Effect of Asphaltene Deposition on the Internal Corrosion in Transmission Lines

1996 ◽  
Author(s):  
José L. Morales ◽  
Alfredo Vllorla ◽  
Carlos A. Palacios T.
Keyword(s):  
Cathodic Protection ◽  
Transmission Lines ◽  
Separation Process ◽  
Asphaltene Precipitation ◽  
Ongoing Research ◽  
Internal Corrosion ◽  
Partial Pressures ◽  
Asphaltene Deposition ◽  
External Corrosion ◽  
Water Saturated

Crude oil from Norte de Monagas field, in Venezuela, contains large amounts of asphaltenes, some of them are very unstable with tendency to precipitate. Because of liquid is carried over from the separation process in the flow stations, asphaltenes are also present in the gas gathering and transmission lines, precipitating on inner wall of pipelines. The gas gathering and transmission lines contain gas with high partial pressures of CO2, some H2S and are water saturated; therefore inhibitors are used to control the internal corrosion. There is uncertainty on how inhibitors perform in the presence of asphaltene deposition. To protect the pipelines from external corrosion, cathodic protection is used. Since asphaltenes have polar properties, there exists an uncertainty on whether it enhances asphaltene precipitation and deposition. The purpose of this paper to describe the causes that enhance asphaltene deposition on gas and some of the preliminary result from an ongoing research project carried out by Intevep and Corpoven.

Risk-Based Integrity Decision Making for Lateral Piping

2018 ◽  
Author(s):  
Amanda Kulhawy ◽  
Alex Nemeth ◽  
Garry Sommer ◽  
Sherif Hassanien
Keyword(s):  
Decision Making ◽  
Transmission Lines ◽  
High Pressures ◽  
Internal Corrosion ◽  
Pressure Cycling ◽  
Integrity Management ◽  
Effective Decision ◽  
The Difference ◽  
Effective Decision Making ◽  
External Corrosion

Integrity reliability science plays a major role in the integrity management of transmission piping, which is piping that traverses long distances across the continent, at high pressures, and can experience high pressure cycling. This science can be applied to non-transmission piping such as lateral piping, which traverses between a transmission line and a facility, or between two facilities, at lower pressures and with lower pressure cycling. Laterals are susceptible to the same threats as transmission lines (internal corrosion, external corrosion, cracking, geotechnical hazards, etc.). However, due to their operation, laterals are only highly susceptible to internal and external corrosion. While site specific conditions may result in a high susceptibility of a geotechnical hazard, this threat is outside of the scope of this paper. On transmission piping, corrosion is generally managed with In-Line Inspection (ILI), Non-Destructive Examination (NDE), and corresponding repairs (e.g. sleeving) to assess and mitigate. With laterals, there can be limited ILI and NDE data. As such, the data used in the quantitative reliability framework for these threats is not available and this creates a gap in the process. This paper addresses this gap through the application of semi-quantitative reliability analysis for internal and external corrosion on laterals along with a risk-based integrity decision making framework. The proposed approach is designed to enable pipeline and facility operators to make effective decisions around lateral integrity programs given the available data, and to better understand the limitations of integrity decision making. Moreover, the paper expands the discussion around the difference between risk-informed and risk-based integrity decision making in order to provide a guideline for optimal and safe integrity management programs considering different criteria. Case studies that include limited or no ILI or NDE information are used to demonstrate the application of semi-quantitative and quantitative reliability assessment of laterals along with the exploration of challenges in calibrating the two assessment methods to provide an example of how reliability science can be applied to laterals and how this can be used in effective decision making given such limitations.

