The Corrosion Behavior of Welded Line Pipes in Wet H2S Environment

2002 ◽  
Author(s):  
Yaorong Feng ◽  
Chunyong Huo ◽  
Feng Yan
Keyword(s):  
Residual Stress ◽  
Corrosion Resistance ◽  
Stress Corrosion ◽  
Applied Stress ◽  
Corrosion Behavior ◽  
Stress Corrosion Cracking ◽  
Corrosion Cracking ◽  
Steel Pipes ◽  
H2s Corrosion ◽  
Hydrogen Induced Cracking

The corrosion behavior of over-bending and under-bending formed Spiral Submerged Arc Welded (SSAW) steel pipes in NACE solution has been investigated by use of the self-designed full-scale corrosion test unit. It indicates that the H2S damage of welded pipes characteristics Blister and Stress Corrosion Cracking (SCC). The blister number, diameter, and crack number is increasing as the increasing of applied stress. The residual stress of welded pipes has a large effect on the H2S corrosion resistance, the tensile residual stress has a detrimental effect, and while the compression residual stress is beneficial to H2S corrosion resistance. The damage mechanism of the welded pipes in H2S containing solution under the presence of applied stress and residual stress has not only Hydrogen Induced Cracking (HIC), but also Stress Corrosion Cracking, and the applied stress and residual stress promote not only Stress Corrosion Cracking, but also Hydrogen Induced Cracking. The test results reveal that improving pipe’s weld surface quality, lowering tensile residual stress, and also control the operating stress are the key measures for controlling the wet H2S corrosion of welded steel pipes. Suggestions for selection of line pipes in different service conditions have been made.

scholarly journals Effect of CO2/H2S and Applied Stress on Corrosion Behavior of 15Cr Tubing in Oil Field Environment

Metals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 409
Author(s):  
Xuehui Zhao ◽  
Wei Huang ◽  
Guoping Li ◽  
Yaorong Feng ◽  
Jianxun Zhang
Keyword(s):  
Stainless Steel ◽  
Partial Pressure ◽  
Stress Corrosion ◽  
Applied Stress ◽  
Corrosion Behavior ◽  
Stress Corrosion Cracking ◽  
Corrosion Cracking ◽  
Oil Field ◽  
Uniform Corrosion ◽  
Field Environment

The corrosion behavior of a 15Cr-6Ni-2Mo martensitic stainless steel (15Cr stainless steel) in a CO2/H2S environment was investigated by conducting high-temperature/high-pressure immersion tests combined with scanning electron microscopy and metallographic microscopy. The presence of H2S decreased the corrosion resistance of the 15Cr tubing steel. The critical H2S partial pressure (PH2S) for stress corrosion cracking in the 15Cr tubing steel in the simulated oil field environment with a CO2 partial pressure of 4 MPa and an applied stress of 80% σs was identified. The 15Cr tubing steel mainly suffered uniform corrosion with no pitting and cracking when the PH2S was below 0.5 MPa. When the PH2S increased to 1 MPa and the test temperature was 150 °C, the pitting and cracking sensitivity increased. The stress corrosion cracking at a higher PH2S is attributed to the sulfide-induced brittle fracture.

scholarly journals Role of Crack-Tip Residual Stresses in Stress Corrosion Behavior of Pre-stressing AA7020

2019 ◽  
Vol 9 (03) ◽  
Author(s):  
Ashish Thakur
Keyword(s):  
Residual Stress ◽  
Aluminum Alloy ◽  
Residual Stresses ◽  
Stress Corrosion ◽  
Corrosion Behavior ◽  
Stress Corrosion Cracking ◽  
Crack Tip ◽  
Corrosion Cracking ◽  
Compressive Residual Stresses

This paper analyzes stress corrosion cracking (SCC) of pre-cracked samples in the presence of compressive residual stresses generated in the vicinity of the crack tip during fatigue pre-cracking. Research focuses on the role of cracktip residual stresses of compressive nature, generated by fatigue loading, in stress corrosion cracking of pre-cracked samples of medium high strength aluminum alloy 7020 subjected to localized anodic dissolution and hydrogen assisted cracking. Fatigue pre-cracking load on the samples generates compressive residual stresses in the vicinity of the crack tip which improve the stress corrosion behavior of the aluminum alloy by delaying either the metal dissolution or the hydrogen entry, thus increasing the fracture load in an aggressive environment. The rice model of the residual stress distribution in the vicinity of a crack tip may be usedto explain these retardation effects by estimating the stress level and plastic zone size. Microscopically, compressive residual stress produce a transition topography between the fatigue pre-crack and the cleavage-like (unstable) fracture mode.

