Investigation of Corrosion Processing for Ti-6Al-4V in Hydrofluoric-Nitric Acid System

Author(s):  
C. Lin ◽  
X. P. Hong

Corrosion processing is an effective way to solve difficult machining of titanium alloy. It can be applied for reducing weight, machining complex shape and fine structure. In this paper, the effects of the bath constituents and operation conditions on corrosion processing rate and surface quality for Ti-6Al-4V were investigated. Corrosion processing rate depends upon hydrofluoric acid concentration, the volume ratio of nitric acid to hydrofluoric acid, temperature. Nitric acid can promote the surface passivation and reduce surface roughness. The surfactant plays a dual role of surface finish improvement and acid fog suppression. During the period of processing, oxide film on the surface is dissolved initially, and there is the faster processing rate. Surface passivation occurs with the extension of time, decreasing processing rate. Finally corrosion processing rate trends to be stable when the growth of passive film and dissolution of the substrate achieve dynamic balance.

2021 ◽  
Vol 13 (3) ◽  
pp. 4156-4164
Author(s):  
Mari Napari ◽  
Tahmida N. Huq ◽  
David J. Meeth ◽  
Mikko J. Heikkilä ◽  
Kham M. Niang ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 640
Author(s):  
Artem I. Khrebtov ◽  
Vladimir V. Danilov ◽  
Anastasia S. Kulagina ◽  
Rodion R. Reznik ◽  
Ivan D. Skurlov ◽  
...  

The passivation influence by ligands coverage with trioctylphosphine oxide (TOPO) and TOPO including colloidal CdSe/ZnS quantum dots (QDs) on optical properties of the semiconductor heterostructure, namely an array of InP nanowires (NWs) with InAsP nanoinsertion grown by Au-assisted molecular beam epitaxy on Si (111) substrates, was investigated. A significant dependence of the photoluminescence (PL) dynamics of the InAsP insertions on the ligand type was shown, which was associated with the changes in the excitation translation channels in the heterostructure. This change was caused by a different interaction of the ligand shells with the surface of InP NWs, which led to the formation of different interfacial low-energy states at the NW-ligand boundary, such as surface-localized antibonding orbitals and hybridized states that were energetically close to the radiating state and participate in the transfer of excitation. It was shown that the quenching of excited states associated with the capture of excitation to interfacial low-energy traps was compensated by the increasing role of the “reverse transfer” mechanism. As a result, the effectiveness of TOPO-CdSe/ZnS QDs as a novel surface passivation coating was demonstrated.


2016 ◽  
Vol 43 (2) ◽  
pp. 105 ◽  
Author(s):  
Lu Wang ◽  
Yong-Ling Ruan

Roots and shoots are distantly located but functionally interdependent. The growth and development of these two organ systems compete for energy and nutrient resource, and yet, they keep a dynamic balance with each other for growth and development. The success of such a relationship depends on efficient root-shoot communication. Aside from the well-known signalling processes mediated by hormones such as auxin and cytokinin, sugars have recently been shown to act as a rapid signal to co-ordinate root and shoot development in response to endogenous and exogenous clues, in parallel to their function as carbon and energy resources for biomass production. New findings from studies on vascular fluids have provided molecular insights into the role of sugars in long-distance communications between shoot and root. In this review, we discussed phloem- and xylem- translocation of sugars and the impacts of sugar allocation and signalling on balancing root–shoot development. Also, we have taken the shoot–root carbon–nitrogen allocation as an example to illustrate the communication between the two organs through multi-layer root–shoot–root signalling circuits, comprising sugar, nitrogen, cytokinin, auxin and vascular small peptide signals.


2006 ◽  
Vol 03 (02) ◽  
pp. 153-175 ◽  
Author(s):  
MIOMIR VUKOBRATOVIĆ ◽  
BRANISLAV BOROVAC ◽  
VELJKO POTKONJAK

One of basic characteristics of the regular bipedal walk of humanoid robots is the maintenance of their dynamic balance during the walk, whereby a decisive role is played by the unpowered degrees of freedom arising at the foot–ground contact. Hence, the role of the Zero-Moment Point (ZMP) as an indicator of dynamic balance is indispensable. This paper gives a detailed discussion of some basic theoretical assumptions related to the ZMP in the light of imprecise, and even incorrect, interpretations that have recently appeared, and which have led to some erroneous conclusions. Examples are given to show some erroneous basic attitudes and the genesis of some of them is indicated. It is also pointed out that in the domain of bipedal walk there are still notions that are not clearly defined and their meanings differentiated in some related branches of science and engineering. One of the examples is dynamic balance and stability, which are often used interchangeably.


