Initiation of Stress Corrosion Cracking on X-65 Linepipe Steels in Near-Neutral pH Environment

Author(s):  
M. Elboujdaini ◽  
Y.-Z. Wang ◽  
R. W. Revie

Initiation and early growth of stress-corrosion cracking of X-65 linepipe steel in near-neutral pH environment were studied in NS-4 solution saturated with N2/5%CO2. The occurrence of SCC is discussed in terms of: 1. Generation of an environment that causes cracks to initiate; 2. Initiation and early growth of cracks; and 3. Effect of the mechanical loading spectrum. SEM observations of cracks at specimen surfaces showed that stress-corrosion cracks were initiated at bottoms of corrosion pits. Pits that lead to initiation of SCC can develop from surface discontinuities, which can be geometrical, such as surface roughness, or metallurgical, such as inclusions, second phase particles, etc. The formation of large cracks resulting from coalescence of micro-cracks was studied.

Author(s):  
Frank Y. Cheng

A thermodynamic model was developed to determine the interactions of hydrogen, stress and anodic dissolution at the crack-tip during near-neutral pH stress corrosion cracking in pipelines. By analyzing the free-energy of the steel in the presence and absence of hydrogen and stress, it is demonstrated that a synergism of hydrogen and stress promotes the cracking of the steel. The enhanced hydrogen concentration in the stressed steel significantly accelerates the crack growth. The quantitative prediction of the crack growth rate in near-neutral pH environment is based on the determination of the effect of hydrogen on the anodic dissolution rate in the absence of stress, the effect of stress on the anodic dissolution rate in the absence of hydrogen, the synergistic effect of hydrogen and stress on the anodic dissolution rate at the crack-tip and the effect of the variation of hydrogen concentration on the anodic dissolution rate.


RSC Advances ◽  
2017 ◽  
Vol 7 (59) ◽  
pp. 36876-36885 ◽  
Author(s):  
Bingying Wang ◽  
Yu Yin ◽  
Zhiwei Gao ◽  
Zhenbo Hou ◽  
Wenchun Jiang

A developed surface enhancement technique, USRP, was applied on X80 pipeline steel and the stress corrosion cracking susceptibility was studied.


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