The Use of a Three-Zone Combustion Model to Determine Nitric Oxide Emissions From a Homogeneous-Charge, Spark-Ignited Engine

2003 ◽  
Author(s):  
Jerald A. Caton
Keyword(s):  
Nitric Oxide ◽  
Engine Speed ◽  
Combustion Process ◽  
Core Region ◽  
Operating Conditions ◽  
Combustion Model ◽  
Nitric Oxides ◽  
Cycle Simulation ◽  
Nitric Oxide Emissions ◽  
Homogeneous Charge

Nitric oxide emissions were estimated for a homogeneous-charge, spark-ignited automotive engine using a cycle simulation which employed three zones for the combustion process: (1) unburned gas, (2) adiabatic core region, and (3) boundary-layer gas. The use of the adiabatic core region has been shown to be especially necessary to capture the production of nitric oxides which are highly temperature dependent. The effects of major engine parameters such as equivalence ratio, spark timing, inlet manifold pressure, and engine speed on nitric oxide emissions are examined. In particular, the detail reasons for the effects of these engine parameters on the nitric oxide emissions are presented. Comparisons are completed between the computed values and a set of published measurements for the nitric oxide concentrations. Although not all engine parameters were known, reasonable agreement is demonstrated for most cases. In particular, the variations of nitric oxide concentrations as engine speed increased were duplicated. As an example, four operating conditions are examined in detail to help explain the measured results. Nitric oxide emissions are shown to be mainly the net result of gas temperatures, oxygen concentrations, and residence times.

First and Second Law Analyses of a Spark-Ignition Engine Using Either Isooctane or Hydrogen: An Initial Assessment

2006 ◽  
Author(s):  
Jerald A. Caton
Keyword(s):  
Nitric Oxide ◽  
Thermal Efficiency ◽  
Equivalence Ratio ◽  
Performance Metrics ◽  
Combustion Process ◽  
Spark Ignition ◽  
Spark Ignition Engine ◽  
Second Law ◽  
Cycle Simulation ◽  
Nitric Oxide Emissions

The use of either hydrogen or isooctane for a spark-ignition engine was examined using a thermodynamic cycle simulation including the second law of thermodynamics. The engine studied was a 5.7 liter, automotive engine operating from idle to wide open throttle. The hydrogen or isooctane was assumed premixed with the air. Two features of hydrogen combustion that were included in the study were the higher flame speeds (shorter burn durations) and the wider lean flammability limits (lean equivalence ratios). Three cases were considered for the use of hydrogen: (1) standard burn duration and an equivalence ratio of 1.0, (2) a shorter burn duration and an equivalence ratio of 1.0, and (3) a shorter burn duration and variable, lean equivalence ratios. The results included thermal efficiencies, other performance metrics, second law parameters, and nitric oxide emissions. In general, for the cases with an equivalence of 1.0, the brake thermal efficiency was slightly lower for the hydrogen cases due to the higher temperatures and higher heat losses. For the variable, lean equivalence ratio cases, the thermal efficiency was higher for the hydrogen case relative to the isooctane case. Due to the higher temperatures, the hydrogen cases had over 50% higher nitric oxide emissions compared to the isooctane case at the base conditions. In addition, the second law analyses indicated that the destruction of availability during the combustion process was lower for the base hydrogen case (11.2%) relative to the isooctane case (21.1%).

Detailed Results for Nitric Oxide Emissions as Determined From a Multiple-Zone Cycle Simulation for a Spark-Ignition Engine

2002 ◽  
Author(s):  
Jerald A. Caton
Keyword(s):  
Nitric Oxide ◽  
Compression Ratio ◽  
Equivalence Ratio ◽  
Combustion Process ◽  
Spark Ignition ◽  
Spark Ignition Engine ◽  
Base Case ◽  
Gas Temperature ◽  
Cycle Simulation ◽  
Nitric Oxide Emissions

A thermodynamic cycle simulation was developed for spark-ignition engines which included a formulation using multiple zones for the combustion process and the capability to compute the net nitric oxide (NO) change due to the “thermal” formation mechanism. This simulation was used to complete analyses for a commercial, 5.7 l spark-ignition V-8 engine operating at a part load operating condition at 1400 rpm with an equivalence ratio of 1.0. The engine possessed a compression ratio of 8.1:1, and had a bore and stroke of 101.6 and 88.4 mm, respectively. At the base case conditions, the nitric oxide emissions were 15.7 g/bhp-hr (2903 ppm). The effects of equivalence ratio, combustion duration, spark timing, exhaust gas recirculation, compression ratio, speed and load on nitric oxide changes were examined. Results for instantaneous nitric oxide as a function of crank angle are presented. The use of an adiabatic zone was shown to dramatically increase the nitric oxide levels relative to using the burned gas temperature. For the base case, almost 50% more nitric oxide was computed using the adiabatic temperature relative to the burned gas temperature. The importance of gas temperature, cylinder gas pressure, and composition is illustrated.

