An Instrumented Field Corrosion Test Loop

Author(s):  
Alebachew Demoz ◽  
Kirk H. Michaelian ◽  
John Donini ◽  
Sankara Papavinasam ◽  
R. Winston Revie

A multi-purpose instrumented loop in line with an oil producing well is described. The loop has several ports for coupons which were replaced periodically. Some of the coupons were used for electrochemical monitoring in addition to weight loss and visual inspection. Weight loss, pit rate and all the electrochemical methods used gave corrosion rates that were dependent on the positions of the coupons inside the loop. The corrosion rate of the coupons increased from top to bottom. This order reflected the media and flow to which the coupons were exposed in a multi-phase producing well.

2011 ◽  
Vol 233-235 ◽  
pp. 648-651
Author(s):  
Ai Jun Wei ◽  
Bei Feng ◽  
Xin Zhang ◽  
Fu Yong Huo

In this corrosion test, simulated brine is used as corrosion medium, added different concentrations of aloe juice. Static weight-loss method is employed, meanwhile, we calculated corrosion rate of Q235 steel and researched on the corrosion inhibition effect of aloe in different temperatures. Results show that aloe is a good inhibitor, rate of corrosion inhibition can reach 80% or more and suitable for the temperature of work environment is less than 60 °C.


CORROSION ◽  
1979 ◽  
Vol 35 (11) ◽  
pp. 505-509 ◽  
Author(s):  
BARRY C. SYRETT ◽  
DIGBY D. MACDONALD

Abstract This work was stimulated by reports that electrochemical methods for measuring the polarization resistance of copper, nickel, or copper-nickel alloys in aqueous systems may lead to appreciable errors in the estimates of the corrosion rate. In the present work, the polarization resistance (Rp) of two copper-nickel alloys (90:10 Cu:Ni and 70:30 Cu:Ni) was monitored as a function of time in flowing sea water that contained 0.045, 0.85, 6.6, or 26.3 mg/dm3 dissolved oxygen. Rp values were obtained using the linear polarization, potential step, and AC impedance techniques. The total weight loss during the test period was calculated from the area under the 1/Rp versus time curve and compared with the measured weight loss. The experimental data support the validity of electrochemical methods for measuring corrosion rates of copper-nickel alloys in sea water, provided that a sufficient number of Rp measurements are made during the first 24 hours, and provided that proper consideration is given to the capacitive elements of the metal/solution interfacial impedance. Previous reports that electrochemical measurements may lead to underestimates of the corrosion rates are thought to have resulted primarily from undetected (and very high) corrosion rates at short exposure times. Reported overestimates of the corrosion rates are thought to have resulted from the use of a potential sweep rate that was too high (linear polarization technique), a time for current decay that was too short (potential step technique), or excitation frequencies that were insufficiently low (AC impedance technique).


Author(s):  
N. O. Adekunle ◽  
P. O. Aiyedun ◽  
S. I. Kuye ◽  
R. O. Adetunji

The unparalleled combinations of properties of aluminum and its alloy makes aluminum one of the most versatile, economical, and attractive metallic materials for a broad range of uses. This study was carried out to evaluate the influence of kerosene, petrol and water on the corrosion performance of three samples of aluminum 6063 alloy (A and B sourced locally while sample C is an imported material). The corrosion rate was determined both by weight loss and Potentiostatics method, and the microstructure of the samples after five weeks of immersion also was examined with the aid of an optical microscope. Samples A, B and C were immersed in the media for five (5) weeks duration. The cumulative corrosion rate was measured at the end of each week. The average corrosion rates using the weight loss method for A in petrol, kerosene and distilled water were 3.100E-4, 4.905 E-4 and 6.205 E-4; for B were 4.367 E-4, 2.703 E-4 and 2.147 E-4; and those of C were 4.550 E-4, 2.257 E-4 and 1.633 E-4 respectively. Similarly, the average corrosion rate using Potentiostatics method of A in petrol, kerosene and distilled water were 0.586E-3, 0.643E-3 and 0.454E-3; for B were 0.206E-3, 0.197E-3 and 0.298E-3; and those of C were 0.183E-3, 0.232E-3 and 0.407E-3 respectively. The average result showed that Sample A had the highest corrosion rate. The media which corroded the samples the most was petrol.


2013 ◽  
Vol 858 ◽  
pp. 177-183
Author(s):  
Bambang Widyanto ◽  
Altur Tambun

Microbiological Influenced Corrosion (MIC) is a common cause of metallic failure and currently known as one of the important case in pipeline failure. Otherwise it was often found also in cooling water system, in the equipment of pulp and paper, and oil and gas industry. Certain bacteria have a wide range of life condition and can be found anywhere. Sulfate Reducing Bacteria (SRB) is a bacteria that was frequently found as a cause of corrosion in steel surface by creating pits. In this research, the corrosion test was done by using one species of SRB which is Desulfovibrio Baculatus. The water that contains bacteria growth medium (API Sulfate Broth) is used as a media for API 5L X65 steel corrosion test. Sulfate for the growing of SRB was added in the solution in 8.56 , 17.12 , 42.8 and 85.64 ppm concentration, and the immersion test was done during 1,7,14,21 days. The source of sulfate is FeSO4.7H2O, and this compound was considered also as a source of Iron (II). The result shows that the weight loss is increase with increasing of immersion period. Between 7-14 days of immersion time, the increase of weight loss that present a corrosion rate attains the highest condition and decrease again after a longer time of immersion period. Morphologic observation reveals that the corrosion product consists of Iron Oxide and biological deposits that were formed at the beginning of corrosion test, and continuing with the formation of Iron Sulfide at a longer period of immersion. The formation of Iron Sulfide was associated with the increase of corrosion rate. Keywords: MIC, SRB, Desulfovibrio Baculatus, Immersion, FeSO4 content.


