Studying of Contact Angle Friction and Contact Angle Hysteresis (CAH) Though Force Measurements

2012 ◽  
Author(s):  
Qi Ni ◽  
Timo Marschke ◽  
Samuel Steele ◽  
Najafi Seyed ◽  
Nathan B. Crane
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Force Measurements ◽  
Droplet Motion ◽  
Characterization Methods ◽  
Receding Contact ◽  
Novel Method ◽  
Contact Line Friction

A novel method of measuring contact line friction and contact angle hysteresis is described. In this method, a droplet is constrained between two surfaces while the surface of interest initiates motion. The results are compared to conventional characterization methods such as measuring the angle of inclined plane for droplet motion and measuring advancing and receding contact angles by infusing/withdrawing liquid from the substrate. At slow speeds, the proposed method provides a measure of the hysteresis but can also capture information about the contact line friction and viscous affects. Droplet force dependence on droplet size (height/width) is also investigated.

Forces Acting on Sessile Droplet on Inclined Surfaces

2009 ◽  
Author(s):  
S. Ravi Annapragada ◽  
Jayathi Y. Murthy ◽  
Suresh V. Garimella
Keyword(s):  
Contact Angle ◽  
Droplet Size ◽  
Contact Line ◽  
Contact Area ◽  
Contact Angles ◽  
Force Model ◽  
Sessile Droplet ◽  
Droplet Motion ◽  
Droplet Shape ◽  
Receding Contact

Although many analytical, experimental and numerical studies have focused on droplet motion, the mechanics of the droplet while still in its static state, and just before motion starts, are not well understood. A study of static droplets would shed light on the threshold voltage (or critical inclination) for initiating electrically (or gravitationally) induced droplet motion. Before the droplet starts to move, the droplet shape changes such that the forces acting at the triple contact line balance the actuation forces. These contact line forces are governed by the contact angles along the contact line. The contact angle varies from an advancing angle at the leading edge to a receding angle at the trailing edge of the droplet. The present study seeks to understand and predict these forces at the triple contact line. The droplet shape, as well as the advancing and receding contact angles, is experimentally measured as a function of droplet size under the action of a gravitational force at different inclination angles. The advancing and receding contact angles are correlated with static contact angle and Bond number. A Volume of Fluid - Continuous Surface Force model with varying contact angles along the triple contact line is developed to predict the same. The model is first verified against a two-dimensional analytical solution. It is then used to simulate the shape of a sessile droplet on an incline at various angles of inclination and to determine the critical angle of inclination as a function of droplet size. Good agreement is found between experimental measurements and predictions. The contact line profile and contact area are also predicted. The contact area predictions based on a spherical-cap assumption are also compared against the numerical predictions.

The Surface Modification with Fluorocarbon Thin Films for the Prevention of Stiction in Mems

1998 ◽  
Vol 518 ◽  
Author(s):  
Sang-Ho Lee ◽  
Myong-Jong Kwon ◽  
Jin-Goo Park ◽  
Yong-Kweon Kim ◽  
Hyung-Jae Shin
Keyword(s):  
Contact Angle ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Fluorocarbon Films ◽  
Perfluorodecanoic Acid ◽  
Large Hysteresis ◽  
Static Contact ◽  
Receding Contact ◽  
Highly Hydrophobic ◽  
Receding Contact Angle

AbstractHighly hydrophobic fluorocarbon films were prepared by the vapor phase (VP) deposition method in a vacuum chamber using both liquid (3M's FC40, FC722) and solid sources (perfluorodecanoic acid (CF3(CF2)8COOH), perfluorododecane (C12F26)) on Al, Si and oxide coated wafers. The highest static contact angles of water were measured on films deposited on aluminum substrate. But relatively lower contact angles were obtained on the films on Si and oxide wafers. The advancing and receding contact angle analysis using a captive drop method showed a large contact angle hysteresis (ΔH) on the VP deposited fluorocarbon films. AFM study showed poor film coverage on the surface with large hysteresis. FTIR-ATR analysis positively revealed the stretching band of CF2 groups on the VP deposited substrates. The thermal stability of films was measured at 150°C in air and nitrogen atmospheres as a function of time. The rapid decrease of contact angles was observed on VP deposited FC and PFDA films in air. However, no decrease of contact angle on them was observed in N2.

