Aeroderivative Power Generation With Coke Oven Gas

Author(s):  
James Dicampli ◽  
Luis Madrigal ◽  
Patrick Pastecki ◽  
Joe Schornick

A major environmental concern associated with integrated steel mills is the pollution produced in the manufacture of coke, an essential intermediate product in the reduction of iron ore in a blast furnace. Coke is produced by driving off the volatile constituents of the coal—including water, coke oven gas, and coal-tar—by baking the coal in an airless furnace at temperatures as high as 2,000 degrees Celsius. This fuses together the fixed carbon and residual ash. The coke oven gas (COG) byproduct, a combustible hydrogen and hydrocarbon gas mix, may be flared, recycled to heat the coal, or cleaned to be used as a fuel source to generate energy or used to produce methanol. There are several inherent problems with COG as a fuel for power generation, notably contaminants that would not be found in pipeline natural gas or distillate fuels. Tar, a by-product of burning coal, is plentiful in COG and can be detrimental to gas turbine hot gas path components. Particulates, in the form of dust particles, are another nuisance contaminant that can shorten the life of the gas turbine’s hot section via erosion and plugging of internal cooling holes. China, the world’s largest steel producing country, has approximately 1,000 coke plants producing 200MT/year of COG. GE Energy has entered into the low British thermal unit (BTU) gases segment in China with an order from Henan Liyuan Coking Co., Ltd. The gas turbines will burn 100% coke oven gas, which will help the Liyuan Coking Plant reduce emissions and convert low BTU gas to power efficiently. This paper will detail the technical challenges and solutions for utilization of COG in an aeroderivative gas turbine, including operational experience. Additionally, it will evaluate the economic returns of gas turbine compared to steam turbine power generation or methanol production.

Author(s):  
Jürgen J. Wolf ◽  
Marko A. Perkavec

A customer of European Gas Turbines GmbH processes coal tar into chemical intermediate and final products. Continuous production throughout the year requires a peak electrical power of 10 megawatts and a continuous supply of approximately 30 tons per hour of superheated steam at a pressure of 41 bar. To cover these needs the customer chose a heavy duty gas turbine, type G3142J driving a generator. The exhaust gas from the gas turbine is fed to a waste heat boiler for steam production.


Author(s):  
S. G. Hewlett ◽  
A. Valera-Medina ◽  
D. G. Pugh ◽  
P. J. Bowen

Abstract Following on from successful experimental trials employing ammonia/hydrogen blends in a model gas turbine combustor, with favorable NOx and unburned fuel emissions, a detailed numerical study has been undertaken to assess the viability of using steelworks by-product ammonia in gas turbines. Every metric ton (tonne) of steel manufactured using a blast furnace results in approximately 1.5 kg of by-product ammonia, usually present in a vapor form, from the cleansing of coke oven gas (COG). This study numerically investigates the potential to utilize this by-product for power generation. Ammonia combustion presents some major challenges, including poor reactivity and a propensity for excessive NOx emissions. Ammonia combustion has been shown to be greatly enhanced through the addition of support fuels, hydrogen and methane (both major components of COG). CHEMKIN-PRO is employed to demonstrate the optimal ratio of ammonia vapor, and alternatively anhydrous ammonia recovered from the vapor, to COG or methane at equivalence ratios between 1.0 and 1.4 under an elevated inlet temperature of 550K. Aspen Plus was used to design a Brayton-Rankine cycle with integrated recuperation, and overall cycle efficiencies were calculated for a range of favorable equivalence ratios, identified from the combustion models. The results have been used to specify a series of emissions experiments in a model gas turbine combustor.


