Photoelectrochemical Water Splitting for Hydrogen Production Using Combination of CIGS2 Solar Cell and RuO2 Photocatalyst

Solar Energy ◽  
2004 ◽  
Author(s):  
Neelkanth G. Dhere ◽  
Anant H. Jahagirdar ◽  
Upendra S. Avachat ◽  
Ankur A. Kadam

This paper presents the development of photoelectrochemical (PEC) setup using multiple bandgap combination of CuIn1−xGaxS2 (CIGS2) thin-film photovoltaic (PV) cell and ruthenium oxide (RuO2) photocatalyst. FSEC PV Materials Lab has developed a PEC setup consisting of two illuminated CIGS2 cells, a ruthenium oxide (RuO2) anode deposited on titanium sheet for oxygen evolution and a platinum foil cathode for hydrogen evolution. With this combination, a PEC efficiency of 4.29% has been achieved.

Author(s):  
Hanwen Xu ◽  
Jiawei Zhu ◽  
Pengyan Wang ◽  
Ding Chen ◽  
Chengtian Zhang ◽  
...  

Rational design and construction of high-efficiency bifunctional catalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is crucial for large-scale hydrogen production by water splitting. Herein, by a...


Author(s):  
Peng Liu ◽  
Weisheng Pan ◽  
Rui Yao ◽  
Lihan Zhang ◽  
Qianyuan Wu ◽  
...  

Developing advanced bifunctional water splitting electrodes that can perform both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is critically important for sustainable hydrogen production because of the simplicity...


Author(s):  
Qianli Ma ◽  
Huihui Jin ◽  
Fan-Jie Xia ◽  
Hanwen Xu ◽  
Jiawei Zhu ◽  
...  

High cost performance catalysts are urgently required for hydrogen production from electrochemical water electrolysis by the hydrogen evolution reaction (HER) and slow oxygen evolution reaction (OER). Herein, by means of...


2020 ◽  
Vol 35 (1) ◽  
pp. 839-846
Author(s):  
Katharina Welter ◽  
Jan-Philipp Becker ◽  
Friedhelm Finger ◽  
Wolfram Jaegermann ◽  
Vladimir Smirnov

2020 ◽  
Vol 16 ◽  
Author(s):  
Yuxue Wei ◽  
Honglin Qin ◽  
Jinxin Deng ◽  
Xiaomeng Cheng ◽  
Mengdie Cai ◽  
...  

Introduction: Solar-driven photocatalytic hydrogen production from water splitting is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. In this review, recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. In particular, the factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Background: Photocatalytic hydrogen evolution from water splitting using photocatalyst semiconductors is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. Methods: This review summarizes the recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation. Results: Recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. The factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Conclusion: The state-of-the-art CdS for producing hydrogen from photocatalytic water splitting under visible light is discussed. The future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are also described.


2018 ◽  
Vol 11 (5) ◽  
pp. 1287-1298 ◽  
Author(s):  
Prashanth W. Menezes ◽  
Chakadola Panda ◽  
Stefan Loos ◽  
Florian Bunschei-Bruns ◽  
Carsten Walter ◽  
...  

The mechanistically distinct and synergistic role of phosphite anions in hydrogen evolution and nickel cations in oxygen evolution have been uncovered for active and durable overall water splitting catalysis in nickel phosphite.


2021 ◽  
Author(s):  
Zihao Liu ◽  
Shifeng Li ◽  
Fangfang Wang ◽  
Mingxia Li ◽  
Yonghong Ni

FeNi-layered double hydroxide (LDH) is thought to be an excellent electrocatalyst for oxygen evolution reaction (OER), but it always shows extremely poor electrocatalytic activity toward hydrogen evolution reaction (HER) in...


Author(s):  
Xuejun Zhai ◽  
Qingping Yu ◽  
Guishan Liu ◽  
Junlu Bi ◽  
Yu Zhang ◽  
...  

Hydrogen evolution reaction (HER) based on water electrolysis is promising for renewable hydrogen production. Limited by sluggish anodic oxygen evolution reaction (OER), rational fabrication of efficient catalyst for HER coupled...


RSC Advances ◽  
2017 ◽  
Vol 7 (73) ◽  
pp. 46286-46296 ◽  
Author(s):  
Nan Zhang ◽  
Junyu Lei ◽  
Jianpeng Xie ◽  
Haiyan Huang ◽  
Ying Yu

A novel 3D hierarchical bifunctional catalytic electrode, MoS2/Ni3S2 nanorod arrays well-aligned on NF exhibited excellent electrocatalytic efficiency for hydrogen evolution reaction, oxygen evolution reaction and overall water splitting.


2017 ◽  
Vol 46 (34) ◽  
pp. 11335-11343 ◽  
Author(s):  
Jiali Lv ◽  
Jinfeng Zhang ◽  
Kai Dai ◽  
Changhao Liang ◽  
Guangping Zhu ◽  
...  

Sustainable photocatalytic hydrogen evolution (PHE) of water splitting has been utilized to solve the serious environmental pollution and energy shortage problems over the last decade.


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