Surface Topography Induced Ultrahydrophobic Behavior: Effect of Three-Phase Contact Line Topology

2006 ◽  
Author(s):  
Neeharika Anantharaju ◽  
Mahesh Panchagnula ◽  
Wayne Kimsey ◽  
Sudhakar Neti ◽  
Svetlana Tatic-Lucic
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Anomalous Behavior ◽  
Contact Angles ◽  
Wet Etching ◽  
Surface Geometry ◽  
Wetting Behavior ◽  
Void Fractions ◽  
Three Phase ◽  
Receding Contact

The wettability of silicon surface hydrophobized using silanization reagents was studied. The advancing and receding contact angles were measured with the captive needle approach. In this approach, a drop under study was held on the hydrophobized surface with a fine needle immersed in it. The asymptotic advancing and receding angles were obtained by incrementally increasing the volume added and removed, respectively, until no change in angles was observed. The values were compared with the previously published results. Further, the wetting behavior of water droplets on periodically structured hydrophobic surfaces was investigated. The surfaces were prepared with the wet etching process and contain posts and holes of different sizes and void fractions. The surface geometry brought up a scope to study the Wenzel (filling of surface grooves) and Cassie (non filling of the surface grooves) theories and effects of surface geometry and roughness on the contact angle. Experimental data point to an anomalous behavior where the data does not obey either Wenzel or Cassie type phenomenology. This behavior is explained by an understanding of the contact line topography. The effect of contact line topography on the contact angle was thus parametrically studied. It was also inferred that, the contact angle increased with the increase in void fraction. The observations may serve as guidelines in designing surfaces with the desired wetting behavior.

Degradation of Hydrophobic Surface Coatings Under Water Exposure

2018 ◽  
Author(s):  
Matthew A. Trapuzzano ◽  
Rasim Guldiken ◽  
Andrés Tejada-Martínez ◽  
Nathan B. Crane
Keyword(s):  
Contact Angle ◽  
Material Selection ◽  
Contact Angle Hysteresis ◽  
Hydrophobic Surface ◽  
Contact Angles ◽  
Water Exposure ◽  
Angle Measurements ◽  
Degradation Rates ◽  
Contact Angle Measurements ◽  
Receding Contact

Many important processes depend on the wetting of liquids on surfaces. Wetting is commonly controlled through material selection, coatings, and/or surface texture, however these means are sensitive to environmental conditions. Some “hydrophobic” fluoropolymer coatings are sensitive to extended water exposure as evidenced by declining contact angles and increasing contact angle hysteresis. Understanding degradation of these coatings is critical to processes that employ them. To accomplish this, contact angle measurements were taken before, during, and after slides coated with FluoroSyl 3750 or Cytop were submerged in water, or vibrated while covered in water. Both methods demonstrated similar changes in advancing contact angle though vibration increased degradation rates significantly. However, it does not simply accelerate the process as different trends are apparent in receding contact angles. The FluoroSyl 3750 showed no clear degradation under either condition. Surface profilometry did not detect any surface morphology differences that might cause contact angle change.

scholarly journals Thick drops climbing uphill on an oscillating substrate

2018 ◽  
Vol 840 ◽  
pp. 131-153 ◽  
Author(s):  
J. T. Bradshaw ◽  
J. Billingham
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Boundary Integral ◽  
Static Contact Angle ◽  
Rise Velocity ◽  
Contact Lines ◽  
Weakly Nonlinear ◽  
Static Contact