Author(s):  
Elliot Sullivan-Lewis ◽  
Vincent McDonell

Lean-premixed gas turbines are now common devices for low emissions stationary power generation. By creating a homogeneous mixture of fuel and air upstream of the combustion chamber, temperature variations are reduced within the combustor, which reduces emissions of nitrogen oxides. However, by premixing fuel and air, a potentially flammable mixture is established in a part of the engine not designed to contain a flame. If the flame propagates upstream from the combustor (flashback), significant engine damage can result. While significant effort has been put into developing flashback resistant combustors, these combustors are only capable of preventing flashback during steady operation of the engine. Transient events (e.g., auto-ignition within the premixer and pressure spikes during ignition) can trigger flashback that cannot be prevented with even the best combustor design. In these cases, preventing engine damage requires designing premixers that will not allow a flame to be sustained. Experimental studies were conducted to determine under what conditions premixed flames of hydrogen and natural gas can be anchored in a simulated gas turbine premixer. Tests have been conducted at pressures up to 9 atm, temperatures up to 750 K, and freestream velocities between 20 and 100 m/s. Flames were anchored in the wakes of features typical of premixer passageways, including cylinders, steps, and airfoils. The results of this study have been used to develop an engineering tool that predicts under what conditions a flame will anchor, and can be used for development of flame anchoring resistant gas turbine premixers.


Author(s):  
Matti Malkamäki ◽  
Ahti Jaatinen-Värri ◽  
Antti Uusitalo ◽  
Aki Grönman ◽  
Juha Honkatukia ◽  
...  

Decentralized electricity and heat production is a rising trend in small-scale industry. There is a tendency towards more distributed power generation. The decentralized power generation is also pushed forward by the policymakers. Reciprocating engines and gas turbines have an essential role in the global decentralized energy markets and improvements in their electrical efficiency have a substantial impact from the environmental and economic viewpoints. This paper introduces an intercooled and recuperated three stage, three-shaft gas turbine concept in 850 kW electric output range. The gas turbine is optimized for a realistic combination of the turbomachinery efficiencies, the turbine inlet temperature, the compressor specific speeds, the recuperation rate and the pressure ratio. The new gas turbine design is a natural development of the earlier two-spool gas turbine construction and it competes with the efficiencies achieved both with similar size reciprocating engines and large industrial gas turbines used in heat and power generation all over the world and manufactured in large production series. This paper presents a small-scale gas turbine process, which has a simulated electrical efficiency of 48% as well as thermal efficiency of 51% and can compete with reciprocating engines in terms of electrical efficiency at nominal and partial load conditions.


Author(s):  
Mark A. Paisley ◽  
Donald Anson

The Biomass Power Program of the US Department of Energy (DOE) has as a major goal the development of cost-competitive technologies for the production of power from renewable biomass crops. The gasification of biomass provides the potential to meet his goal by efficiently and economically producing a renewable source of a clean gaseous fuel suitable for use in high efficiency gas turbines. This paper discusses the development and first commercial demonstration of the Battelle high-throughput gasification process for power generation systems. Projected process economics are presented along with a description of current experimental operations coupling a gas turbine power generation system to the research scale gasifier and the process scaleup activities in Burlington, Vermont.


Author(s):  
Wolfgang Kappis ◽  
Stefan Florjancic ◽  
Uwe Ruedel

Market requirements for the heavy duty gas turbine power generation business have significantly changed over the last few years. With high gas prices in former times, all users have been mainly focusing on efficiency in addition to overall life cycle costs. Today individual countries see different requirements, which is easily explainable picking three typical trends. In the United States, with the exploitation of shale gas, gas prices are at a very low level. Hence, many gas turbines are used as base load engines, i.e. nearly constant loads for extended times. For these engines reliability is of main importance and efficiency somewhat less. In Japan gas prices are extremely high, and therefore the need for efficiency is significantly higher. Due to the challenge to partly replace nuclear plants, these engines as well are mainly intended for base load operation. In Europe, with the mid and long term carbon reduction strategy, heavy duty gas turbines is mainly used to compensate for intermittent renewable power generation. As a consequence, very high cyclic operation including fast and reliable start-up, very high loading gradients, including frequency response, and extended minimum and maximum operating ranges are required. Additionally, there are other features that are frequently requested. Fuel flexibility is a major demand, reaching from fuels of lower purity, i.e. with higher carbon (C2+), content up to possible combustion of gases generated by electrolysis (H2). Lifecycle optimization, as another important request, relies on new technologies for reconditioning, lifetime monitoring, and improved lifetime prediction methods. Out of Alstom’s recent research and development activities the following items are specifically addressed in this paper. Thermodynamic engine modelling and associated tasks are discussed, as well as the improvement and introduction of new operating concepts. Furthermore extended applications of design methodologies are shown. An additional focus is set ono improve emission behaviour understanding and increased fuel flexibility. Finally, some applications of the new technologies in Alstom products are given, indicating the focus on market requirements and customer care.


