Flowing Electrolyte As Coolant Inside the Microgrooves Embedded in the Electrodes: A Novel Thermal Management of Li-Ion Batteries

Author(s):  
Shahabeddin K. Mohammadian ◽  
Yuwen Zhang

Abstract One way to enhance thermal performance of the Li-ion batteries is embedding microgrooves inside the porous electrodes and flowing the electrolyte through these microgrooves. A 2D thermal Lattice Boltzmann Method (LBM) was employed to predict electrolyte flow, heat transfer, and internal heat generation inside the positive porous electrode. Size and number of the microgrooves were investigated, and it was found that embedding microgrooves inside the porous electrode improved the thermal performance of the Li-ion battery by keeping the electrode in lower temperatures and improving its temperature uniformity. Furthermore, increasing the number of microgrooves (in a constant ratio between total size of the microgrooves to size of the porous electrode) kept the porous electrode in lower temperatures and enhanced temperature uniformity.

2020 ◽  
Vol 142 (5) ◽  
Author(s):  
Shahabeddin K. Mohammadian ◽  
Yuwen Zhang

Abstract One way to enhance the thermal performance of the Li-ion batteries is embedding microgrooves inside the porous electrodes and flowing the electrolyte through these microgrooves. Heat transfer from the battery can be enhanced by having both convection and conduction heat transfers inside the electrodes, instead of conduction heat transfer alone. A two-dimensional thermal lattice Boltzmann method (LBM) was employed to predict electrolyte flow, heat transfer, and internal heat generation inside the positive porous electrode. Size and number of the microgrooves and the electrolyte flow velocity inside them were investigated, and it was found that embedding microgrooves inside the porous electrode improved the thermal performance of the Li-ion battery by keeping the electrode in lower temperatures and improving its temperature uniformity. Furthermore, increasing the electrolyte flow velocity as well as increasing the number of microgrooves (in a constant ratio between the total size of the microgrooves to the size of the porous electrode) kept the porous electrode in lower temperatures and enhanced temperature uniformity.


2020 ◽  
Vol MA2020-01 (1) ◽  
pp. 83-83
Author(s):  
Juan Alfonso Campos ◽  
Abhas Deva ◽  
Jarrod Lund ◽  
Aniruddha Jana ◽  
Ilenia Battiato ◽  
...  

2015 ◽  
Vol 1120-1121 ◽  
pp. 730-734 ◽  
Author(s):  
M.Yu. Maximov ◽  
A.A. Popovich ◽  
A.M. Rumyantsev

In this work, we investigated the influence of passivation coating of aluminum oxide on cycle life of lithium-ion batteries. Al2O3 was synthesized by atomic layer deposition directly on the porous electrodes based on LiCoO2. More than 800 charge-discharge cycles were done. No increase of internal resistance due to Al2O3 coating was observed. According to the results, electrodes coated by aluminum oxide have better cycle life.


2011 ◽  
Vol 196 (24) ◽  
pp. 10692-10697 ◽  
Author(s):  
Biao Zhang ◽  
Zhen-Dong Huang ◽  
Sei Woon Oh ◽  
Jang-Kyo Kim

2021 ◽  
Author(s):  
Julia Hestenes ◽  
Richard May ◽  
Jerzy Sadowski ◽  
Naiara Munich ◽  
Lauren Marbella

The high specific capacities of Ni-rich transition metal oxides have garnered immense interest for improving the energy density of Li-ion batteries (LIBs). Despite the potential of these materials, Ni-rich cathodes suffer from interfacial instabilities that lead to crystallographic rearrangement of the active material surface as well as the formation of a cathode electrolyte interphase (CEI) layer on the composite during electrochemical cycling. While changes in crystallographic structure can be detected with diffraction-based methods, probing the chemistry of the disordered, heterogeneous CEI layer is challenging. In this work, we use a combination of ex situ solid-state nuclear magnetic resonance (SSNMR) spectroscopy and X-ray photoemission electron microscopy (XPEEM) to provide chemical and spatial information on the CEI deposited on LiNi0.8Mn0.1Co0.1O2 (NMC811) composite cathode films. Specifically, XPEEM elemental maps offer insight into the lateral arrangement of the electrolyte decomposition products that comprise the CEI and paramagnetic interactions (assessed with electron paramagnetic resonance (EPR) and relaxation measurements) in 13C SSNMR provide information on the radial arrangement of the CEI from the NMC811 particles outward. Using this approach, we find that LiF, Li2CO3, and carboxy-containing structures are directly appended to NMC811 active particles, whereas soluble species detected during in situ 1H and 19F solution NMR experiments (e.g., alkyl carbonates, HF, and vinyl compounds) are randomly deposited on the composite surface. We show that the combined approach of ex situ SSNMR and XPEEM, in conjunction with in situ solution NMR, allows spatially-resolved, molecular-level characterization of paramagnetic surfaces and new insights into electrolyte oxidation mechanisms in porous electrode films.


Author(s):  
Ravi N Methekar ◽  
Vijayasekaran Boovaragavan ◽  
Mounika Arabandi ◽  
Venkatasailanathan Ramadesigan ◽  
Venkat R Subramanian ◽  
...  

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