Microscopic Approaches to Decomposition and Burning Processes of a Micro Plastic Resin Particle

2007 ◽  
Author(s):  
Atsunori Yamamoto ◽  
Ryuji Yamakita ◽  
Yojiro Ishino ◽  
Norio Ohiwa
Keyword(s):  
High Speed ◽  
Diffusion Flames ◽  
Temporal Variations ◽  
Heating Time ◽  
Liquid Fuels ◽  
Combustion Gas ◽  
Resin Particle ◽  
Schlieren System ◽  
Volatile Liquid ◽  
Plastic Resin

From a fundamental and microscopic viewpoint to elucidate the possibility and availability of thermal recycling of wasted plastic resin, a series of heating processes of melting, thermal decomposition and burning of a spherical micro plastic resin particle having a diameter of about 200 μm are observed, when it is suddenly exposed to hot oxidizing combustion gas. Three ingenious devices are introduced; the first is a high-speed microscopic direct and schlieren system, the second is a pre-mixed mini-burner for abrupt heating, which is equipped with a pair of spark gaps at its exit and is discharged synchronously with the starting signal of high-speed camera, and the third is a single mini-puff generator, which enables to extinguish instantly all flames around the micro particle at an arbitrary assigned time after the spark ignition. Polyethylene terephthalate and polyethylene are used as two typical plastic resins. In this paper the dependency of internal and external appearances of residual plastic embers on the heating time and the initial plastic composition is optically analyzed, along with appearances of internal micro bubbling, micro jets and micro diffusion flames during abrupt heating. Based on temporal variations of the surface area of a micro plastic particle, the burning rate constant is also evaluated and compared with well-known volatile liquid fuels.

High Speed Imaging of Forced Ignition Kernels in Non-Uniform Jet Fuel/Air Mixtures

2017 ◽  
Author(s):  
Sheng Wei ◽  
Brandon Sforzo ◽  
Jerry Seitzman
Keyword(s):  
Heat Release ◽  
High Speed ◽  
Air Flow ◽  
Cetane Number ◽  
High Energy ◽  
Liquid Fuels ◽  
High Speed Imaging ◽  
Ignition Probability ◽  
Turbine Engine ◽  
Planar Laser

This paper describes experimental measurements of forced ignition of prevaporized liquid fuels in a well-controlled facility that incorporates non-uniform flow conditions similar to those of gas turbine engine combustors. The goal here is to elucidate the processes by which the initially unfueled kernel evolves into a self-sustained flame. Three fuels are examined: a conventional Jet-A and two synthesized fuels that are used to explore fuel composition effects. A commercial, high-energy recessed cavity discharge igniter located at the test section wall ejects kernels at 15 Hz into a preheated, striated crossflow. Next to the igniter wall is an unfueled air flow; above this is a premixed, prevaporized, fuel-air flow, with a matched velocity and an equivalence ratio near 0.75. The fuels are prevaporized in order to isolate chemical effects. Differences in early ignition kernel development are explored using three, synchronized, high-speed imaging diagnostics: schlieren, emission/chemiluminescence, and OH planar laser-induced fluorescence (PLIF). The schlieren images reveal rapid entrainment of crossflow fluid into the kernel. The PLIF and emission images suggest chemical reactions between the hot kernel and the entrained fuel-air mixture start within tens of microseconds after the kernel begins entraining fuel, with some heat release possibly occurring. Initially, dilution cooling of the kernel appears to outweigh whatever heat release occurs; so whether the kernel leads to successful ignition or not, the reaction rate and the spatial extent of the reacting region decrease significantly with time. During a successful ignition event, small regions of the reacting kernel survive this dilution and are able to transition into a self-sustained flame after ∼1–2 ms. The low aromatic/low cetane number fuel, which also has the lowest ignition probability, takes much longer for the reaction zone to grow after the initial decay. The high aromatic, more easily ignited fuel, shows the largest reaction region at early times.