Experiments have shown that a liquid droplet on an inclined plane can be made to move uphill by sufficiently strong, vertical oscillations (Brunet et al., Phys. Rev. Lett., vol. 99, 2007, 144501). In this paper, we study a two-dimensional, inviscid, irrotational model of this flow, with the velocity of the contact lines a function of contact angle. We use asymptotic analysis to show that, for forcing of sufficiently small amplitude, the motion of the droplet can be separated into an odd and an even mode, and that the weakly nonlinear interaction between these modes determines whether the droplet climbs up or slides down the plane, consistent with earlier work in the limit of small contact angles (Benilov and Billingham, J. Fluid Mech. vol. 674, 2011, pp. 93–119). In this weakly nonlinear limit, we find that, as the static contact angle approaches $\unicode[STIX]{x03C0}$ (the non-wetting limit), the rise velocity of the droplet (specifically the velocity of the droplet averaged over one period of the motion) becomes a highly oscillatory function of static contact angle due to a high frequency mode that is excited by the forcing. We also solve the full nonlinear moving boundary problem numerically using a boundary integral method. We use this to study the effect of contact angle hysteresis, which we find can increase the rise velocity of the droplet, provided that it is not so large as to completely fix the contact lines. We also study a time-dependent modification of the contact line law in an attempt to reproduce the unsteady contact line dynamics observed in experiments, where the apparent contact angle is not a single-valued function of contact line velocity. After adding lag into the contact line model, we find that the rise velocity of the droplet is significantly affected, and that larger rise velocities are possible.

CHARACTERIZATION OF DYNAMIC WETTING OF PLASMA-TREATED PTFE FILM

2007 ◽  
Vol 14 (04) ◽  
pp. 821-825 ◽  
Author(s):  
Q. F. WEI ◽  
Y. LIU ◽  
F. L. HUANG ◽  
S. H. HONG
Keyword(s):  
Contact Angle ◽  
Plasma Treatment ◽  
Surface Properties ◽  
Contact Angle Hysteresis ◽  
Frictional Coefficient ◽  
Dynamic Contact Angle ◽  
Contact Angles ◽  
Dynamic Wetting ◽  
Ptfe Film ◽  
Receding Contact

Polytetrafluoroethylene (PTFE) has been increasingly used in many industries due to its low frictional coefficient and excellent chemical inertness. The surface properties of PTFE are of importance in various applications. The surface properties of PTFE can be modified by different techniques. In this study, PTFE film was treated in oxygen plasma for improving surface wettability. The effects of plasma treatment on dynamic wetting behavior were characterized using Scanning Probe Microscopy (SPM), Fourier transform infrared spectroscopy (FTIR), and dynamic contact angle (DCA) measurements. SPM observations revealed the etching effect of the plasma treatment on the film. The introduction of hydrophilic groups by plasma treatment was detected by FTIR. The roughened and functionalized surface resulted in the change in both advancing and receding contact angles. Advancing and receding contact angles were significantly reduced, but the contact angle hysteresis was obviously increased after plasma treatment.

Contact-angle hysteresis induced by pulmonary surfactants

1983 ◽  
Vol 54 (2) ◽  
pp. 420-426 ◽  
Author(s):  
B. A. Hills
Keyword(s):  
Contact Angle ◽  
Pulmonary Surfactant ◽  
Contact Angle Hysteresis ◽  
Hysteresis Loops ◽  
Contact Angles ◽  
Published Data ◽  
Hydrophilic Surfaces ◽  
Glass Slides ◽  
Dipalmitoyl Lecithin ◽  
Receding Contact

Hydrophilic surfaces in the form of glass slides have been coated with monolayers of three of the major components of pulmonary surfactant, and the wettabilities of the resulting surfaces have been studied by applying a single drop of saline. As fluid was added and removed over successive cycles, there was much hysteresis between the contact angle measured by a goniometer and the location of the triple point. All three surfactants, especially dipalmitoyl lecithin, were found to impart antiwetting properties, with maximum (advancing) contact angles sometimes exceeding 90 degrees and minimum (receding) contact angles seldom less than 28 degrees. In all cases (216 cycles on 36 films) fluid receded to expose the dry subphase. The hysteresis loops agree well with a similar loop calculated from published data for a cat lung in which the pressure-volume cycle has been established for both liquid and air inflation. Contact-angle hysteresis is offered as a possible alternative to surface tension as the surface parameter primarily responsible for the interfacial contribution to compliance hysteresis in the excised lung.