Corrosion of 310S Austenitic Stainless Steel in Simulated Rocket Combustion Gas

2018 ◽  
Vol 765 ◽  
pp. 155-159
Author(s):  
Tosapolporn Pornpibunsompop ◽  
Purit Thanakijkasem
Keyword(s):  
Stainless Steel ◽  
Austenitic Stainless Steel ◽  
Testing Temperature ◽  
Chemical Information ◽  
Metal Chlorides ◽  
Internal Corrosion ◽  
Combustion Gas ◽  
Wet Condition ◽  
External Corrosion ◽  
Peeling Off

High temperature corrosion of 310S austenitic stainless steel in simulated rocket combustion gas at 900 degree Celsius was investigated and discussed in this paper. 310S austenitic stainless steel was chosen because it was used for building some components of a rocket launcher. The corrosive atmosphere was prepared by mixing of hydrochloric acid and distilled water with 5.5 mole per liter then, boiling that solution and feeding into a corrosion testing chamber. The chamber was set up at 900 degree Celsius with duration 210 hrs. After testing, the corroded specimen was microscopically characterized by OM and SEM/EDS techniques. The corrosion layer was classified into three main sublayers: peeling-off scale, external corrosion sublayer, and internal corrosion sublayer. The local chemical information was analyzed by XRD (in case of peeling-off scale) and SEM/EDS (in case of external and internal corrosion sublayers). The peeling off scale mainly comprised Fe2O3and Fe21.3O32ferrous oxides because they needed much oxygen consumption to exist. In case of external and internal sublayers, there were a lot of pore tunnels and corrosion products. Chlorine and/or hydrogen chloride would penetrate through a passive film and, then, metal chlorides was formed on both external and internal corrosion sublayers. Metal chlorides would volatile because of their lower evaporation temperature than the testing temperature. Moreover, they were oxidized by oxygen in wet condition and resulted metal oxides mostly remaining on the external corrosion sublayer.

Integrity Assessment of Non-Piggable Pipeline Through Direct Assessment

2013 ◽  
Author(s):  
Jai Prakash Sah ◽  
Mohammad Tanweer Akhter
Keyword(s):  
Hydrostatic Pressure ◽  
Natural Gas ◽  
Stress Corrosion ◽  
Health Assessment ◽  
Assessment Method ◽  
Pipeline System ◽  
Internal Corrosion ◽  
Integrity Assessment ◽  
Direct Assessment ◽  
External Corrosion

Managing the integrity of pipeline system is the primary goal of every pipeline operator. To ensure the integrity of pipeline system, its health assessment is very important and critical for ensuring safety of environment, human resources and its assets. In long term, managing pipeline integrity is an investment to asset protection which ultimately results in cost saving. Typically, the health assessment to managing the integrity of pipeline system is a function of operational experience and corporate philosophy. There is no single approach that can provide the best solution for all pipeline system. Only a comprehensive, systematic and integrated integrity management program provides the means to improve the safety of pipeline systems. Such programme provides the information for an operator to effectively allocate resources for appropriate prevention, detection and mitigation activities that will result in improved safety and a reduction in the number of incidents. Presently GAIL (INDIA) LTD. is operating & maintaining approximately 10,000Kms of natural gas/RLNG/LPG pipeline and HVJ Pipeline is the largest pipeline network of India which transports more than 50% of total gas being consumed in this country. HVJ pipeline system consists of more than 4500 Kms of pipeline having diameter range from 04” to 48”, which consist of piggable as well as non-piggable pipeline. Though, lengthwise non-piggable pipeline is very less but their importance cannot be ignored in to the totality because of their critical nature. Typically, pipeline with small length & connected to dispatch terminal are non-piggable and these pipelines are used to feed the gas to the consumer. Today pipeline industries are having three different types of inspection techniques available for inspection of the pipeline. 1. Inline inspection 2. Hydrostatic pressure testing 3. Direct assessment (DA) Inline inspection is possible only for piggable pipeline i.e. pipeline with facilities of pig launching & receiving and hydrostatic pressure testing is not possible for the pipeline under continuous operation. Thus we are left with direct assessment method to assess health of the non-piggable pipelines. Basically, direct assessment is a structured multi-step evaluation method to examine and identify the potential problem areas relating to internal corrosion, external corrosion, and stress corrosion cracking using ICDA (Internal Corrosion Direct Assessment), ECDA (External Corrosion Direct Assessment) and SCCDA (Stress Corrosion Direct Assessment). All the above DA is four steps iterative method & consist of following steps; a. Pre assessment b. Indirect assessment c. Direct assessment d. Post assessment Considering the importance of non-piggable pipeline, integrity assessment of following non piggable pipeline has done through direct assessment method. 1. 30 inch dia pipeline of length 0.6 km and handling 18.4 MMSCMD of natural gas 2. 18 inch dia pipeline of length 3.65 km and handling 4.0 MMSCMD of natural gas 3. 12 inch dia pipeline of length 2.08 km and handling 3.4 MMSCMD of natural gas In addition to ICDA, ECDA & SCCDA, Long Range Ultrasonic Thickness (LRUT-a guided wave technology) has also been carried out to detect the metal loss at excavated locations observed by ICDA & ECDA. Direct assessment survey for above pipelines has been conducted and based on the survey; high consequence areas have been identified. All the high consequence area has been excavated and inspected. No appreciable corrosion and thickness loss have observed at any area. However, pipeline segments have been identified which are most vulnerable and may have corrosion in future.