Phenomenon Identification and Ranking Exercise and a Review of Large-Scale Spray Modeling Technology

2008 ◽  
Author(s):  
Alexander L. Brown ◽  
Sam S. Yoon ◽  
Richard A. Jepsen
Keyword(s):  
High Speed ◽  
Large Scale ◽  
Fire Suppression ◽  
Particle Surface ◽  
Liquid Fuels ◽  
Fire Propagation ◽  
Research Activities ◽  
Ranking Exercise ◽  
Productive Research ◽  
Multi Phase

We are engaged in efforts to model spray phenomena. Applications of principal interest include the high-speed impact of large vessels of fuel and the subsequent fire, fire suppression, solid propellant fires, pressurized pipe or tank rupture, and fire propagation for cascading liquid fuels. To help guide research and development efforts geared towards designing an appropriate spray modeling capability, a Phenomenon Identification and Ranking exercise was conducted. The summarized results of the exercise in tabular format, a Phenomenon Identification and Ranking Table (PIRT), are presented. The table forms the context for a textual literature review of the existing state of knowledge for modeling applications of interest. This exercise highlights some of the shortcomings in existing tools and knowledge, and suggests productive research activities that can help advance the modeling capabilities for the desired applications. Notable needs exist for research in high Weber number particle-surface impacts, particle collisions, multi-physics couplings, and low void fraction multi-phase coupling.

Effect of Pre-Oxidation Treatment on the Thermal Shock Resistance of Thermal Barrier Coatings in a Combustion Gas Environment

2010 ◽  
Vol 654-656 ◽  
pp. 1924-1927 ◽  
Author(s):  
Hui Mei ◽  
Lai Fei Cheng ◽  
Ya Nan Liu ◽  
Li Tong Zhang
Keyword(s):  
Thermal Shock ◽  
Thermal Barrier Coatings ◽  
Thermal Shock Resistance ◽  
High Speed ◽  
Thermal Barrier ◽  
Air Plasma ◽  
Oxidation Treatment ◽  
Barrier Coatings ◽  
Combustion Gas ◽  
Shock Resistance

Thermal barrier coatings (TBCs) were deposited by an Air Plasma Spraying (APS) technique. The TBC coating comprised of 92 wt.% ZrO2 and 8 wt.% Y2O3 (YSZ), CoNiCrAlY bond coat, and MarM247 nickel base super alloy. After APS of YSZ two batches of TBC specimens were tested, one batch of which was pre-oxidised in air for 10h at 1080 oC. Both types of the specimens were directly pushed into a combustion gas at 1150 oC for 25 min and then out to the natural air for quenching. The combustion gas was produced by burning jet fuel with high speed air in a high temperature wind tunnel, which simulates the real service conditions in an aeroengine. Results show that TBCs prepared by the APS had good thermal shock resistance in the combustion gas. The pre-oxidation treatment of the TBC had a significant effect on its thermal shock life. The as-oxidised TBCs always had worse thermal shock resistance than the as-sprayed ones after thermal shock cycles.

Spreading behavior of firefighting foam solutions on typical liquid fuel surfaces

2021 ◽  
Author(s):  
Youjie Sheng ◽  
Yang Li ◽  
Kui Wu
Keyword(s):  
High Speed ◽  
Liquid Fuel ◽  
Spreading Rate ◽  
Liquid Fuels ◽  
Spreading Coefficient ◽  
Spreading Area ◽  
Spreading Behavior ◽  
Film Forming ◽  
Series Of Experiments ◽  
Spreading Coefficients

Abstract A series of experiments was performed to investigate the spreading behavior of firefighting foam solutions on liquid fuel surfaces. The spreading coefficients of six kinds of aqueous film-forming foam solutions and one fluorine-free foam solution on the surface of four liquid fuels, namely, cyclohexane, diesel, n-heptane, and ethanol, were calculated on the basis of surface and interfacial tension. Spreading behavior was studied systematically using a high-speed camera, and then the relationship between spreading behavior and spreading coefficient was analyzed. Furthermore, the spreading area and spreading rate of different foam solution droplets on liquid fuel surfaces were studied in depth. The spreading amount of the foam solution droplets on the liquid fuel surfaces was measured. Four typical spreading phenomena, namely, spreading, suspension, dissolution, and sinking, of AFFF solutions on liquid fuel surfaces were identified. Moreover, a positive spreading coefficient did not necessarily lead to the formation of an aqueous film. The spreading area, spreading rate, and spreading amount were not proportional to the spreading coefficient. During the evaluation of the spreading property of firefighting foam, the spreading coefficient, spreading rate, and spreading amount must be focused on instead of only the spreading coefficient.