Author(s):  
M. Sato ◽  
T. Abe ◽  
T. Ninomiya ◽  
T. Nakata ◽  
T. Yoshine ◽  
...  

From the view point of future coal utilization technology for the thermal power generation systems, the coal gasification combined cycle system has drawn special interest recently. In the coal gasification combined cycle power generation system, it is necessary to develop a high temperature gas turbine combustor using a low-BTU gas (LBG) which has high thermal efficiency and low emissions. In Japan a development program of the coal gasification combined cycle power generation system has started in 1985 by the national government and Japanese electric companies. In this program, 1300°C class gas turbines will be developed. If the fuel gas cleaning system is a hot type, the coal gaseous fuel to be supplied to gas turbines will contain ammonia. Ammonia will be converted to nitric oxides in the combustion process in gas turbines. Therefore, low fuel-NOx combustion technology will be one of the most important research subjects. This paper describes low fuel-NOx combustion technology for 1300°C class gas turbine combustors using coal gaseous low-BTU fuel as well as combustion characteristics and carbon monoxide emission characteristics. Combustion tests were conducted using a full-scale combustor used for the 150 MW gas turbine at the atmospheric pressure. Furthermore, high pressure combustion tests were conducted using a half-scale combustor used for the 1 50 MW gas turbine.


Author(s):  
Thomas Wagner ◽  
Robert J. Burke

The desire to maintain power plant profitability, combined with current market fuel gas pricing is forcing power generation companies to constantly look for ways to keep their industrial gas turbine units operating at the highest possible efficiency. Gas Turbines Operation requires the compression of very large quantities of air that is mixed with fuel, ignited and directed into a turbine to produce torque for purposes ranging from power generation to mechanical drive of pumping systems to thrust for air craft propulsion. The compression of the air for this process typically uses 60% of the required base energy. Therefore management of the compression process efficiency is very important to maintain overall cycle efficiency. Since fouling of turbine compressors is almost unavoidable, even with modern air filter treatment, and over time results in lower efficiency and output, compressor cleaning is required to maintain gas turbine efficiency.


2021 ◽  
Author(s):  
Takashi Nishiumi ◽  
Hirofumi Ohara ◽  
Kotaro Miyauchi ◽  
Sosuke Nakamura ◽  
Toshishige Ai ◽  
...  

Abstract In recent years, MHPS achieved a NET M501J gas turbine combined cycle (GTCC) efficiency in excess of 62% operating at 1,600°C, while maintaining NOx under 25ppm. Taking advantage of our gas turbine combustion design, development and operational experience, retrofits of earlier generation gas turbines have been successfully applied and will be described in this paper. One example of the latest J-Series technologies, a conventional pilot nozzle was changed to a premix type pilot nozzle for low emission. The technology was retrofitted to the existing F-Series gas turbines, which resulted in emission rates of lower than 9ppm NOx(15%O2) while maintaining the same Turbine Inlet Temperature (TIT: Average Gas Temperature at the exit of the transition piece). After performing retrofitting design, high pressure rig tests, the field test prior to commercial operation was conducted on January 2019. This paper describes the Ultra-Low NOx combustor design features, retrofit design, high pressure rig test and verification test results of the upgraded M501F gas turbine. In addition, it describes another upgrade of turbine to improve efficiency and of combustion control system to achieve low emissions. Furthermore it describes the trouble-free upgrade of seven (7) units, which was completed by utilizing MHPS integration capabilities, including handling all the design, construction and service work of the main equipment, plant and control systems.


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