Second Law Aspects of Simplified Models for Sensible Thermal Storage
Abstract This paper presents results for entropy generation during the inflow of a low temperature stream into a sensible thermal storage vessel initially filled with a uniformly high temperature liquid. The level of internal entropy generation due to thermal mixing between the cold and hot liquid corresponds to losses in the usable fraction of the stored volume and therefore decreased efficiency. Empirically, the observed behavior of sensible storage devices spans the range of nearly mixed to well stratified. In this investigation, analytical models for these two limits, the fully mixed and ideally stratified conditions, are used to bound the entropy generation levels of the observed behaviors. A numerical model for stratified storage systems based on the one-dimensional convective energy equation which accounts for aspects of the observed thermal mixing is then examined in relation to the afore-mentioned limits. The results show that even at moderate throughflow rates, the fully mixed and ideally stratified limits are separated by orders of magnitude in terms of entropy generated. The empirically-based numerical model exhibits mixing levels midway between these two limits and thereby underscores the potential for significant improvements in efficiency. Examination of the numerical model shows the crucial importance of resolving the evolution of the interior thermal layer and the boundary heat fluxes in computing the entropy generation.