Effect of Carbon Dioxide on the Laminar Burning Speed of Propane–Air Mixtures

2019 ◽  
Vol 141 (8) ◽  
Author(s):  
Sai C. Yelishala ◽  
Ziyu Wang ◽  
Hameed Metghalchi ◽  
Yiannis A. Levendis ◽  
Kumaran Kannaiyan ◽  
...  
Keyword(s):  
High Speed ◽  
Pressure Rise ◽  
Gas Temperature ◽  
Cmos Camera ◽  
Primary Input ◽  
One Dimensional ◽  
Schlieren System ◽  
Co2 Concentrations ◽  
Constant Volume Chamber ◽  
Laminar Burning Speed

This experimental research examined the effect of CO2 as a diluent on the laminar burning speed of propane–air mixtures. Combustion took place at various CO2 concentrations (0–80%), different equivalence ratios (0.7<ϕ<1.2) and over a range of temperatures (298–420 K) and pressures (0.5–6.2 atm). The experiments were performed in a cylindrical constant volume chamber with a Z-shaped Schlieren system, coupled with a high-speed CMOS camera to capture the propagation of the flames at speeds up to 4000 frames per second. The flame stability of these mixtures at different pressures, equivalence ratios, and CO2 concentrations was also studied. Only laminar, spherical, and smooth flames were considered in measuring laminar burning speed. Pressure rise data as a function of time during the flame propagation were the primary input of the multishell thermodynamic model for measuring the laminar burning speed of propane-CO2-air mixtures. The laminar burning speed of such blends was observed to decrease with the addition of CO2 and to increase with the gas temperature. It was also noted that the laminar burning speed decreases with increasing pressure. The collected experimental data were compared with simulation data obtained via a steady one-dimensional (1D) laminar premixed flame code from Cantera, using a detailed H2/CO/C1–C4 kinetics model encompassing 111 species and 784 reactions.

Experimental Investigation of Low Weber Number Post-Impact Drop Spreading on Solid Substrates

2010 ◽  
Author(s):  
Milind A. Jog ◽  
Raj M. Manglik
Keyword(s):  
Surface Tension ◽  
High Speed ◽  
Pure Water ◽  
Surfactant Solution ◽  
Video Camera ◽  
Dynamic Surface Tension ◽  
Temporal Variations ◽  
Dynamic Surface ◽  
Post Impact ◽  
Triton X

The post-impact spreading and recoil behaviors of droplets of pure liquids (water and ethanol) and aqueous solution of Triton X-100 (a surfactant) on a dry horizontal hydrophilic (glass) substrate are investigated for low Weber numbers. The evolution of drop shape during spreading and recoil are captured using a high-speed (4,000 frames per second) digital video camera. Digital image-processing was used to determine the spread and height of the liquid film on the surface from each frame. Unlike pure liquids, the liquid-gas interfacial tension for surfactant solution is a function of surface age, where surface tension is that of the solvent at zero time and then reaches an equilibrium value with increasing surface age. Furthermore, the equilibrium surface tension is a function of the surfactant concentration, which decreases from that of the solvent at zero concentration to that at the critical micelle concentration (CMC), and remains essentially constant thereafter. The surface tension of aqueous Triton X-100 solution varies from that of pure water to nearly that of ethanol. As such the comparison of transient droplet-impact-spreading-recoil behavior of the three liquids, or their temporal variations of the spread and the flattening factor, provides a basis for understanding the role of dynamic surface tension and surface wettability.

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