1989 ◽  
Vol 4 (6) ◽  
pp. 1320-1325 ◽  
Author(s):  
Q. X. Jia ◽  
W. A. Anderson

Effects of hydrofluoric acid (HF) treatment on the properties of Y–Ba–Cu–O oxides were investigated. No obvious etching of bulk Y–Ba–Cu–O and no degradation of zero resistance temperature were observed even though the oxides were placed into 49% HF solution for up to 20 h. Surface passivation of Y–Ba–Cu–O due to HF immersion was verified by subsequent immersion of Y–Ba–Cu–O in water. A thin layer of amorphous fluoride formed on the surface of the Y–Ba–Cu–O during HF treatment, which limited further reaction between Y–Ba–Cu–O and HF, and later reaction with water. Thin film Y–Ba–Cu–O was passivated by HF vapors and showed no degradation in Tc-zero after 30 min immersion in water. The properties of the surface layer of Y–Ba–Cu–O oxide after HF treatment are reported from Auger electron spectroscopy, x-ray diffraction, and scanning electron microscopy studies.


Author(s):  
Harsh A. Chaliyawala ◽  
Suresh Vemuri ◽  
Kashinath Lellala ◽  
Indrajit Mukhopadhyay

2008 ◽  
Vol 72 (1) ◽  
pp. 85-89 ◽  
Author(s):  
J. R. Leake ◽  
A. L. Duran ◽  
K. E. Hardy ◽  
I. Johnson ◽  
D. J. Beerling ◽  
...  

AbstractBiological weathering is a function of biotic energy expenditure. Growth and metabolism of organisms generates acids and chelators, selectively absorbs nutrient ions, and applies turgor pressure and other physical forces which, in concert, chemically and physically alter minerals. In unsaturated soil environments, plant roots normally form symbiotic mycorrhizal associations with fungi. The plants provide photosynthate-carbohydrate-energy to the fungi in return for nutrients absorbed from the soil and released from minerals. In ectomycorrhiza, one of the two major types of mycorrhiza of trees, roots are sheathed in fungus, and 15—30% of the net photosynthate of the plants passes through these fungi into the soil and virtually all of the water and nutrients taken up by the plants are supplied through the fungi. Here we show that ectomycorrhizal fungi actively forage for minerals and act as biosensors that discriminate between different grain sizes (53—90 μm, 500—1000 μm) and different minerals (apatite, biotite, quartz) to favour grains with a high surface-area to volume ratio and minerals with the highest P content. Growth and carbon allocation of the fungi is preferentially directed to intensively interact with these selected minerals to maximize resource foraging.


2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Yaser Abdulraheem ◽  
Moustafa Ghannam ◽  
Hariharsudan Sivaramakrishnan Radhakrishnan ◽  
Ivan Gordon

Photovoltaic devices based on amorphous silicon/crystalline silicon (a-Si:H/c-Si) heterojunction interfaces hold the highest efficiency as of date in the class of silicon-based devices with efficiencies exceeding 26% and are regarded as a promising technology for large-scale terrestrial PV applications. The detailed understanding behind the operation of this type of device is crucial to improving and optimizing its performance. SHJ solar cells have primarily two main interfaces that play a major role in their operation: the transparent conductive oxide (TCO)/a-Si:H interface and the a-Si:H/c-Si heterojunction interface. In the work presented here, a detailed analytical description is provided for the impact of both interfaces on the performance of such devices and especially on the device fill factor ( FF ). It has been found that the TCO work function can dramatically impact the FF by introducing a series resistance element in addition to limiting the forward biased current under illumination causing the well-known S-shape characteristic in the I-V curve of such devices. On the other hand, it is shown that the thermionic emission barrier at the heterojunction interface can play a major role in introducing an added series resistance factor due to the intrinsic a-Si:H buffer layer that is usually introduced to improve surface passivation. Theoretical explanation on the role of both interfaces on device operation based on 1D device simulation is experimentally verified. The I-V characteristics of fabricated devices were compared to the curves produced by simulation, and the observed degradation in the FF of fabricated devices was explained in light of analytical findings from simulation.