scholarly journals THE STUDY AND THE MECHANISM OF NITROGEN OXIDES’ FORMATION IN COMBUSTION OF FOSSIL FUELS

2018 ◽  
Vol 16 (2) ◽  
pp. 273 ◽  
Author(s):  
Bulbul Ongar ◽  
Iliya K. Iliev ◽  
Vlastimir Nikolić ◽  
Aleksandar Milašinović
Keyword(s):  
Nitric Oxide ◽  
Nitrogen Oxides ◽  
Coal Combustion ◽  
Fossil Fuels ◽  
Coal Dust ◽  
Chemical Reduction ◽  
Molecular Nitrogen ◽  
Combustion Process ◽  
Nitric Oxides ◽  
Nitric Oxide Emissions

The burning of all fossil fuels is accompanied by the production of large quantities of nitrogen oxides. Nitrogen oxide from coal combustion is formed from the molecular nitrogen in the air and the nitrogen contained in the fuel. In accordance with the mechanism of formation of nitric oxide from fuel, it is desirable to increase the concentration of coal dust in the flame. The thermal regime of combustion accelerates the release of volatiles, with flames spreading out and the coke residue contributes to the chemical reduction of NOx. In this work we consider the specific issues of the formation mechanism of NOx fuel and ways to reduce their atmospheric emissions. Presented are results from the calculation of the influence of the following on the level of nitric oxides during coal combustion: temperature, oxygen concentration and time of release of fuel nitrogen. It has been established that the influence of nitric oxide fuel on the total nitric oxide emissions is more noticeable at low temperatures of the combustion process.

scholarly journals Thermodynamic model for homogeneous charge compression ignition combustion with recompression valve events and direct injection: Part II—Combustion model and evaluation against transient experiments

2016 ◽  
Vol 18 (7) ◽  
pp. 677-700
Author(s):  
Prasad S Shingne ◽  
Jeff Sterniak ◽  
Dennis N Assanis ◽  
Claus Borgnakke ◽  
Jason B Martz
Keyword(s):  
Homogeneous Charge Compression Ignition ◽  
Direct Injection ◽  
Combustion Process ◽  
Operating Conditions ◽  
Combustion Model ◽  
Compression Ignition ◽  
Ignition Timing ◽  
Ignition And Combustion ◽  
Compression Ignition Combustion ◽  
Homogeneous Charge

This two-part article presents a combustion model for boosted and moderately stratified homogeneous charge compression ignition combustion for use in thermodynamic engine cycle simulations. The model consists of two parts: one an ignition model for the prediction of auto-ignition onset and the other an empirical combustion rate model. This article focuses on the development of the combustion model which is algebraic in form and is based on the key physical variables affecting the combustion process. The model is fit with experimental data collected from 290 discrete automotive homogeneous charge compression ignition operating conditions with moderate stratification resulting from both the direct injection and negative valve overlap valve events. Both the ignition model from part 1 and the combustion model from this article are implemented in GT-Power and validated against experimental homogeneous charge compression ignition data under steady-state and transient conditions. The ignition and combustion model are then exercised to identify the dominant variables affecting the homogeneous charge compression ignition and combustion processes. Sensitivity analysis reveals that ignition timing is primarily a function of the charge temperature, and that combustion duration is largely a function of ignition timing.

Prediction of CO and NOx Pollutants in a Stratified Bluff Body Burner

2017 ◽  
Author(s):  
Pascal Gruhlke ◽  
Fabian Proch ◽  
Andreas M. Kempf ◽  
Enric Illana Mahiques ◽  
Stefan Dederichs ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Carbon Monoxide ◽  
Bluff Body ◽  
Combustion Products ◽  
Combustion Model ◽  
Wide Range ◽  
Flame Region ◽  
Numerical Grid ◽  
Nitric Oxide Emissions ◽  
Heavy Duty Gas Turbine

The major exhaust gas pollutants from heavy duty gas turbine engines are CO and NOx. The difficulty of predicting the concentration of these combustion products originates from their wide range of chemical time scales. In this paper, a combustion model that includes the prediction of the carbon monoxide and nitric oxide emissions is tested. Large eddy simulations (LES) are performed using a compressible code (OpenFOAM). A modified flamelet generated manifolds (FGM) approach is applied with a thickened flame approach (ATF) to resolve the flame on the numerical grid, with a flame sensor to ensure that the flame is only thickened in the flame region. For the prediction of the CO and NOx emissions, pollutant species transport equations and a second, CO based, progress variable are introduced for the flame burnout zone to account for slow chemistry effects. For the validation of the models, the Cambridge burner of Sweeney and Hochgreb [1, 2] is employed, as both carbon monoxide and nitric oxide [3] data is available.