scholarly journals Superhydrophobicity and Contact-Line Issues

MRS Bulletin ◽  
2008 ◽  
Vol 33 (8) ◽  
pp. 747-751 ◽  
Author(s):  
Lichao Gao ◽  
Alexander Y. Fadeev ◽  
Thomas J. McCarthy
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Contact Angle Hysteresis ◽  
Water Repellency ◽  
Contact Angles ◽  
Single Step ◽  
Contact Lines ◽  
Lotus Effect ◽  
Three Phase ◽  
Solid Liquid

AbstractThe wettability of several superhydrophobic surfaces that were prepared recently by simple, mostly single-step methods is described and compared with the wettability of surfaces that are less hydrophobic. We explain why two length scales of topography can be important for controlling the hydrophobicity of some surfaces (the lotus effect). Contact-angle hysteresis (difference between the advancing, θA, and receding, θR, contact angles) is discussed and explained, particularly with regard to its contribution to water repellency. Perfect hydrophobicity (θA/θR = 180°/180°) and a method for distinguishing perfectly hydrophobic surfaces from those that are almost perfectly hydrophobic are described and discussed. The Wenzel and Cassie theories, both of which involve analysis of interfacial (solid/liquid) areas and not contact lines, are criticized. Each of these related topics is addressed from the perspective of the three-phase (solid/liquid/vapor) contact line and its dynamics. The energy barriers for movement of the three-phase contact line from one metastable state to another control contact-angle hysteresis and, thus, water repellency.

scholarly journals Dependency of Contact Angles on Three-Phase Contact Line: A Review

2021 ◽  
Vol 5 (1) ◽  
pp. 8
Author(s):  
H. Yildirim Erbil
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Contact Radius ◽  
Phase Contact ◽  
Sessile Droplet ◽  
Line Energy ◽  
Three Phase ◽  
Tension Term

The wetted area of a sessile droplet on a practical substrate is limited by the three-phase contact line and characterized by contact angle, contact radius and drop height. Although, contact angles of droplets have been studied for more than two hundred years, there are still some unanswered questions. In the last two decades, it was experimentally proven that the advancing and receding contact angles, and the contact angle hysteresis of rough and chemically heterogeneous surfaces, are determined by interactions of the liquid and the solid at the three-phase contact line alone, and the interfacial area within the contact perimeter is irrelevant. However, confusion and misunderstanding still exist in this field regarding the relationship between contact angle and surface roughness and chemical heterogeneity. An extensive review was published on the debate for the dependence of apparent contact angles on drop contact area or the three-phase contact line in 2014. Following this old review, several new articles were published on the same subject. This article presents a review of the novel articles (mostly published after 2014 to present) on the dependency of contact angles on the three-phase contact line, after a short summary is given for this long-lasting debate. Recently, some improvements have been made; for example, a relationship of the apparent contact angle with the properties of the three-phase line was obtained by replacing the solid–vapor interfacial tension term, γSV, with a string tension term containing the edge energy, γSLV, and curvature of the triple contact line, km, terms. In addition, a novel Gibbsian thermodynamics composite system was developed for a liquid drop resting on a heterogeneous multiphase and also on a homogeneous rough solid substrate at equilibrium conditions, and this approach led to the same conclusions given above. Moreover, some publications on the line energy concept along the three-phase contact line, and on the “modified” Cassie equations were also examined in this review.

LATTICE BOLTZMANN SIMULATIONS OF CONTACT LINE PINNING

2007 ◽  
Vol 18 (04) ◽  
pp. 595-601 ◽  
Author(s):  
XINLI JIA ◽  
J. B. MCLAUGHLIN ◽  
G. AHMADI ◽  
K. KONTOMARIS
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Lattice Boltzmann ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Contact Lines ◽  
Lattice Boltzmann Simulations ◽  
Spatially Periodic ◽  
Contact Line Pinning ◽  
Geometrical Defects

Contact angle hysteresis is caused by contact line pinning by geometrical and/or chemical non-uniformities on a solid surface. For small contact angles, theories have been developed for the pinning of contact angles, and an analogy between geometrical and chemical defects has been established. This paper presents LBM results for the interaction of a contact line with a spatially periodic array of chemical defects. The results are for finite contact angles. Qualitative comparisons with existing theories for chemical defects and experimental results for geometrical defects are made for pinned contact lines.

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