, and remarkable catalytic activity. In this review, we discuss various possibilities for the synthesis of different metal nanoparticles; specifically, we address some of the green synthesis approaches. In the second part of the paper, we review the catalytic performance of the most commonly used metal nanoparticles and we explore a few roadblocks to the commercialization of the developed metal nanoparticles as efficient catalysts.

Rheological Properties of Liquid Metals and Semisolid Materials at Low Solid Fraction

2016 ◽  
Vol 256 ◽  
pp. 133-138 ◽  
Author(s):  
Marialaura Tocci ◽  
Christoph Zang ◽  
Ines Cadòrniga Zueco ◽  
Annalisa Pola ◽  
Michael Modigell
Keyword(s):  
Surface Tension ◽  
Rheological Properties ◽  
Liquid Metals ◽  
High Surface ◽  
Measuring System ◽  
High Surface Tension ◽  
Viscous Forces ◽  
Low Viscosity ◽  
Semi Solid ◽  
Low Shear

Rheological properties of liquid metals are difficult to investigate experimentally because of the extreme border conditions to consider. One difficulty is related to the low viscosity of liquid metals. Surface tension effects can cause forces that can be considerably higher than the viscous forces in the liquid metals. Evaluating the experimental data without considering these effects leads to an apparent shear thinning behavior of the material. In the present study, experiments were performed by means of a Searle rheometer changing the dimension of the measuring system with metals of high surface tension, as mercury and tin. It became evident that surface tension plays a significant role in the effects that falsify measurements at low shear rate. Conclusions can be drawn to what extent measurements of semi-solid metals are affected.

Biosynthesis of Silver Nanoparticles: Minireview

2020 ◽  
Vol 6 (2) ◽  
pp. 114-119
Author(s):  
Alaa Alnaimat ◽  
Intesar Aljamaeen
Keyword(s):  
Metal Nanoparticles ◽  
Pathogenic Bacteria ◽  
Wide Spectrum ◽  
High Surface ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Macro Scale ◽  
Physical And Chemical ◽  
Nano Size ◽  
And Chemical Properties

In principle, nanoscience focus on the understanding of the structure, physical and chemical properties of nano size objects. Nanoscience and nanotechnology are both recent and active ongoing branch of science includes multi interdisciplinary sciences. On the other hand, nanotechnology considered as the invested outcomes of the obtained fundamental knowledge about nano objects in various commercial, industrial, environmental and medical sectors. All nano scale matters regardless of their nature referred to as nano-objects were the prefix ‘nano’ mean one millionth of millimeter size. Due to their nano size and high surface area, metal nanoparticles exhibits unique and novel physical and chemical properties compared to their macro scale counterparts. They are considered as very interesting and popular antimicrobial agent with wide spectrum activity against the variety of pathogenic bacteria and fungi. Three main methods were routinely used for metal nanoparticles formation that are chemical, physical and biological approaches. As eco-friendly, cheap and safe synthesis approach without the use of toxic chemicals and free of resulted hazardous byproducts several extracellular and intracellular biological methods using bacteria, fungi, plants or their extracts were reported that known collectively as green nanotechnology

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