Analysis of Undercooling, Nucleation, Rapid Solidification, and Microstructure Formation in Thermal Spraying

Author(s):  
H. Zhang ◽  
X. Y. Wang ◽  
S. Sampath

A splat formation model including undercooling, nucleation, and non-equilibrium solidification has been developed to study the thermal characteristics of molten droplets impacting on a flat substrate. The nucleation sub-model is based on the classic nucleation theory accounting for heterogeneous nucleation kinetic and crystal growth. The effects of contact angle on nucleation temperature and grain density have been investigated. The grain size distributions have been predicted and compared with experimental results for molybdenum (Mo) splats on different substrates. Based on scaling analysis, time scales of various sub-processes, e.g., the nucleation delay, recalesence, and total solidification time, have been derived, and compared with simulation results.

2007 ◽  
Vol 539-543 ◽  
pp. 1218-1223 ◽  
Author(s):  
F. Azarmi ◽  
A. Moradian ◽  
J. Mostaghimi ◽  
Tom W. Coyle ◽  
L. Pershin

There is a growing interest in use of the nickel-based alloy Inconel 625 coatings due to its ability to improve base materials high temperature properties. Thermal spraying methods such as Air Plasma Spraying (APS) can be considered as a convenient method to deposit this material. The present work deals with APS deposited Inconel 625 structures consisting of huge number of individual splats formed by impacting molten droplets on substrates during spraying process. It is clear that the splat formation mechanism which dominates its size, cohesion, and boundaries highly influences the microstructure of the coating. This paper presents a developed numerical technique performed to simulate splat formation using a three dimensional model. In this method flow field is solved by Finite Volume Method (FVM) and free surfaces are determined from Youngs’ Volume of Fraction method (VOF). Finally, the model prediction is correlated with the actual splat geometries.


Author(s):  
Mo Ji ◽  
Martin Strangwood ◽  
Claire Davis

AbstractThe effects of Nb addition on the recrystallization kinetics and the recrystallized grain size distribution after cold deformation were investigated by using Fe-30Ni and Fe-30Ni-0.044 wt pct Nb steel with comparable starting grain size distributions. The samples were deformed to 0.3 strain at room temperature followed by annealing at 950 °C to 850 °C for various times; the microstructural evolution and the grain size distribution of non- and fully recrystallized samples were characterized, along with the strain-induced precipitates (SIPs) and their size and volume fraction evolution. It was found that Nb addition has little effect on recrystallized grain size distribution, whereas Nb precipitation kinetics (SIP size and number density) affects the recrystallization Avrami exponent depending on the annealing temperature. Faster precipitation coarsening rates at high temperature (950 °C to 900 °C) led to slower recrystallization kinetics but no change on Avrami exponent, despite precipitation occurring before recrystallization. Whereas a slower precipitation coarsening rate at 850 °C gave fine-sized strain-induced precipitates that were effective in reducing the recrystallization Avrami exponent after 50 pct of recrystallization. Both solute drag and precipitation pinning effects have been added onto the JMAK model to account the effect of Nb content on recrystallization Avrami exponent for samples with large grain size distributions.


1980 ◽  
Vol 117 (5) ◽  
pp. 425-436 ◽  
Author(s):  
R. S. J. Sparks ◽  
T. C. Huang

SummaryMany volcanic ash layers preserved in deep-sea sediments are the products of large magnitude ignimbrite eruptions. The characteristics of such co-ignimbrite ash-fall deposits are illustrated by two layers from the Eastern Mediterranean: the Minoan ash, Santorini, and the Campanian ash, Italy. These layers are divisible into a coarse lower unit and a fine upper unit in proximal cores. Both layers also show striking bimodal grain size distributions in more distal cores. The coarser mode decreases in median diameter with distance from source whereas the finer mode shows no lateral variation. These features are interpreted in terms of a model for ignimbrite formation by eruption column collapse. Comparable volumes of ignimbrite and associated air-fall ejecta are produced.


1999 ◽  
Vol 580 ◽  
Author(s):  
G.D. Hibbard ◽  
U. Erb ◽  
K.T. Aust ◽  
G. Palumbo

AbstractIn this study, the effect of grain size distribution on the thermal stability of electrodeposited nanocrystalline nickel was investigated by pre-annealing material such that a limited amount of abnormal grain growth was introduced. This work was done in an effort to understand the previously reported, unexpected effect, of increasing thermal stability with decreasing grain size seen in some nanocrystalline systems. Pre-annealing produced a range of grain size distributions in materials with relatively unchanged crystallographic texture and total solute content. Subsequent thermal analysis of the pre-annealed samples by differential scanning calorimetry showed that the activation energy of further grain growth was unchanged from the as-deposited nanocrystalline nickel.


