Tetrahedral Amorphous Carbon With Ultratrace Hydrogen

Author(s):  
Hiroshi Inaba ◽  
Toru Matsumura ◽  
Yoko Saito ◽  
Hiroyuki Matsumoto

In heat assisted magnetic recording (HAMR) where near-field light from a head heats up a disk, disk overcoat needs to be heat-resistive and transparent. ta-C (tetrahedral amorphous carbon) films have been considered to be promising for HAMR disk overcoat, because they are denser and harder than diamond-like carbon (DLC) films that have been used as disk overcoat. In the previous study, ta-C did not show any change in the film thickness by heating up to 450 degrees Celsius, approving a heat-resistant high protective film [1]. The purpose of this study is to investigate enhanced ta-C, which is harder, denser and higher-thermostability than those of conventional ta-C in reference to that nanometer-sized diamonds were more stable than graphite by adding the small amount of hydrogen [2]. In this report, ultratrace hydrogenerated ta-C, amorphous films, was investigated to expect similar effect as was observed in the crystalline films.

1999 ◽  
Vol 593 ◽  
Author(s):  
A.C. Ferrari ◽  
J. Robertson ◽  
R. Pastorelli ◽  
M.G. Beghi ◽  
C.E. Bottani

ABSTRACTThe elastic constants of thin Diamond-Like Carbon (DLC) films supply important information, but their measurement is difficult. Standard nanoindentation does not directly measure the elastic constants and has strong limitations particularly in the case of hard thin films on softer substrates, such as tetrahedral amorphous carbon on Si. Surface acoustic waves provide a better mean to investigate elastic properties. Surface Brillouin scattering (SBS) intrinsically probes acoustic waves of the wavelength which is appropriate to test the properties of films in the tens to hundreds of nanometers thickness range. SBS can be used to derive all the isotropic elastic constants of hard-on-soft and soft-on-hard amorphous carbon films of different kinds, with thickness down to less than 10 nm. The results help to resolve the previous uncertainties in mechanical data. The Young's modulus of tetrahedral amorphous carbon (ta-C) turns out to be lower than that of diamond, while the moduli of hydrogenated ta-C (ta-C:H) are considerably lower than those of ta-C because of the weakening effect of C-H bonding.


1999 ◽  
Vol 594 ◽  
Author(s):  
A. C. Ferrari ◽  
J. Robertson ◽  
R. Pastorelli ◽  
M. G. Beghi ◽  
C. E. Bottani

AbstractThe elastic constants of thin Diamond-Like Carbon (DLC) films supply important information, but their measurement is difficult. Standard nanoindentation does not directly measure the elastic constants and has strong limitations particularly in the case of hard thin films on softer substrates, such as tetrahedral amorphous carbon on Si. Surface acoustic waves provide a better mean to investigate elastic properties. Surface Brillouin scattering (SBS) intrinsically probes acoustic waves of the wavelength which is appropriate to test the properties of films in the tens to hundreds of nanometers thickness range. SBS can be used to derive all the isotropic elastic constants of hard-on-soft and soft-on-hard amorphous carbon films of different kinds, with thickness down to less than 10 nm. The results help to resolve the previous uncertainties in mechanical data. The Young's modulus of tetrahedral amorphous carbon (ta-C) turns out to be lower than that of diamond, while the moduli of hydrogenated ta-C (ta-C:H) are considerably lower than those of ta-C because of the weakening effect of C-H bonding.


2000 ◽  
Vol 366 (1-2) ◽  
pp. 169-174 ◽  
Author(s):  
J.R. Shi ◽  
X. Shi ◽  
Z. Sun ◽  
E. Liu ◽  
B.K. Tay ◽  
...  

2011 ◽  
Vol 60 (6) ◽  
pp. 066804
Author(s):  
Han Liang ◽  
Chen Xian ◽  
Yang Li ◽  
Wang Yan-Wu ◽  
Wang Xiao-Yan ◽  
...  

Vacuum ◽  
2020 ◽  
Vol 172 ◽  
pp. 109043
Author(s):  
Yongfeng Kang ◽  
Bin Li ◽  
Jingyi Zhao ◽  
Bangzhi Ge ◽  
Ming Weng ◽  
...  

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