Effective Removal of Asphaltene Deposition in Metal-Capillary Tubes

SPE Journal ◽  
2016 ◽  
Vol 21 (05) ◽  
pp. 1747-1754 ◽  
Author(s):  
Sara M. Hashmi ◽  
Abbas Firoozabadi
Keyword(s):  
Organic Acid ◽  
Laboratory Scale ◽  
Asphaltene Precipitation ◽  
Aromatic Solvent ◽  
Benzene Sulfonic Acid ◽  
Chemical Treatments ◽  
Effective Removal ◽  
Dodecyl Benzene Sulfonic Acid ◽  
Asphaltene Deposition ◽  
Petroleum Fluid

Summary We describe asphaltene deposition and removal processes in metal capillaries. We induce asphaltene precipitation by adding an asphaltene precipitant, heptane, to a petroleum fluid. The mixture is then injected through a laboratory-scale capillary and allowed to deposit. We assess the reversal of the deposition by means of the use of two separate chemical treatments: (1) a strong organic acid surfactant and (2) an aromatic solvent. The strong organic acid surfactant, dodecyl benzene sulfonic acid (DBSA), was shown to completely dissolve asphaltenes by means of acid-base chemistry reactions at heteroatomic sites on the asphaltene molecules. We investigate the use of DBSA as an efficient removal agent, injecting it in a mixture of petroleum fluid after the deposit was already formed. An aromatic solvent, toluene, is also investigated in such a fashion to assess its ability in removing deposited asphaltenes. We find that DBSA can effectively remove asphaltene deposits within one pore-volume (PV) of injection and at concentrations roughly ten times less than that required by an aromatic solvent such as toluene. To the best of our knowledge, our current study is the first laboratory-scale investigation with surfactant chemicals to reverse asphaltene deposition in capillaries.

Laboratory Investigation of Permeability Impairment Caused by Asphaltene Precipitation during Screening for Gas-Injection Enhanced Oil Recovery and Pressure Change in a Major Gulf of Mexico Field

SPE Journal ◽  
2021 ◽  
pp. 1-21
Author(s):  
M. R. Fassihi ◽  
E. Turek ◽  
M. Matt Honarpour ◽  
D. Peck ◽  
R. Fyfe
Keyword(s):  
Gulf Of Mexico ◽  
Gas Injection ◽  
Rock Surface ◽  
Permeability Reduction ◽  
Test Results ◽  
Asphaltene Precipitation ◽  
The Core ◽  
Asphaltene Deposition ◽  
Core Permeability ◽  
Permeability Impairment