Modelling and Optimization of the NO Formation in an Industrial Glass Furnace

1992 ◽  
Vol 114 (4) ◽  
pp. 514-523 ◽  
Author(s):  
M. G. Carvalho ◽  
V. S. Semia˜o ◽  
P. J. Coelho
Keyword(s):  
Nitric Oxide ◽  
Mathematical Model ◽  
Glass Furnace ◽  
Dominant Role ◽  
Formation Rate ◽  
Heat Transfer Process ◽  
Operating Conditions ◽  
Industrial Glass ◽  
Nitric Oxide Emissions ◽  
Glass Furnaces

The effects of combustion excess-air level, air preheating, and fuel composition on the nitric oxide emissions from an industrial glass furnace are studied through the use of a mathematical model. The mathematical model is based on the solution of the time-averaged form of the governing conservation equations for mass, momentum, energy, and chemical species. The k-ε turbulence model is employed for modelling the turbulence fluxes. The flame is modelled as a turbulent diffusion one and the chemical reactions associated with the heat release are assumed to be fast. The fluctuations of scalar properties are accounted for by use of a clipped-Gaussian probability density function. The thermal radiation, playing the dominant role in the heat-transfer process, is modelled using the discrete transfer method. Because of the high temperatures at which industrial glass furnaces operate a considerable amount of thermal NO is formed. The present work presents a model, based on a chemical kinetic approach, to predict the nitric oxide emissions from industrial glass furnaces. The Zeldovich mechanism, retaining the reverse reactions, is incorporated in the model in order to predict the instantaneous NO net formation rate from atmospheric nitrogen. The whole procedure is applied to a cross-fired regenerative furnace. A set of parametric studies is carried out, demonstrating the ability of the model to evaluate the influence of changes in operating conditions on the NO emissions.

Modelling of Nitric Oxide Formation During Liquid Fuel Combustion

2016 ◽  
Vol 246 ◽  
pp. 279-283
Author(s):  
Stanisław Gil ◽  
Wojciech Bialik
Keyword(s):  
Nitric Oxide ◽  
Experimental Data ◽  
Carbon Monoxide ◽  
Liquid Fuel ◽  
Combustion Process ◽  
Fuel Combustion ◽  
Nitric Oxides ◽  
Oxide Formation ◽  
Nitric Oxide Formation ◽  
The Impact

A liquid fuel combustion process, being a source of many environmentally hazardous pollutants (e.g. nitric oxides, carbon monoxide, polycyclic aromatic hydrocarbons, soot and sulphur oxides), is a subject of extensive research aimed at reduction of their emissions. A high temperature of the combustion air tends to increase the content of NOX in exhaust gases. Based on the experimental data and literature as well as using the CFD tools, a model of light fuel oil combustion has been developed with an emphasis on nitric oxide formation. The model adequately reflects the impact of geometry changes in the flow of combustion substrates on concentrations of carbon monoxide and nitric oxides in the chamber. The quantitative results obtained are comparable to the experimental data.

Enhancement of the combustion process in dual-fuel engines at part loads using exhaust gas recirculation

2007 ◽  
Vol 221 (7) ◽  
pp. 877-888 ◽  
Author(s):  
V Pirouzpanah ◽  
R Khoshbakhti Saray
Keyword(s):  
Chemical Kinetics ◽  
Combustion Process ◽  
Exhaust Gas Recirculation ◽  
Operating Conditions ◽  
Combustion Model ◽  
Dual Fuel ◽  
Exhaust Gas ◽  
Performance And Emission ◽  
Dual Fuel Engines ◽  
Gas Recirculation