2013 ◽  
Vol 318 ◽  
pp. 312-315
Author(s):  
Xiong Yang ◽  
Jian Tong ◽  
Xiao Ming Li

The effects of concentration and temperature of hydrochloric acid and etching time on the corrosion rates of 434 stainless steel fibres are investigated by using weight loss method,The results show that with the concentration of hydrochloric acid increase,the temperature of hydrochloric acid rise, etching time prolonging, the corrosion rate of 434 stainless steel fibres is increased, and the corrosion rate of smalldimension of 434 stainless steel fibres faster.Though Cl- of hydrochloric acid doesn’t take direct part in the reaction,the corrosion rate is significantly accelerated.


Author(s):  
Okpaga D. M

Abstract: This work deals with the inhibitive characteristics of Moringa oleifera fruits and leaves extracts in Hydrochloric Acid solution and Sodium Hydroxide solution respectively on the corrosion of mild steel. This was carried out using weight loss and polarization techniques. The effects of immersion time, the effect of acid and alkaline concentration on the corrosion behavior of mild steel in 1.0M HCl and 1.0 NaOH with addiction of extracts were deduced. The fruits which were dried and grounded to powder of 10g and the leaves which range from 25cm3 to 100cm3 were used for this study. The corrosion rate was very high in the absence of inhibitors (Moringa oleifera fruits and the leaves extracts). The mild steel was cut into coupon averaging a total surface area of 4.262cm2 . The sample was weighed and immersed into a beaker containing 1.0M NaOH with different volumes of moringa leaves and 1.0M HCl with 10g dried concentrated powdered moringa fruits with coupons removed every 7 days for weight loss measurements till 4 weeks. The corrosion rates were found to be decreased by 83% in 1.0M HCl and 78% in 1.0M NaOH respectively, values of inhibition efficiency (ࣁ (%were calculated from weight loss. The results obtained showed that the Moringa oleifera fruits and leaves extracts could serve as effective inhibitors on the corrosion of mild steel in HCl and NaOH respectively. Keywords: Moringa oleifera, Corrosion rate, Weight loss, Mild steel, Inhibitor.


2011 ◽  
Vol 690 ◽  
pp. 365-368 ◽  
Author(s):  
Zhi Ming Shi ◽  
Andrej Atrens

Plug-in specimens enable measurement of reliable Mg polarization curves. Cathodic polarization curves were measured for high purity Mg in 3.5% NaCl saturated with Mg(OH)2using (i) mounted specimens and (ii) plug-in specimens. Polarization curves yielded the corrosion current densityicorrand the corresponding corrosion ratePi, which was compared with corrosion rates evaluated from hydrogen evolution,PH, and weight loss,PW. Mounted specimens producePivalues three times larger than plug-in specimens, due to crevice corrosion in the mounted specimens. Plug-in specimens had no crevice and allow simultaneous measurement ofPHandPi. Piwas less thanPHand indicated an apparent valence of 1.45 in support of the existence of the uni-positive Mg+ion.


2014 ◽  
Vol 548-549 ◽  
pp. 242-246 ◽  
Author(s):  
K. Rithdang ◽  
P. Wongbunyakul ◽  
P. Jamawatr ◽  
P. Lortrakul ◽  
G. Lothongkum

Under-deposit corrosion in cooling water system is often found in industries. The under-deposit corrosion rate in cooling water system is rarely found in a literature. The mechanism depends on the metal, types of deposit and corrosive species in the cooling water system. In this study, the under-deposit corrosion rates of carbon steel in cooling water at various times were determined by weight loss, profilometric and electrical resistance methods at 40C. From this experiment, these three methods showed the consistent results. The under-deposit corrosion rates of carbon steel were about 0.1-0.2 mm/y.


1970 ◽  
Vol 25 ◽  
pp. 75-82
Author(s):  
Basu Ram Aryal ◽  
Jagadeesh Bhattarai

The synergistic effect of the simultaneous additions of tungsten and zirconium in thesputter-deposited amorphous or nanocrystalline Zr-(12-21)Cr-W alloys is studied in 0.5 MNaCl solution open to air at 25°C using corrosion tests and open circuit potentialmeasurements. Corrosion rates of the sputter-deposited Zr-(12-21)Cr-W alloys containing10-80 at % tungsten (that is, 0.95-1.85 x 10-2 mm.y-1) are more than one order of magnitudelower than that of the sputter-deposited tungsten and even lower than those of zirconium aswell as chromium in 0.5 M NaCl solution. The addition of 8-73 at % zirconium content inthe sputter-deposited binary W-(12-21)Cr alloys seems to be more effective to improve thecorrosion-resistant properties of the sputter-deposited ternary Zr-Cr-W alloys containing12-21 at % chromium in 0.5 M NaCl solution. The sputter-deposited Zr-(17-21)Cr-W alloyscontaining an adequate amounts of zirconium metal showed the more stable passivity andshowed higher corrosion resistance than those of alloy-constituting elements in 0.5 M NaClsolution open to air at 25°C.Keywords: Zr-(12-21)Cr-W alloys, sputter deposition, corrosion test, open circuit potential,0.5 M NaCl.DOI:  10.3126/jncs.v25i0.3305Journal of Nepal Chemical Society Volume 25, 2010 pp 75-82


2011 ◽  
Vol 47 (7) ◽  
pp. 921-925 ◽  
Author(s):  
V. I. Kichigin ◽  
O. M. Perel’man ◽  
A. I. Rabinovich ◽  
N. V. Bezmaternykh ◽  
O. P. Koshcheev

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