Author(s):  
Chunli Wu ◽  
Xiaohao Dong ◽  
Lan Wang ◽  
Lei Zhang ◽  
Xiaotong Liu

Abstract In order to improve the visible light catalytic activity of titanium dioxide (TiO2) and ensure its long-term stability on the surface of concrete, an N-TiO2/SiO2 composite was prepared using tetrabutyl titanate, nitric acid, and modified SiO2 nanospheres as the precursors by a solvothermal method. The effect of nitric acid on the phase composition, morphology and photoelectric properties of the synthesized photocatalytic composites was systematically studied by various characterization methods. The results show that the optimum nitric acid/butyl titanate volume ratio is 1/6. The nitrogen-doped TiO2 nanoparticles were uniformly dispersed on the surface of spherical SiO2 with a diameter of 200 nm. The degradation rate of simulated pollutants (RhB) with pH 5 and 7 exceeded 95% within 30 minutes and the catalytic effect remained excellent after five repetitions without much weakening. The excellent visible photocatalytic performance can be attributed to the doping of N replacing part of the oxygen atoms in TiO2, forming the energy level of N 2p at the O 2p energy level and reducing the TiO2 energy band gap to 2.99 eV. At the same time, the better dispersion of N-TiO2/SiO2 prepared by this new synthesis method also plays an important role in the improvement of visible light photocatalytic activity.


2020 ◽  
Vol 6 (1) ◽  
pp. 130
Author(s):  
Igor Chugunov ◽  
Valentina Makohon

The purpose of the article is to reveal the role of budgetary projection in the system of financial and economic regulation of social processes within the framework of improving the efficiency of fiscal policy intended to macroeconomic stability maintenance in both countries with transformational and advanced economies. The comparative and factorial methods allowed to developthe features of the institutional environment of the budgetary progection methodology, to identify approaches for its improvement. Methodology. Substantiation of the role of budget forecasting in the system of financial and economic regulation of social processes, determination of provisions for improving its methodology is based on generalized and systematic approaches that are applied in both developed and transformational economies. An analysis of the stages of the process and the budgetary projection methods evaluation, that are used in different countries, have been carried out. Results showed that the efficient budgetary projection methodology is the basis for sound fiscal policy. The development of realistic budgetary projections facilitates justified management decisions aimed at ensuring the country financial firmness. Devia-tions from budget revenues from the projected indicators do not make it possible to achieve certain fiscal policy outcomes and, accordingly, cause a budget cut. In order to develop realistic budgetary projections, a welldesigned and coherent database is needed for all time series, necessary to analyze and project budget revenues. Time series of key determinants affecting the budget revenues level should be available at different frequencies (monthly, quarterly, annually). Where data reflecting similar economic processes by different revenue sources are available, any differences between them shall be determined by reference to their coverage and methodology. Practical implications. Budgetary projections are the basis for the formation of effective fiscal policy and the benchmark of the reproduction process. Adequate level of justification for budget projection will help to provide a dynamic balance of budgetary indicators and the budgetary system stability. Institutional changes to the budgetary projection methodology should be made on the basis of taking into account the dynamic interrelation of budgetary and macroeconomic indicators. The remarkable task here is the development of an economic and mathematical model based on the assessment of the national economy capabilities by reference to the assessment of macroeconomic proportions and the corresponding social and economic conditions of social production. Value/ originality. Developing the budgetary projection approaches in the context of improvement of the fiscal policy efficiency is an important precondition for ensuring macroeconomic stability. In order to increase the budget projection justifiability, it is advisable to make institutional changes to its methodology. Based on the methioned above, the article reveals the essence and role of the budgetary projection in the system of financial and economic regulation of social processes in the context of improving the fiscal policy effectiveness aimed at macroeconomic stability maintenance; approaches to improving the budgetary projection methodology have been identified, and it has been determined that the soundness and feasibility of budgetary projection are the basis for effective fiscal policy. The predictability of budgetary criteria, budgetary architectonics contribute to improving the efficiency of transformations in the public finance system.


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