Thin-Wall Titanium Condenser Tubing: The Next Plateau

Author(s):  
Dennis J. Schumerth

Commercially pure (cp.) titanium and its alloys provide excellent resistance to general and localized corrosion attack under most oxidizing, neutral and inhibited reducing conditions in aqueous environments. Titanium is also notable for its outstanding resistance to chlorides and other halides generally present in most process streams. In addition, titanium resists other malicious phenomenon including steam and particle erosion, crevice corrosion, galvanic attack and MIC. Given this general corrosion immunity, designers have increasingly applied thin-wall condenser tubing in pursuit of cost savings and performance enhancement. Typically, these thin-wall applications have, over the past several years, been limited to 25 BWG or 0.020”/0.5mm walls or heavier. The “industry” has, out of necessity, moved to address the special nuances of the 25 BWG including design, procurement, handling, fabrication and testing parameters with increasing success. It would appear however, that designers, operators and pundits alike require further education and refinement on the specific operational characteristics when integrated into the powerplant environment. Considerable work has been recently completed investigating even thinner wall titanium tubing. This paper will address the essential data elements of this expanded research focusing specifically on Grade 2 titanium in 27 BWG or 0.016”/0.4mm. Since a significant portfolio of 27 BWG installations is rapidly taking shape, it is prudent to examine key ingredients that would warrant consideration of this “next-plateau” gauge material. Indeed, work is currently underway exploring the technology required to fabricate condenser tubes as thin as 30 BWG /0.013”/0.3 mm.) In summary, the paper will present and summarize substantive evidence suitable for comparison against previously acquired empirical data and prior art.

1994 ◽  
Vol 353 ◽  
Author(s):  
Rolf Sjöblom ◽  
Hans-Peter Hermansson ◽  
Örjan Amcoff

AbstractIn the Swedish waste management programme, the copper canister is expected to provide containment of the radionuclides for a very long time, perhaps millions of years. The purpose of the present paper, is to analyse prerequisites for assessments of corrosion lifetimes for copper canisters.The analysis is based on compilations of literature from the following areas: chemical literature on copper and copper corrosion, mineralogical literature with emphasis on the stability of copper in near surface environments, and chemical and mineralogical literature with emphasis on the stabilities and thermodynamics of species and phases that may exist in a repository environment.Three main types of situations are identified: (1) under oxidizing and low chloride conditions, passivating oxide type of layers may form on the copper surface; (2) under oxidizing and high chloride conditions, the species formed may all be dissolved; and (3) under reducing conditions, non-passivating sulfide type layers may form on the copper surface.Considerable variability and uncertainty exists regarding the chemical environment for the canister, especially in certain scenarios. Thus, the mechanisms for corrosion can be expected to differ greatly for different situations. The lifetime of a thick-walled copper canister subjected to general corrosion appears to be long for most reasonable chemistries. (It is assumed that the canister has no defects from manufacturing and that the bentonite buffer is intact). Localized corrosion may appear for types (1) and (3) above but the mechanisms are widely different in character. The penetration caused by localized corrosion can be expected to be very sensitive to details in the chemistry.


Author(s):  
Allan Matthews ◽  
Adrian Leyland

Over the past twenty years or so, there have been major steps forward both in the understanding of tribological mechanisms and in the development of new coating and treatment techniques to better “engineer” surfaces to achieve reductions in wear and friction. Particularly in the coatings tribology field, improved techniques and theories which enable us to study and understand the mechanisms occurring at the “nano”, “micro” and “macro” scale have allowed considerable progress to be made in (for example) understanding contact mechanisms and the influence of “third bodies” [1–5]. Over the same period, we have seen the emergence of the discipline which we now call “Surface Engineering”, by which, ideally, a bulk material (the ‘substrate’) and a coating are combined in a way that provides a cost-effective performance enhancement of which neither would be capable without the presence of the other. It is probably fair to say that the emergence and recognition of Surface Engineering as a field in its own right has been driven largely by the availability of “plasma”-based coating and treatment processes, which can provide surface properties which were previously unachievable. In particular, plasma-assisted (PA) physical vapour deposition (PVD) techniques, allowing wear-resistant ceramic thin films such as titanium nitride (TiN) to be deposited on a wide range of industrial tooling, gave a step-change in industrial productivity and manufactured product quality, and caught the attention of engineers due to the remarkable cost savings and performance improvements obtained. Subsequently, so-called 2nd- and 3rd-generation ceramic coatings (with multilayered or nanocomposite structures) have recently been developed [6–9], to further extend tool performance — the objective typically being to increase coating hardness further, or extend hardness capabilities to higher temperatures.


Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3515
Author(s):  
Weikang Wang ◽  
Xuanchun Wei ◽  
Xinhua Cai ◽  
Hongyang Deng ◽  
Bokang Li

: The early-age carbonation curing technique is an effective way to improve the performance of cement-based materials and reduce their carbon footprint. This work investigates the early mechanical properties and microstructure of calcium sulfoaluminate (CSA) cement specimens under early-age carbonation curing, considering five factors: briquetting pressure, water–binder (w/b) ratio, starting point of carbonation curing, carbonation curing time, and carbonation curing pressure. The carbonization process and performance enhancement mechanism of CSA cement are analyzed by mercury intrusion porosimetry (MIP), thermogravimetry and derivative thermogravimetry (TG-DTG) analysis, X-ray diffraction (XRD), and scanning electron microscope (SEM). The results show that early-age carbonation curing can accelerate the hardening speed of CSA cement paste, reduce the cumulative porosity of the cement paste, refine the pore diameter distribution, and make the pore diameter distribution more uniform, thus greatly improving the early compressive strength of the paste. The most favorable w/b ratio for the carbonization reaction of CSA cement paste is between 0.15 and 0.2; the most suitable carbonation curing starting time point is 4 h after initial hydration; the carbonation curing pressure should be between 3 and 4 bar; and the most appropriate time for carbonation curing is between 6 and 12 h.


Sign in / Sign up

Export Citation Format

Share Document