Prospect of Reduced CO and NOx Emissions in Diesel Dual Fuel Engines

Author(s):  
Mwila C. Mulenga ◽  
Graham T. Reader ◽  
David S.-K. Ting ◽  
Ming Zheng

A numerical analysis of homogeneous natural gas/diesel/air mixture, that could be formed when small amounts of diesel pilot are used in a diesel dual fuel engine or when using natural gas/diesel dual fuel homogeneous charge compression ignition combustion, was studied to provide insight on future experimental investigations to be conducted by the institution. Use was made of Curran’s normal-heptane mechanism in CHEMKIN to deduce its effects on lean fuel/air mixtures with respect to ignition timing and carbon monoxide (CO) and oxides of nitrogen (NOx) emissions. For the cases considered, increase in the amount of n-heptane addition resulted in advanced ignition closer to TDC thereby increasing peak cylinder pressure and gross IMEP. Increase in the amount of n-heptane addition also resulted in early decomposition of the fuel consequently advancing the production of OH radicals that oxidised the CO. For the same fuel/air mixture strength, increase in the amount of n-heptane addition increased NOx production due to increased peak temperature, residence time and availability of O2. When using leaner mixtures and small amounts of n-heptane to promote/advance ignition, however, peak cylinder temperatures were reduced and hence comparatively reducing engine-out NOx emissions.

Author(s):  
N. Kapilan ◽  
Chandramohan Somayaji ◽  
P. Mohanan ◽  
R. P. Reddy

In the present work, an attempt has been made for the effective utilization of Compressed Natural Gas (CNG) in diesel engine. A four stroke, single cylinder diesel engine was modified to work on dual fuel mode. The effect of CNG flow rate and Exhaust Gas Recirclulation (EGR) on the performance and emissions of the dual fuel engine was studied. The variables considered for the tests were different CNG flow rates (0.2, 0.3, 0.4, 0.5, 0.6 and 0.7 kg/hr), EGR (0 %, 4.28 %, 6.63 % and 8.12 %) and loads (25 %, 50 %, 75 % and 100 % of full load). From the test results, it was observed that the EGR rate of 4.28 % results in better brake thermal efficiency and lower CO and NOx emissions than other ERG rates at 25 %, 50% and 75% of full loads. At full load, EGR rate of 8.12 % results in higher brake thermal efficiency and lower NOx emissions.


2021 ◽  
Vol 9 (2) ◽  
pp. 123
Author(s):  
Sergejus Lebedevas ◽  
Lukas Norkevičius ◽  
Peilin Zhou

Decarbonization of ship power plants and reduction of harmful emissions has become a priority in the technological development of maritime transport, including ships operating in seaports. Engines fueled by diesel without using secondary emission reduction technologies cannot meet MARPOL 73/78 Tier III regulations. The MEPC.203 (62) EEDI directive of the IMO also stipulates a standard for CO2 emissions. This study presents the results of research on ecological parameters when a CAT 3516C diesel engine is replaced by a dual-fuel (diesel-liquefied natural gas) powered Wartsila 9L20DF engine on an existing seaport tugboat. CO2, SO2 and NOx emission reductions were estimated using data from the actual engine load cycle, the fuel consumption of the KLASCO-3 tugboat, and engine-prototype experimental data. Emission analysis was performed to verify the efficiency of the dual-fuel engine in reducing CO2, SO2 and NOx emissions of seaport tugboats. The study found that replacing a diesel engine with a dual-fuel-powered engine led to a reduction in annual emissions of 10% for CO2, 91% for SO2, and 65% for NOx. Based on today’s fuel price market data an economic impact assessment was conducted based on the estimated annual fuel consumption of the existing KLASCO-3 seaport tugboat when a diesel-powered engine is replaced by a dual-fuel (diesel-natural gas)-powered engine. The study showed that a 33% fuel costs savings can be achieved each year. Based on the approved methodology, an ecological impact assessment was conducted for the entire fleet of tugboats operating in the Baltic Sea ports if the fuel type was changed from diesel to natural gas. The results of the assessment showed that replacing diesel fuel with natural gas achieved 78% environmental impact in terms of NOx emissions according to MARPOL 73/78 Tier III regulations. The research concludes that new-generation engines on the market powered by environmentally friendly fuels such as LNG can modernise a large number of existing seaport tugboats, significantly reducing their emissions in ECA regions such as the Baltic Sea.


Author(s):  
Yafeng Liu ◽  
Stuart R. Bell ◽  
K. Clark Midkiff

Abstract A phenomenological cycle simulation for a dual fuel engine has been developed to mathematically simulate the significant processes of the engine cycle, to predict specific performance parameters for the engine, and to investigate approaches to improve performance and reduce emissions. The simulation employs two zones (crevice and unburned) during the processes of exhaust, intake, compression before fuel injection starts, and expansion after combustion ends. From the start of fuel injection to the end of combustion, several, zones are utilized to account for crevice flow, diesel fuel spray, air entrainment, diesel fuel droplet evaporation, ignition delay, flame propagation, and combustion quenching. The crevice zone absorbs charge gas from the cylinder as pressure increases, and releases mass back into the chamber as pressure decreases. Some crevice mass released during late combustion may not be oxidized, resulting in emissions of hydrocarbon and carbon monoxide. Quenching ahead of the flame front may leave additional charge unburned, yielding high methane emissions. Potential reduction of engine-out NOx emissions with natural gas fueling has also been investigated. The higher substitution of natural gas in the engine produces less engine-out NOx emissions. This paper presents the development of the model, baseline predictions, and comparisons to experimental measurements performed in a single-cylinder Caterpillar 3400 series engine.


