The Compatibility of Nuclear Graphite With Molten Salt in the Molten Salt Reactor

Author(s):  
Zhoutong He ◽  
Hui Tang ◽  
Can Zhang ◽  
Yantao Gao ◽  
Huihao Xia ◽  
...  

In thermal Molten Salt Reactors, the nuclear graphite core is in direct contact with the molten salt coolant. Due to the porous nature of nuclear graphite, the molten salt may infiltrate the nuclear graphite, which may affect the mechanical strength and irradiation behavior of the nuclear graphite. In order to evaluate the infiltration behavior of molten salt in nuclear graphite, both FLiNaK and FLiBe salts were used to infiltrate two typical nuclear graphite grades: IG110 and NBG18. The pressure dependence of the infiltration weight gain ratio was measured. The influence of molten salt infiltration on the thermal properties of these two graphite grades, such as their thermal expansion behavior and thermal conductivity, was also measured. The mechanical strength of the FLiNaK-infiltrated graphite was measured at room temperature and elevated temperature, and showed that the mechanical strength of the nuclear graphite was enhanced at room temperature and weakened at elevated temperature by molten salt infiltration. Finally, the thermal expansion coefficient and the fracture surface analysis measured after FLiNaK infiltration indicated that the stress induced by molten salt infiltration could be one of the reasons for the graphite property changes.

1989 ◽  
Vol 68 (9) ◽  
pp. 1313-1315 ◽  
Author(s):  
C.W. Fairhurst ◽  
D.T. Hashinger ◽  
S.W. Twiggs

Porcelain-fused-to-metal restorations are fired several hundred degrees above the glass-transition temperature and cooled rapidly through the glass-transition temperature range. Thermal expansion data from room temperature to above the glass-transition temperature range are important for the thermal expansion of the porcelain to be matched to the alloy. The effect of heating rate during measurement of thermal expansion was determined for NBS SRM 710 glass and four commercial opaque and body porcelain products. Thermal expansion data were obtained at heating rates of from 3 to 30°C/min after the porcelain was cooled at the same rate. By use of the Moynihan equation (where Tg systematically increases in temperature with an increase in cooling/heating rate), the glass-transition temperatures (Tg) derived from these data were shown to be related to the heating rate.


Materialia ◽  
2019 ◽  
Vol 6 ◽  
pp. 100289 ◽  
Author(s):  
Chang Zhou ◽  
Qiang Zhang ◽  
Xin Tan ◽  
Sihao Deng ◽  
Kewen Shi ◽  
...  

2014 ◽  
Vol 84-85 ◽  
pp. 19-22 ◽  
Author(s):  
Jun Yan ◽  
Ying Sun ◽  
Cong Wang ◽  
Lihua Chu ◽  
Zaixing Shi ◽  
...  

2020 ◽  
pp. 17-24
Author(s):  
Patrice Berthod ◽  
Jean-Paul Gomis ◽  
Lionel Aranda ◽  
Pierre-Jean Panteix

This paper aims to investigate the thermal expansion behavior, up to an elevated temperature, of superalloys based on nickel and cobalt with various proportions and designed to be strengthened by tantalum carbides. The as-cast microstructures of these superalloys and their evolutions at two very high temperatures were also of interest. All results are discussed by considering the Ni/Co repartition in the base element position. It appears that when the Ni content is higher than the Co one: 1/the thermal expansion is slower, 2/the as-cast microstructures as well as the ones stabilized at high temperature contain not only TaC but also chromium carbides, and 3/the hardness in as-cast or aged state is lower.


1994 ◽  
Vol 340 ◽  
Author(s):  
J. R. Kim ◽  
R. M. Park ◽  
K. S. Jones

ABSTRACTThe thermal expansion behavior of ZnSe and ZnS0.03Se0.97 epilayers grown on GaAs has been investigated using high resolution X-ray diffraction at temperatures between room temperature and the growth temperature. The lattice parameters perpendicular and parallel to the surface were measured with the Bond's method. The lattice mismatch for a partially relaxed ZnSe layer was Δa(⊥)/a =2300 ppm and Δa(‖)/a = 2600 ppm at room temperature(R.T.) and Δa (⊥)/a =3600 ppm and Δa(‖)/a =2400 ppm at 250°C. For ZnS0.03Se0.97 which is almost lattice matched at R.T. to GaAs, Δa(⊥)/a =200 ppm, Δa(⊥)/a =20ppmatR.T. and Δa(⊥)/a =1400ppm, Δa(⊥)/a =50ppm at 250°C. The relaxed lattice constants were evaluated and the thermal expansion coefficients of relaxed ZnSe layers were found to vary from 7.8*10−6/°C at room temperature to 12.2*10−6/°C at 250°C and for ZnS0.03Se0.97 layers the variation was from 7.5*10−6/°C at R.T. to 11.7*10−6/°C at 250°C.


Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 125
Author(s):  
Seyed Kiomars Moheimani ◽  
Mehran Dadkhah ◽  
Mohammad Hossein Mosallanejad ◽  
Abdollah Saboori

Metal matrix nanocomposites (MMNCs) with high specific strength have been of interest for numerous researchers. In the current study, Mg matrix nanocomposites reinforced with AlN nanoparticles were produced using the mechanical stirring-assisted casting method. Microstructure, hardness, physical, thermal and electrical properties of the produced composites were characterized in this work. According to the microstructural evaluations, the ceramic nanoparticles were uniformly dispersed within the matrix by applying a mechanical stirring. At higher AlN contents, however, some agglomerates were observed as a consequence of a particle-pushing mechanism during the solidification. Microhardness results showed a slight improvement in the mechanical strength of the nanocomposites following the addition of AlN nanoparticles. Interestingly, nanocomposite samples were featured with higher electrical and thermal conductivities, which can be attributed to the structural effect of nanoparticles within the matrix. Moreover, thermal expansion analysis of the nanocomposites indicated that the presence of nanoparticles lowered the Coefficient of Thermal Expansion (CTE) in the case of nanocomposites. All in all, this combination of properties, including high mechanical strength, thermal and electrical conductivity, together with low CTE, make these new nanocomposites very promising materials for electro packaging applications.


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