Hydrogen Production by Steam-Gasification of Petroleum Coke Using Concentrated Solar Power: Reactor Experimentation With Slurry Feeding

Solar Energy ◽  
2006 ◽  
Author(s):  
Andreas Z’Graggen ◽  
Philipp Haueter ◽  
Gilles Maag ◽  
Alfonso Vidal ◽  
Manuel Romero ◽  
...  
Keyword(s):  
Energy Conversion ◽  
Conversion Efficiency ◽  
Chemical Conversion ◽  
Chemical Reactor ◽  
Energy Conversion Efficiency ◽  
Steam Gasification ◽  
Solar Furnace ◽  
Molar Ratio ◽  
Particle Size Range ◽  
Reactor Temperature

We report on the experimental evaluation of a 5 kW solar chemical reactor for the steam-gasification of petcoke, carried out at PSI’s solar furnace. A petcoke-water slurry was continuously injected into a solar cavity-receiver to create a vortex flow directly exposed to concentrated solar radiation. For a nominal reactor temperature of 1500 K, a residence time of 2.4 s, and a water-petcoke molar ratio of 4.8, the maximum degree of petcoke conversion was 87%. Typical syngas composition produced was 62% H2, 25% CO, 12% CO2, and 1% CH4. The energy conversion efficiency — defined as the portion of solar energy absorbed as chemical energy and sensible heat — attained 17%. The effect of varying the particle size (range 8.5–200 μm) and slurry stoichiometry (range 2.1–6.3) on the degree of chemical conversion and energy conversion efficiency was examined.

Experimental Investigation of the Solar Carbothermic Reduction of ZnO Using a Two-cavity Solar Reactor

2004 ◽  
Vol 126 (1) ◽  
pp. 633-637 ◽  
Author(s):  
T. Osinga ◽  
U. Frommherz ◽  
A. Steinfeld ◽  
C. Wieckert
Keyword(s):  
Carbothermic Reduction ◽  
Chemical Conversion ◽  
Chemical Reactor ◽  
Reaction Chamber ◽  
Solar Furnace ◽  
Molar Ratio ◽  
Solar Simulator ◽  
Co2 Emission Reduction ◽  
In Series ◽  
Reduction Of Zno

Zinc production by solar carbothermic reduction of ZnO offers a CO2 emission reduction by a factor of 5 vis-a`-vis the conventional fossil-fuel-based electrolytic or Imperial Smelting processes. Zinc can serve as a fuel in Zn-air fuel cells or can be further reacted with H2O to form high-purity H2. In either case, the product ZnO is solar-recycled to Zn. We report on experimental results obtained with a 5 kW solar chemical reactor prototype that features two cavities in series, with the inner one functioning as the solar absorber and the outer one as the reaction chamber. The inner cavity is made of graphite and contains a windowed aperture to let in concentrated solar radiation. The outer cavity is well insulated and contains the ZnO-C mixture that is subjected to irradiation from the inner graphite cavity. With this arrangement, the inner cavity protects the window against particles and condensable gases and further serves as a thermal shock absorber. Tests were conducted at PSI’s Solar Furnace and ETH’s High-Flux Solar Simulator to investigate the effect of process temperature (range 1350-1600 K), reducing agent type (beech charcoal, activated charcoal, petcoke), and C:ZnO stoichiometric molar ratio (range 0.7–0.9) on the reactor’s performance and chemical conversion. In a typical 40-min solar experiment at 1500 K, 500 g of a ZnO-C mixture were processed into Zn(g), CO, and CO2. Thermal efficiencies of up to 20% were achieved.

Experimental Investigation of the Solar Carbothermic Reduction of ZnO Using a Two-Cavity Solar Reactor

Solar Energy ◽  
2003 ◽  
Author(s):  
T. Osinga ◽  
U. Frommherz ◽  
A. Steinfeld ◽  
C. Wieckert
Keyword(s):  
Carbothermic Reduction ◽  
Chemical Conversion ◽  
Chemical Reactor ◽  
Reaction Chamber ◽  
Solar Furnace ◽  
Molar Ratio ◽  
Solar Simulator ◽  
Co2 Emission Reduction ◽  
In Series ◽  
Reduction Of Zno