Author(s):  
M. Krishnamoorthi ◽  
S. Sreedhara ◽  
Pavan Prakash Duvvuri

Abstract This work investigates the effects of low reactivity fuel (LRF) on reactivity controlled compression ignition (RCCI) engine with fossil diesel. RCCI mode of combustion is a low temperature combustion (LTC) strategy which reduces both oxides of nitrogen (NOx) and soot emissions simultaneously. Syngas and methanol can be obtained from renewable biological resources and conventional coal. LRF (methanol, syngas and gasoline) has been supplied to the engine along with intake air and diesel is injected to initiate the combustion process. Test engine has been operated for different dual fuel modes at constant engine speed (1500 rpm) and load (80%). Closed cycle combustion simulations have been performed to complement the experimental results and in-cylinder dynamics. Particle size mimic (PSM) model has been used to investigate the soot particle number and mass-size distributions and mean particle size. Results confirmed that maximum gross indicated thermal efficiency (38%) has been observed in gasoline/diesel dual fuel mode. Compared to gasoline/diesel dual fuel mode, about 74% and 86%, lower soot and NOx emissions have been observed for methanol/diesel dual fuel mode, while about 46% and 52% lower soot and NOx emissions have been found in syngas/diesel mode. About 53% higher carbon monoxide emission has been observed for syngas/diesel case as compared to gasoline/diesel case. Predictions from soot modelling reveal that condensation mode, surface growth mode and nucleation mode particles are dominant in methanol, syngas and gasoline/diesel dual fuel modes respectively. Bigger primary soot particles (diameter > 35 nm, nanometre) have been observed for methanol/diesel mode and the gasoline/diesel mode shows a smaller size of primary particles.


2013 ◽  
Vol 136 (1) ◽  
Author(s):  
K. K. Srinivasan ◽  
S. R. Krishnan ◽  
Y. Qi

Dual fuel pilot-ignited natural gas engines are identified as an efficient and viable alternative to conventional diesel engines. This paper examines cyclic combustion fluctuations in conventional dual fuel and in dual fuel partially premixed combustion (PPC). Conventional dual fueling with 95% (energy basis) natural gas (NG) substitution reduces NOx emissions by almost 90% relative to neat diesel operation; however, this is accompanied by 98% increase in HC emissions, 10 percentage points reduction in fuel conversion efficiency (FCE) and 12 percentage points increase in COVimep. Dual fuel PPC is achieved by appropriately timed injection of a small amount of diesel fuel (2–3% on an energy basis) to ignite a premixed natural gas–air mixture to attain very low NOx emissions (less than 0.2 g/kWh). Cyclic variations in both combustion modes were analyzed by observing the cyclic fluctuations in start of combustion (SOC), peak cylinder pressures (Pmax), combustion phasing (Ca50), and the separation between the diesel injection event and Ca50 (termed “relative combustion phasing”). For conventional dual fueling, as NG substitution increases, Pmax decreases, SOC and Ca50 are delayed, and cyclic variations increase. For dual fuel PPC, as diesel injection timing is advanced from 20 deg to 60 deg BTDC, Pmax is observed to increase and reach a maximum at 40 deg BTDC and then decrease with further pilot injection advance to 60 deg BTDC, the Ca50 is progressively phased closer to TDC with injection advance from 20 deg to 40 deg BTDC, and is then retarded away from TDC with further injection advance to 60 deg BTDC. For both combustion modes, cyclic variations were characterized by alternating slow and fast burn cycles, especially at high NG substitutions and advanced injection timings. Finally, heat release return maps were analyzed to demonstrate thermal management strategies as an effective tool to mitigate cyclic combustion variations, especially in dual fuel PPC.