Summary As part of studying miscible gas injection (GI) in a major field within the Green Canyon protraction area in the Gulf of Mexico (GOM), asphaltene-formation risk was identified as a key factor affecting a potential GI project. The industry has not conducted many experiments to quantify the effect of asphaltenes on reservoir and well performance under GI conditions. In this paper we discuss a novel laboratory test for evaluating the asphaltene effect on permeability. The goals of the study were to define the asphaltene-precipitation envelope using blends of reservoir fluid and injection gas, and measure permeability reduction caused by asphaltene precipitation in a core under GI. To properly analyze the effect of GI, a suite of fluid-characterization studies was conducted, including restored-oil samples, compositional analysis, constant composition expansion (CCE), and differential vaporization. Miscibility conditions were defined through slimtube-displacement tests. Gas solubility was determined through swelling tests complemented by asphaltene-onset-pressure (AOP) testing. The unique procedure was developed to estimate the effect of asphaltene deposition on core permeability. The 1-ft-long core was saturated with the live-oil and GI mixture at a pressure greater than the AOP, and then pressure was depleted to a pressure slightly greater than the bubblepoint. Several cycles of charging and depletion were conducted to mimic continuous flow of oil along the path of injected gas and thereby to observe the accumulation of asphaltene on the rock surface. The test results indicated that during this cyclic asphaltene-deposition process, the core permeability to the live mixture decreased in the first few cycles but appeared to stabilize after Cycle 5. The deposited asphaltenes were analyzed further through environmental scanning electron microscopy (ESEM), and their deposition was confirmed by mass balance before and after the tests. Finally, a relationship was established between permeability reduction and asphaltene precipitation. The results from the asphaltene-deposition experiment show that for the sample, fluids, and conditions used, permeability is impaired as asphaltene flocculates and begins to coat the grain surfaces. This impairment reaches a plateau at approximately 40% of the initial permeability. Distribution of asphaltene along the core was measured at the end by segmenting the core and conducting solvent extraction on each segment. Our recommendation is numerical modeling of these test results and using this model to forecast the magnitude of the permeability impairment in a reservoir setting during miscible GI.

Evaluation of Methods for Detecting and Monitoring of Corrosion Damage in Risers

2005 ◽  
Vol 127 (3) ◽  
pp. 244-254 ◽  
Author(s):  
M. G. Lozev ◽  
R. W. Smith ◽  
B. B. Grimmett
Keyword(s):  
Corrosion Damage ◽  
Localized Corrosion ◽  
General Corrosion ◽  
Splash Zone ◽  
Manufacturing Companies ◽  
Internal Corrosion ◽  
Remaining Service Life ◽  
Torsional Waves ◽  
Offshore Pipeline ◽  
External Corrosion

Offshore pipeline failure statistics have been collected for more than 30 years now and illustrate that the riser predominantly fails as a result of corrosion. The consistent wetting and drying in the splash zone combined with defects in the coatings are the usual contributors to the problem. Risers are inspected at some determined frequency and can be done by internal and external methods. Inspecting by either means brings into account caveats and limitations from the technology used as well as human factors. For example, external inspections can be inefficient and inaccurate with some tools missing defects in areas of coating disbondment. In addition, internal inspections sometimes create false positives and can miss defects. These inaccuracies in the technologies or the techniques used may miss defects that eventually lead to failure. On the other hand, using corrosion mapping and fitness-for-service (FFS) assessment from the data collected, along with the inherent conservatism of this data from limited measurement accuracy, may result in the premature replacement of risers. A literature search is being conducted to review existing riser inspection methods and identify candidate nondestructive methods for riser inspection. These methods should be capable of detecting and monitoring general corrosion, localized corrosion pitting, and stress-corrosion cracking (sulfide or hydrogen induced) as external or internal corrosion damage. Thus far, this search has found that assessing the remaining service life of aging risers is largely dependent on the accuracy of analyzing corrosion damage to the riser surface in the atmospheric, splash (tidal), submerged, and buried environmental zones. The accuracy of each technology was analyzed. The capabilities and limitations of each method/technique used for riser inspection are summarized. The investigation is focused on long- and short-range ultrasonic techniques used for initial screening and corrosion mapping. These techniques can be deployed to detect a significant reduction in wall thickness using guided and torsional waves or to map accurately a corrosion damage using single/multiple transducers and phased-array probes in manual or automated mode. A pulsed eddy-current technique that uses a stepped or pulsed input signal for the detection of corrosion areas under insulation (CUI) is also being evaluated. This allows the detection of wall-thinning areas in the riser without removing the outside coatings. In addition, it is found that filmless, real-time, and digital radiography can be used to find internal and external corrosion defects in an insulated splash zone while the riser remains in service. A survey of nondestructive evaluation (NDE) manufacturing companies, NDE inspection companies, and operating companies was completed to collect information about current instrumentation and inspection/operators’ experience for riser inspection. Examples of advanced riser inspection instrumentation and field results are included. The ability of the candidate technologies to be adapted to riser variations, the stage of standardization, and costs are also discussed.