AMBRONZE 413

Alloy Digest ◽  
1969 ◽  
Vol 18 (6) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Physical Properties ◽  
Surface Treatment ◽  
Stress Corrosion ◽  
Tensile Properties ◽  
Stress Corrosion Cracking ◽  
Electrical Contact ◽  
Heat Treating ◽  
Corrosion Cracking ◽  
Tin Bronze

Abstract AMBRONZE 413 is a copper-tin bronze recommended for plater's plates and electrical contact springs. It is relatively immune to stress-corrosion cracking. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: Cu-201. Producer or source: Anaconda American Brass Company.

NICROFER 5716 HMoW

Alloy Digest ◽  
1985 ◽  
Vol 34 (11) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Physical Properties ◽  
Stress Corrosion ◽  
Tensile Properties ◽  
Stress Corrosion Cracking ◽  
Crevice Corrosion ◽  
Corrosion Cracking ◽  
Low Carbon ◽  
Nickel Chromium ◽  
Corrosion Pitting

Abstract NICROFER 5716 HMoW is a nickel-chromium-molybdenum alloy with tungsten and extremely low carbon and silicon contents. It has excellent resistance to crevice corrosion, pitting and stress-corrosion cracking. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, machining, and joining. Filing Code: Ni-324. Producer or source: Vereingte Deutsche Metallwerke AG.

NAS 825

Alloy Digest ◽  
2012 ◽  
Vol 61 (2) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Physical Properties ◽  
Stress Corrosion ◽  
Tensile Properties ◽  
Nickel Alloy ◽  
Stress Corrosion Cracking ◽  
Chloride Ion ◽  
Heat Treating ◽  
Corrosion Cracking ◽  
Corrosion Resistant

Abstract NAS 825 is a corrosion-resistant nickel alloy that has resistance to both oxidizing and reducing environments, and with 42% nickel, the alloy is very resistant to chloride-ion stress-corrosion cracking. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Ni-694. Producer or source: Nippon Yakin Kogyo Company Ltd.

NRC/EPRI Residual Stress Validation Program Phase I: Experimental Specimen Modeling and Measurement

2011 ◽  
Author(s):  
J. Broussard ◽  
P. Crooker
Keyword(s):  
Residual Stress ◽  
Residual Stresses ◽  
Stress Corrosion ◽  
Stress Corrosion Cracking ◽  
Phase 1 ◽  
Measurement Techniques ◽  
Corrosion Cracking ◽  
Welding Residual Stress ◽  
Hole Drilling ◽  
Pressurized Water

The US Nuclear Regulatory Commission (NRC) and the Electric Power Research Institute (EPRI) are working cooperatively under a memorandum of understanding to validate welding residual stress predictions in pressurized water reactor primary cooling loop components containing dissimilar metal welds. These stresses are of interest as DM welds in pressurized water reactors are susceptible to primary water stress corrosion cracking (PWSCC) and tensile weld residual stresses are one of the primary drivers of this stress corrosion cracking mechanism. The NRC/EPRI weld residual stress (WRS) program currently consists of four phases, with each phase increasing in complexity from lab size specimens to component mock-ups and ex-plant material. This paper describes the Phase 1 program, which comprised an initial period of learning and research for both FEA methods and measurement techniques using simple welded specimens. The Phase 1 specimens include a number of plate and cylinder geometries, each designed to provide a controlled configuration for maximum repeatability of measurements and modeling. A spectrum of surface and through-wall residual stress measurement techniques have been explored using the Phase 1 specimens, including incremental hole drilling, ring-core, and x-ray diffraction for surface stresses and neutron diffraction, deep-hole drilling, and contour method for through-wall stresses. The measured residual stresses are compared to the predicted stress results from a number of researchers employing a variety of modeling techniques. Comparisons between the various measurement techniques and among the modeling results have allowed for greater insight into the impact of various parameters on predicted versus measured residual stress. This paper will also discuss the technical challenges and lessons learned as part of the DM weld materials residual stress measurements.