Author(s):  
K. K. Srinivasan ◽  
S. R. Krishnan ◽  
Y. Qi

Dual fuel pilot ignited natural gas engines are identified as an efficient and viable alternative to conventional diesel engines. This paper examines cyclic combustion fluctuations in conventional dual fuel and in dual fuel partially premixed low temperature combustion (LTC) at 1700 rev/min and 6 bar brake mean effective pressure (bmep). Conventional dual fueling with 95% (energy basis) natural gas (NG) substitution reduces NOx emissions by almost 90%t relative to straight diesel operation; however, this is accompanied by 98% increase in HC emissions, 10 percentage points reduction in fuel conversion efficiency (FCE) and 12 percentage points increase in COVimep. Dual fuel LTC is achieved by injection of a small amount of diesel fuel (2–3 percent on an energy basis) to ignite a premixed natural gas–air mixture to attain very low NOx emissions (less than 0.2 g/kWh). Cyclic variations in both combustion modes were analyzed by observing the cyclic fluctuations in start of combustion (SOC), peak cylinder pressures (Pmax), combustion phasing (Ca50), and the separation between the diesel injection event and Ca50 (termed “relative combustion phasing”). For conventional dual fueling, as % NG increases, Pmax decreases, SOC and Ca50 are delayed, and cyclic variations increase. For dual fuel LTC, as diesel injection timing is advanced from 20° to 60°BTDC, the relative combustion phasing is identified as an important combustion parameter along with SoC, Pmax, and CaPmax. For both combustion modes, cyclic variations were characterized by alternating slow and fast burn cycles, especially at high %NG and advanced injection timings. Finally, heat release return maps were analyzed to demonstrate thermal management strategies as an effective tool to mitigate cyclic combustion variations, especially in dual fuel LTC.


2020 ◽  
Vol 6 ◽  
Author(s):  
Shouvik Dev ◽  
Hongsheng Guo ◽  
Brian Liko

Diesel fueled compression ignition engines are widely used in power generation and freight transport owing to their high fuel conversion efficiency and ability to operate reliably for long periods of time at high loads. However, such engines generate significant amounts of carbon dioxide (CO2), nitrogen oxides (NOx), and particulate matter (PM) emissions. One solution to reduce the CO2 and particulate matter emissions of diesel engines while maintaining their efficiency and reliability is natural gas (NG)-diesel dual-fuel combustion. In addition to methane emissions, the temperatures of the diesel injector tip and exhaust gas can also be concerns for dual-fuel engines at medium and high load operating conditions. In this study, a single cylinder NG-diesel dual-fuel research engine is operated at two high load conditions (75% and 100% load). NG fraction and diesel direct injection (DI) timing are two of the simplest control parameters for optimization of diesel engines converted to dual-fuel engines. In addition to studying the combined impact of these parameters on combustion and emissions performance, another unique aspect of this research is the measurement of the diesel injector tip temperature which can predict potential coking issues in dual-fuel engines. Results show that increasing NG fraction and advancing diesel direct injection timing can increase the injector tip temperature. With increasing NG fraction, while the methane emissions increase, the equivalent CO2 emissions (cumulative greenhouse gas effect of CO2 and CH4) of the engine decrease. Increasing NG fraction also improves the brake thermal efficiency of the engine though NOx emissions increase. By optimizing the combustion phasing through control of the DI timing, brake thermal efficiencies of the order of ∼42% can be achieved. At high loads, advanced diesel DI timings typically correspond to the higher maximum cylinder pressure, maximum pressure rise rate, brake thermal efficiency and NOx emissions, and lower soot, CO, and CO2-equivalent emissions.


2008 ◽  
Vol 130 (2) ◽  
Author(s):  
K. K. Srinivasan ◽  
P. J. Mago ◽  
G. J. Zdaniuk ◽  
L. M. Chamra ◽  
K. C Midkiff

Intense energy security debates amidst the ever increasing demand for energy in the US have provided sufficient impetus to investigate alternative and sustainable energy sources to the current fossil fuel economy. This paper presents the advanced (injection) low pilot ignition natural gas (ALPING) engine as a viable, efficient, and low emission alternative to conventional diesel engines, and discusses further efficiency improvements to the base ALPING engine using organic rankine cycles (ORC) as bottoming cycles. The ALPING engine uses advance injection (50–60deg BTDC) of very small diesel pilots in the compression stroke to compression ignite a premixed natural gas-air mixture. It is believed that the advanced injection of the higher cetane diesel fuel leads to longer in-cylinder residence times for the diesel droplets, thereby resulting in distributed ignition at multiple spatial locations, followed by lean combustion of the higher octane natural gas fuel via localized flame propagation. The multiple ignition centers result in faster combustion rates and higher fuel conversion efficiencies. The lean combustion of natural gas leads to reduction in local temperatures that result in reduced oxides of nitrogen (NOx) emissions, since NOx emissions scale with local temperatures. In addition, the lean premixed combustion of natural gas is expected to produce very little particulate matter emissions (not measured). Representative base line ALPING (60deg BTDC pilot injection timing) (without the ORC) half load (1700rpm, 21kW) operation efficiencies reported in this study are about 35% while the corresponding NOx emission is about 0.02g∕kWh, which is much lower than EPA 2007 Tier 4 Bin 5 heavy-duty diesel engine statutes of 0.2g∕kWh. Furthermore, the possibility of improving fuel conversion efficiency at half load operation with ORCs using “dry fluids” is discussed. Dry organic fluids, due to their lower critical points, make excellent choices for waste heat recovery Rankine cycles. Moreover, previous studies indicate that dry fluids are more preferable compared to wet fluids because the need to superheat the fluid to extract work from the turbine is eliminated. The calculations show that ORC—turbocompounding results in fuel conversion efficiency improvements of the order of 10% while maintaining the essential low NOx characteristics of ALPING combustion.


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