Intrinsic Protection of Water Mains

CORROSION ◽  
1956 ◽  
Vol 12 (10) ◽  
pp. 66-72
Author(s):  
M. UNZ
Keyword(s):  
Prestressed Concrete ◽  
Irrigation System ◽  
Complete Solution ◽  
Water Supply Systems ◽  
Chemical Absorption ◽  
Internal Corrosion ◽  
Trunk Line ◽  
Water Mains ◽  
External Corrosion ◽  
Supply Systems

Abstract Inherent protection against corrosion hazards is essential in water supply systems. External corrosion is reduced by the use of cement coatings and separation of heterogeneous line sections. Internal galvanic action, especially in prestressed concrete structures, is eliminated by separation or matching of materials. A complete solution of the problem is attained only by electrically nonconducting pipe. Internal corrosion and blocking of pipes can be prevented by water treatment. Investigations on an irrigation system confirm that bare or bituminous coated steel components are anodic to cement coated lines. Irrigation outlets during the dry season also usually are anodic to the trunk line. In anodic areas a chemical absorption process takes place in the cement coating, which intrinsically increases its protective value. The presence of an adequate layer of pure cement over the steel surface is essential for this protective effect. 7.2

Validating ILI Accuracy Using API 1163

2014 ◽  
Author(s):  
Lucinda Smart ◽  
Harvey Haines
Keyword(s):  
Burst Pressure ◽  
Metal Loss ◽  
Internal Corrosion ◽  
Know How ◽  
Pressure Calculation ◽  
Loss Data ◽  
Pipeline Segment ◽  
External Corrosion ◽  
Corrosion Pits

It is important to validate the accuracy of in-line inspection (ILI) tools to know how many excavations are needed to maintain the integrity of a pipeline segment. Performing sufficient excavations is important to ensure there are no defects left in the pipeline that have even a remote chance of failure. In some cases additional excavations may be necessary to ensure safety where in other cases no excavations may be necessary. This paper looks at using spatially recorded metal-loss data collected “in-the-ditch” to measure the accuracy of ILI tool results. Examples of spatial in-ditch data are laser scans for external corrosion and UT scans for internal corrosion. Spatially mapped metal loss, because all of the corrosion area is mapped, has the advantage of allowing more comparisons to be made for a given corrosion area and also allows the interaction among corrosion pits to be studied for examining burst pressure calculation accuracy. From our studies we find the depth error for shallow corrosion 10%–20% wt deep is often not representative of deeper corrosion in the same pipeline and the interaction criteria for ILI tools needs to be larger than the interaction criteria for in-ditch data. Examples are shown with these types of results, and by interpreting the results in conjunction with API 1163, certain ILI runs are shown that require no excavations where others may require additional excavations than suggested by normal +/−10% wt ILI data.