2021 ◽  
Author(s):  
◽  
Anna Borisovna Albot

<p>Grain size analysis of the terrigenous fraction of a laminated diatom ooze dating back to 11.4 kyr recovered offshore Adélie Land, East Antarctic margin was used to examine variations in sediment transport, depositional environments and Holocene climate variability at the location. Interpretations were assisted by additional proxies of primary productivity (δ¹³CFA, BSi%), glacial meltwater input (δDFA) and subsurface temperature (TEXL₈₆). Three lithologic intervals with distinct grain size distributions were identified. At ~11.4 ka the diatom ooze has a clear glacimarine influence which gradually decreases until ~8.2 ka. During this time interval, coincident with the early Holocene warm period, sediment is inferred to have been delivered by glacial meltwater plumes and ice-bergs in a calving bay environment. It is suggested that the glaciers in Adélie Land had retreated to their present day grounding lines by 8.2 ka, and from then on sediment was delivered to the site primarily via the Antarctic Coastal and Slope Front Currents, largely through a suspended sediment load and erosion of the surrounding banks. Enhanced biogenic mass accumulation rates and primary production at 8.2 ka suggest onset of warmer climatic conditions, coincident with the mid-Holocene Climatic Optimum.  At ~4.5 ka, grain size distributions show a rapid increase in mud content coincident with a transient pulse of glacial meltwater and a sudden decrease in biogenic and terrigenous mass accumulation rates. The increased mud content is inferred to have been deposited under a reduced flow regime of the Antarctic Coastal and Slope Front Currents during the Neoglacial period that followed the final stages of deglaciation in the Ross Sea. It is hypothesised here that cessation of glacial retreat in the Ross Sea and the development of the modern day Ross Sea polynya resulted in enhanced Antarctic Surface Water production which led to increased sea ice growth in the Adélie Land region. The presence of sea ice led to reduced primary production and a decrease in the maximum current strength acting to advect coarser-sized terrigenous sediment to the core site during this time.  Sedimentation rates appear to have a strong correlation with the El Niño Southern Oscillation (ENSO) over the last 8.2 kyr, and are inferred to be related to changing sea ice extent and zonal wind strength. Light laminae counts (biogenic bloom events) appear to decrease in frequency during time intervals dominated by El Niño events. Spectral analysis of the greyscale values of core photographs reveals peaks in the 2-7 year band, known ENSO periods, which increase in frequency in the mid-and-late Holocene. Spectral analyses of the sand percent and natural gamma ray (NGR, a measure of clay mineral input) content of the core reveal peaks in the ~40-60, 200-300, 600, 1200-1600 and 2200-2400 year bands. The most significant of these cycles in the NGR data is in 40-60 year band may be related to internal mass balance dynamics of the Mertz Glacier or to the expansion and contraction of the Antarctic circumpolar vortex. Cycles in the 200-300 and 2200-2400 year bands are related to known periods of solar variability, which have previously been found to regulate primary productivity in Antarctic coastal waters. Cycles in the 590-625 and 1200-1600 year bands have a strong signal through the entire record and are common features of Holocene climatic records, however the origin of these cycles is still under debate between solar forcing and an independent mode of internal ocean oscillation.</p>


2020 ◽  
Vol 641 ◽  
pp. A75
Author(s):  
T. Löhne

The excess emission seen in spectral energy distributions (SEDs) is commonly used to infer the properties of the emitting circumstellar dust in protoplanetary and debris discs. Most notably, dust size distributions and details of the collision physics are derived from SED slopes at long wavelengths. This paper reviews the approximations that are commonly used and contrasts them with numerical results for the thermal emission. The inferred size distribution indexes p are shown to be greater and more sensitive to the observed sub(mm) spectral indexes, αmm, than previously considered. This effect results from aspects of the transition from small grains with volumetric absorption to bigger grains that absorb and emit near to their surface, controlled by both the real and the imaginary part of the refractive index. The steeper size distributions indicate stronger size-dependence of material strengths or impact velocities or, otherwise, less efficient transport or erosion processes. Strong uncertainties remain because of insufficient knowledge of the material composition, porosity, and optical properties at long wavelengths.


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