Effects of Cold Working and Heat Treatment on Caustic Stress Corrosion Cracking of Alloy 800M

2005 ◽  
Vol 297-300 ◽  
pp. 993-998 ◽  
Author(s):  
Chun Bo Huang ◽  
Guang Fu Li ◽  
Zhan Peng Lu ◽  
Jian Min Zeng ◽  
Wu Yang
Keyword(s):  
Heat Treatment ◽  
Residual Stress ◽  
Stress Corrosion ◽  
Stress Corrosion Cracking ◽  
Cold Working ◽  
Corrosion Cracking ◽  
Caustic Solution ◽  
Surface Films ◽  
Microstructure Examination ◽  
Increasing Temperature

The effects of cold working and heat treatment on caustic stress corrosion cracking (SCC) of mill annealed (MA) alloy 800M in boiling solution of 50%NaOH+0.3%SiO2+0.3%Na2S2O3 were investigated by means of microstructure examination, tensile test, X-ray stress analysis, SCC testing of C-rings, Auger electron spectroscopy (AES), scanning electron microscopy (SEM) and metallography. The microstructure of alloy 800M under tested conditions was austenite. With a train of 25% by cold working, the grains of alloy 800M became longer, yield strength (YS) and ultimate tensile strength (UTS) increased, elongation (δ ) decreased, residual stress and the susceptibility to SCC increased. With increasing temperature of heat treatment of alloy 800M with cold working, the grains became bigger , residual stress, YS and UTS decreased and δ increased, the susceptibility to SCC of alloy 800M decreased. In boiling caustic solution, SCC cracks on the surfaces of C-ring specimens polarized potentiostatically at –20mV/SCE initiated from pitting and propagated along grain boundaries. AES analysis indicated that the surface films on MA alloy 800M were enriched in nickel and depleted in iron and chromium.

Effect of Ultrasonic Impact Treatment on the Stress Corrosion Cracking of 304 Stainless Steel Welded Joints

2008 ◽  
Author(s):  
Gang Ma ◽  
Xiang Ling
Keyword(s):  
Residual Stress ◽  
Finite Element ◽  
Stainless Steel ◽  
Stress Corrosion ◽  
Stress Corrosion Cracking ◽  
Welded Joints ◽  
Corrosion Cracking ◽  
Coarse Grained ◽  
304 Stainless Steel ◽  
Ultrasonic Impact Treatment

High tensile weld residual stress is an important factor contributing to stress corrosion cracking (SCC). Ultrasonic impact treatment (UIT) can produce compressive stresses on the surface of welded joints that negate the tensile stresses to enhance the SCC resistance of welded joints. In the present work, X-ray diffraction method was used to obtain the distribution of residual stress induced by UIT. The results showed that UIT could cause a large compressive residual stress up to 325.9MPa on the surface of the material. A 3D finite element model was established to simulate the UIT process by using a finite element software ABAQUS. The residual stress distribution of the AISI 304 stainless steel induced by UIT was predicted by finite element analysis. In order to demonstrate the improvement of the SCC resistance of the welded joints, the specimens were immersed in boiling 42% magnesium chloride solution during SCC testing, and untreated specimen cracked after immersion for 23 hours. In contrast, treated specimens with different coverage were tested for 1000 hours without visible stress corrosion cracks. The microstructure observation results revealed that a hardened layer was formed on the surface and the initial coarse-grained structure in the surface was refined into ultrafine grains. The above results indicate that UIT is an effective approach for protecting weldments against SCC.

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