Dual-fuel engines at part loads inevitably suffer from lower thermal efficiency and higher carbon monoxide and unburned fuel emission. The present work was carried out to investigate the combustion characteristics of a dual-fuel (diesel-gas) engine at part loads, using a single-zone combustion model with detailed chemical kinetics for combustion of natural gas fuel. The authors have developed software in which the pilot fuel is considered as a subsidiary zone and a heat source derived from two superimposedWiebe combustion functions to account for its contribution to ignition of the gaseous fuel and the rest of the total released energy. The chemical kinetics mechanism consists of 112 reactions with 34 species. This quasi-two-zone combustion model is able to establish the development of the combustion process with time and the associated important operating parameters, such as pressure, temperature, heat release rate (HRR), and species concentration. Therefore, this paper describes an attempt to investigate the combustion phenomenon at part loads and using hot exhaust gas recirculation (EGR) to improve the above-mentioned drawbacks and problems. By employing this technique, it is found that lower percentages of EGR and allowance for its thermal and radical effects have a positive influence on performance and emission parameters of dual-fuel engines at part loads. Predicted values show good agreement with corresponding experimental values under special engine operating conditions (quarter-load, 1400 r/min). Implications are discussed in detail.

A Study on Biodiesel NOx Emission Control With the Reduced Chemical Kinetics Model

2014 ◽  
Vol 136 (10) ◽  
Author(s):  
Juncheng Li ◽  
Zhiyu Han ◽  
Cai Shen ◽  
Chia-fon Lee
Keyword(s):  
Chemical Kinetics ◽  
Combustion Process ◽  
Operating Conditions ◽  
Nox Emission ◽  
Kinetics Model ◽  
Combustion Model ◽  
Nox Emissions ◽  
Soot Emission ◽  
Start Of Injection ◽  
Combustion Processes

In this paper, the effects of the start of injection (SOI) timing and exhaust gas recirculation (EGR) rate on the nitrogen oxides (NOx) emissions of a biodiesel-powered diesel engine are studied with computational fluid dynamics (CFD) coupling with a chemical kinetics model. The KIVA code coupling with a CHEMKIN-II chemistry solver is applied to the simulation of the in-cylinder combustion process. A surrogate biodiesel mechanism consisting of two fuel components is employed as the combustion model of soybean biodiesel. The in-cylinder combustion processes of the cases with four injection timings and three EGR rates are simulated. The simulation results show that the calculated NOx emissions of the cases with default EGR rate are reduced by 20.3% and 32.9% when the injection timings are delayed by 2- and 4-deg crank angle, respectively. The calculated NOx emissions of the cases with 24.0% and 28.0% EGR are reduced by 38.4% and 62.8%, respectively, compared to that of the case with default SOI and 19.2% EGR. But higher EGR rate deteriorates the soot emission. When EGR rate is 28.0% and SOI is advanced by 2 deg, the NOx emission is reduced by 55.1% and soot emission is controlled as that of the case with 24% EGR and default SOI. The NOx emissions of biodiesel combustion can be effectively improved by SOI retardation or increasing EGR rate. Under the studied engine operating conditions, introducing more 4.8% EGR into the intake air with unchanged SOI is more effective for NOx emission controlling than that of 4-deg SOI retardation with default EGR rate.

Combustion Quasi-Two Zone Predictive Model for Dual Fuel Engines

1999 ◽  
Author(s):  
G. H. Abd Alla ◽  
H. A. Soliman ◽  
O. A. Badr ◽  
M. F. Abd Rabbo
Keyword(s):  
Predictive Model ◽  
Combustion Process ◽  
Chemical Species ◽  
Kinetic Scheme ◽  
Chemical Kinetic ◽  
Operating Conditions ◽  
Gaseous Fuel ◽  
Combustion Model ◽  
Dual Fuel ◽  
Dual Fuel Engines

Abstract A quasi-two zone predictive model developed in the present work for the prediction of the combustion processes in dual fuel engines and some of their performance features. Methane is used as the main fuel while employing a small quantity of liquid fuel (pilot) injected through the conventional diesel fuel system. This model emphasizes the effects of chemical kinetics activity of the premixed gaseous fuel on the combustion performance, while the role of the pilot fuel in the ignition and heat release processes is considered. A detailed chemical kinetic scheme consists of 178 elementary reaction steps and 41 chemical species is employed to describe the oxidation of the gaseous fuel from the start of compression to the end of expansion process. The associated formation and concentrations of exhaust emissions are correspondingly established. This combustion model is able to establish the development of the combustion process with time and the associated important operating parameters such as pressure, temperature, rates of energy release and composition. Predicted values for methane operation show good agreement with corresponding previous experimental values over a range of operating conditions mainly associated with high load operation.

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