Zinc production by solar carbothermic reduction of ZnO offers a CO2 emission reduction by a factor of 5 vis-a´-vis the conventional fossil-fuel-based electrolytic or Imperial Smelting processes. Zinc can serve as a fuel in Zn-air fuel cells or can be further reacted with H2O to form high-purity H2. In either case, the product ZnO is solar-recycled to Zn. We report on experimental results obtained with a 5 kW solar chemical reactor prototype that features two cavities in series, with the inner one functioning as the solar absorber and the outer one as the reaction chamber. The inner cavity is made of graphite and contains a windowed aperture to let in concentrated solar radiation. The outer cavity is well insulated and contains the ZnO-C mixture that is subjected to irradiation from the inner graphite cavity. With this arrangement, the inner cavity protects the window against particles and condensable gases and further serves as a thermal shock absorber. Tests were conducted at PSI’s Solar Furnace and ETH’s High-Flux Solar Simulator to investigate the effect of process temperature (range 1350–1600 K), reducing agent type (beech charcoal, activated charcoal, petcoke), and C:ZnO stoichiometric molar ratio (range 0.7–0.9) on the reactor’s performance and chemical conversion. In a typical 40-min solar experiment at 1500 K, 500 g of a ZnO-C mixture were processed into Zn(g), CO, and CO2. Thermal efficiencies of up to 20% were achieved.

First-principles study on the electronic and optical properties of the orthorhombic CsPbBr3 and CsPbI3 with Cmcm space group

2021 ◽  
Author(s):  
Xianhao Zhao ◽  
Tianyu Tang ◽  
Quan Xie ◽  
like gao ◽  
Limin Lu ◽  
...  
Keyword(s):  
Optical Properties ◽  
Solar Cells ◽  
Energy Conversion ◽  
Conversion Efficiency ◽  
First Principles ◽  
Energy Conversion Efficiency ◽  
Space Group ◽  
Absorbing Materials ◽  
Halide Perovskites ◽  
Lead Halide

The cesium lead halide perovskites are regarded as effective candidates for light-absorbing materials in solar cells, which have shown excellent performances in experiments such as promising energy conversion efficiency. In...

Metal-like electrical conductivity in LaxSr2−xTiMoO6 oxides for high temperature thermoelectric power generation

2017 ◽  
Vol 46 (18) ◽  
pp. 5872-5879 ◽  
Author(s):  
Mandvi Saxena ◽  
Tanmoy Maiti
Keyword(s):  
Power Generation ◽  
Electrical Conductivity ◽  
High Temperature ◽  
Energy Conversion ◽  
Thermoelectric Power ◽  
Conversion Efficiency ◽  
Energy Conversion Efficiency ◽  
Power Generators ◽  
Thermoelectric Power Generation

Increasing electrical conductivity in oxides, which are inherently insulators, can be a potential route in developing oxide-based thermoelectric power generators with higher energy conversion efficiency.

Performance Improvements in Cooker-Top Gas Burners for Small Aspect Ratio Changes

2017 ◽  
Vol 9 (4) ◽  
Author(s):  
Robson L. Silva ◽  
Bruno V. Sant′Ana ◽  
José R. Patelli ◽  
Marcelo M. Vieira
Keyword(s):  
Energy Conversion ◽  
Fuel Consumption ◽  
Conversion Efficiency ◽  
Minimum Energy ◽  
Energy Conversion Efficiency ◽  
Energy Performance ◽  
Operating Conditions ◽  
Lower Fuel Consumption ◽  
Performance Improvements ◽  
Aspect Ratios

This paper aims to identify performance improvements in cooker-top gas burners for changes in its original geometry, with aspect ratios (ARs) ranging from 0.25 to 0.56 and from 0.28 to 0.64. It operates on liquefied petroleum gas (LPG) and five thermal power (TP) levels. Considering the large number of cooker-top burners currently being used, even slight improvements in thermal performance resulting from a better design and recommended operating condition will lead to a significant reduction of energy consumption and costs. Appropriate instrumentation was used to carry out the measurements and methodology applied was based on regulations from INMETRO (CONPET program for energy conversion efficiency in cook top and kilns), ABNT (Brazilian Technical Standards Normative) and ANP—National Agency of Petroleum, Natural Gas (NG) and Biofuels. The results allow subsidizing recommendations to minimum energy performance standards (MEPS) for residential use, providing also higher energy conversion efficiency and/or lower fuel consumption. Main conclusions are: (i) Smaller aspect ratios result in the same heating capacity and higher efficiency; (ii) higher aspect ratios (original burners) are fuel consuming and inefficient; (iii) operating conditions set on intermediate are lower fuel consumption without significant differences in temperature increases; (iv) Reynolds number lower than 500 provides higher efficiencies.

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