Solid-State Dye-Sensitized Solar Cells Using Conducting Polymers as Hole Transporting Materials

Solar Energy ◽  
2006 ◽  
Author(s):  
Mi-Ra Kim ◽  
Seung-Yeop Lee ◽  
Yun-Seon Yeo ◽  
Yong-Rae Cho ◽  
Sung-Hae Park ◽  
...  

Thiophene-based polymers have good prospects in the field of electronic and photoelectronic devices because of their solubility, processability, environmental stability, and excellent electrical conductivity. We synthesized new type of thiophene-based polymers to use as hole transporting materials on dye-sensitized solar cells (DSSC). The thiophene-based polymers were synthesized as random copolymers containing 3-{2-[2-(2-(4-methoxybiphenyl)ethoxy)ethoxy]ethoxy}methylthiophene (MEET) units and 3-hexylthiophene (3HT) units. The photovoltaic performance of the solid-state DSSC device was improved to 3.88% overall efficiency under AM 1.5 illumination when the thiophene-based copolymer was introduced to the electrolyte as a hole transporting material.

2012 ◽  
Vol 162 (23) ◽  
pp. 1997-2004 ◽  
Author(s):  
Ausra Tomkeviciene ◽  
Gabija Puckyte ◽  
Juozas Vidas Grazulevicius ◽  
Martial Degbia ◽  
Francois Tran-Van ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (61) ◽  
pp. 49590-49597 ◽  
Author(s):  
Thanh-Tuân Bui ◽  
Said Karim Shah ◽  
Xavier Sallenave ◽  
Mamatimin Abbas ◽  
Gjergji Sini ◽  
...  

Star shaped hole conducting molecular glasses were synthetized and applied in solid state dye-sensitized solar cells.


ChemNanoMat ◽  
2015 ◽  
Vol 1 (3) ◽  
pp. 203-210 ◽  
Author(s):  
Thanh-Tuân Bui ◽  
Said Karim Shah ◽  
Mamatimin Abbas ◽  
Xavier Sallenave ◽  
Gjergji Sini ◽  
...  

Molecules ◽  
2020 ◽  
Vol 25 (1) ◽  
pp. 198 ◽  
Author(s):  
Michèle Chevrier ◽  
Alberto Fattori ◽  
Laurent Lasser ◽  
Clément Kotras ◽  
Clémence Rose ◽  
...  

Chlorophyll a derivatives were integrated in “all solid-state” dye sensitized solar cells (DSSCs) with a mesoporous TiO2 electrode and 2′,2′,7,7′-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene as the hole-transport material. Despite modest power conversion efficiencies (PCEs) between 0.26% and 0.55% achieved for these chlorin dyes, a systematic investigation was carried out in order to elucidate their main limitations. To provide a comprehensive understanding of the parameters (structure, nature of the anchoring group, adsorption …) and their relationship with the PCEs, density functional theory (DFT) calculations, optical and photovoltaic studies and electron paramagnetic resonance analysis exploiting the 4-carboxy-TEMPO spin probe were combined. The recombination kinetics, the frontier molecular orbitals of these DSSCs and the adsorption efficiency onto the TiO2 surface were found to be the key parameters that govern their photovoltaic response.


Crystals ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 452 ◽  
Author(s):  
Yu Jeong Jang ◽  
Suresh Thogiti ◽  
Kang-yong Lee ◽  
Jae Hong Kim

The long-term stability of liquid-state dye-sensitized solar cells (liquid-DSSCs) is a primary problem for the upscaling and commercialization of this technology. The solid-state dye-sensitized solar cell (ss-DSSC) has been instigated to overcome the liquid-DSSC’s inherent production and instability issues and advancement has been made to achieve low-cost high-power conversion efficiency. The photovoltaic performance of ruthenium-based complex Z907 dye was studied in ss-DSSCs using a solid-state polymerized conductive polymer as hole-transporting material (HTM). We investigated the long-term stability of both liquid and solid-state DSSCs and the findings revealed an improved photovoltaic performance and long-term stability of ss-DSSC. This mainly depends on the transport phenomena of the HTM throughout the interface. The present results show a pavement for manufacturing highly stable and inexpensive ss-DSSC and the practical use is promising.


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