Using Ultrasound to Gauge Pipeline Internal Corrosion With Coating for ICDA

2006 ◽  
Author(s):  
Qingshan Feng ◽  
Zupei Yang
Keyword(s):  
Test Time ◽  
Thickness Gauge ◽  
Internal Corrosion ◽  
Direct Assessment ◽  
Metal Thickness ◽  
Integrity Management ◽  
External Corrosion ◽  
Key Steps ◽  
Thickness Measurements ◽  
Non Destructive

Internal corrosion direct assessment (ICDA) for pipeline enhances the abilities to assess internal corrosion in pipeline and is based on the principle that corrosion is most likely where water first accumulates. ICDA employs the same four-step process as all other direct assessment methods. The important step is direct examinations: the pipeline is excavated and examined at locations prioritized to have the highest likelihood of corrosion. A variety of inservice non-destructive examination processes are available to pipeline operators to inspect for internal corrosion. Manual assessment of internal corrosion is considered more challenging than normal external corrosion assessments since the corrosion feature is not visible and must be interpreted by the ultrasonic response, but in the past ultrasonic test need always remove the coating and then measure on the surface of bare pipe, which brings the measurement point of the pipe body more risk because of weaker quality of patch coating. Recently, advances in the design of ultrasonic corrosion thickness gauges utilizing dual element transducers have made it possible to take accurate metal thickness measurements while coatings need not to be removed. This feature is often referred to as echo-to-echo thickness measurements. Using the ultrasound thickness gauge to measure pipeline internal corrosion while external coatings need not to be removed can keep the integrity of coating, make pipeline operating and monitoring more economical and improve inspection activities to estimate corrosion in pipelines for ICDA. Gauge equipment requirement, Measurement procedures and Accuracy were validated in laboratory. How to arrange the gauge locations, interval test time and data treatment and analysis also are the key steps of ICDA for integrity management.

External Corrosion and Internal Corrosion Direct Assessment Validation Project

2004 ◽  
Author(s):  
Carl A. Mikkola ◽  
Christina L. Case ◽  
Kevin C. Garrity
Keyword(s):  
Natural Gas ◽  
Final Report ◽  
Internal Corrosion ◽  
Assessment Development ◽  
Direct Assessment ◽  
Natural Gas Pipeline ◽  
Assessment Validation ◽  
External Corrosion ◽  
Development And Validation ◽  
To Receive

In January, 2003, Enbridge Midcoast Energy, L.P., a subsidiary of Enbridge Energy Partners, L.P., implemented a comprehensive direct assessment development and validation project for its Natural Gas Business segment; a project intended to demonstrate the validity of External Corrosion and Internal Corrosion Direct Assessment (ECDA and ICDA). The work began in January 2003 and was concluded in June 2003. The primary goal of the project was to demonstrate that External Corrosion Direct Assessment and Internal Corrosion Direct Assessment as performed in compliance with the NACE and INGAA methodologies could be used to effectively verify and manage the integrity of non-piggable and non-interruptible natural gas pipeline segments. The programs were validated by in-line inspection (ILI) using high-resolution magnetic flux leakage tools and field verification digs. The objective of the project was to receive approval from the Texas Railroad Commission to use direct assessment (“DA”), where demonstrated to be appropriate, for integrity verification and management of pipeline systems that are not verifiable through other approved means. The Enbridge DA Validation Project was successfully completed and is considered to be one of the leading DA validation projects undertaken to date in the U.S. A total of 12,000 manhours and over $1MM was expended in performing the pre-assessment to identify a candidate pipeline, develop detailed procedures for DA execution and implementation, perform indirect surveys, modify pipe and complete cleaning pig runs, gauge pig runs, dummy pig runs, intelligent pig runs, perform detailed direct examinations and perform detailed analysis of the results including the preparation of the final report. This paper is intended to describe the steps that Enbridge took in validating DA.

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