scholarly journals Influence of Residence Time on Fuel Spray Sauter Mean Diameter (SMD) and Emissions Using Biodiesel and its Blends in a Low NOx Gas Turbine Combustor

Author(s):  
Mohamed A. Altaher ◽  
Hu Li ◽  
Gordon E. Andrews

Biodiesels have advantages of low carbon footprint, reduced toxic emissions, improved energy supply security and sustainability and therefore attracted attentions in both industrial and aero gas turbines sectors. Industrial gas turbine applications are more practical biodiesels due to low temperature waxing and flow problems at altitude for aero gas turbine applications. This paper investigated the use of biodiesels in a low NOx radial swirler, as used in some industrial low NOx gas turbines. A waste cooking oil derived methyl ester biodiesel (WME) was tested on a radial swirler industrial low NOx gas turbine combustor under atmospheric pressure, 600K air inlet temperature and reference Mach number of 0.017&0.023. The pure WME, its blends with kerosene (B20 and B50) and pure kerosene were tested for gaseous emissions and lean extinction as a function of equivalence ratio for both Mach numbers. Sauter Mean Diameter (SMD) of the fuel spray droplets was calculated. The results showed that the WME and its blends had lower CO, UHC emissions and higher NOx emissions than the kerosene. The weak extinction limits were determined for all fuels and B100 has the lowest value. The higher air velocity (at Mach = 0.023) resulted in smaller SMDs which improved the mixing and atomizing of fuels and thus led to reductions in NOx emissions.

2000 ◽  
Author(s):  
K. Su ◽  
C. Q. Zhou

Abstract A numerical study was conducted to determine the effects of combustion condition parameters, including inlet temperature and pressure, fuel spray characteristics on NOx emissions in gas turbine combustion using the KIVA-3V code. Log-normal spray distribution was assumed for the simulation of real fuel spray distributions at injection. A simplified mechanism with 17-species and 26-step was employed for chemical reactions of Jet A in a formula of C12H23. A sector model of a typical annular combustor was used in calculations. Flow fields and temperature distributions were analyzed. A wide range of operating condition was varied with the inlet pressure from 0.1 to 2.0 MPa, inlet temperature from 400 to 900 K, and overall fuel/air ratio from 0.012 to 0.08. The results reasonably agreed with those from experimental data and Chemkin modeling, which demonstrates the applicability of KIVA-3V and the chemical mechanism to the predictions of NOx emissions. With respect to the inlet temperature, NOx productions show a trend of monotone increasing. As the inlet pressure increases, NOx emissions increase at the beginning and then decrease. The droplet mean diameter as well as injection velocity and angle were independently varied to distinguish the separate effects of variables involved. It is found that the NOx emissions decrease with the Sauter mean diameter, but increase with the injection velocity and angle of fuel sprays. It appears that KIVA-3V code can be a valuable tool for the development of low emission combustors.


Author(s):  
Oanh Nguyen ◽  
Scott Samuelsen

In view of increasingly stringent NOx emissions regulations on stationary gas turbines, lean combustion offers an attractive option to reduce reaction temperatures and thereby decrease NOx production. Under lean operation, however, the reaction is vulnerable to blowout. It is herein postulated that pilot hydrogen dopant injection, discretely located, can enhance the lean blowout performance without sacrificing overall performance. The present study addresses this hypothesis in a research combustor assembly, operated at atmospheric pressure, and fired on natural gas using rapid mixing injection, typical of commercial units. Five hydrogen injector scenarios are investigated. The results show that (1) pilot hydrogen dopant injection, discretely located, leads to improved lean blowout performance and (2) the location of discrete injection has a significant impact on the effectiveness of the doping strategy.


Author(s):  
Ralph A. Dalla Betta ◽  
James C. Schlatter ◽  
Sarento G. Nickolas ◽  
Martin B. Cutrone ◽  
Kenneth W. Beebe ◽  
...  

The most effective technologies currently available for controlling NOx emissions from heavy-duty industrial gas turbines are either diluent injection in the combustor reaction zone, or lean premixed Dry Low NOx (DLN) combustion. For ultra low emissions requirements, these must be combined with selective catalytic reduction (SCR) DeNOx systems in the gas turbine exhaust. An alternative technology for achieving comparable emissions levels with the potential for lower capital investment and operating cost is catalytic combustion of lean premixed fuel and air within the gas turbine. The design of a catalytic combustion system using natural gas fuel has been prepared for the GE model MS9OOIE gas turbine. This machine has a turbine inlet temperature to the first rotating stage of over 1100°C and produces approximately 105 MW electrical output in simple cycle operation. The 508 mm diameter catalytic combustor designed for this gas turbine was operated at full-scale conditions in tests conducted in 1992 and 1994. The combustor was operated for twelve hours during the 1994 test and demonstrated very low NOx emissions from the catalytic reactor. The total exhaust NOx level was approximately 12–15 ppmv and was produced almost entirely in the preburner ahead of the reactor. A small quantity of steam injected into the preburner reduced the NOx emissions to 5–6 ppmv. Development of the combustion system has continued with the objectives of reducing CO and UHC emissions, understanding the parameters affecting reactor stability and spatial non-uniformities which were observed at low inlet temperature, and improving the structural integrity of the reactor system to a level required for commercial operation of gas turbines. Design modifications were completed and combustion hardware was fabricated for additional full-scale tests of the catalytic combustion system in March 1995 and January 1996. This paper presents a discussion of the combustor design, the catalytic reactor design and the results of full-scale testing of the improved combustor at MS9OOIE cycle conditions in the March 1995 and January 1996 tests. Major improvements in performance were achieved with CO and UHC emissions of 10 ppmv and 0 ppmv at base load conditions. This ongoing program will lead to two additional full-scale combustion system tests in 1996. The results of these tests will be available for discussion at the June 1996 Conference in Birmingham.


1982 ◽  
Vol 104 (1) ◽  
pp. 52-57 ◽  
Author(s):  
S. J. Anderson ◽  
M. A. Friedman ◽  
W. V. Krill ◽  
J. P. Kesselring

Catalytically supported thermal combustion can provide low NOx emissions with gaseous and distillate fuels while maintaining high combustion efficiency. For stationary gas turbines, catalytic combustion may be the only emerging technology that can cost effectively meet recent federal regulations for NOx emissions. Under EPA sponsorship, a small-scale, catalytic gas turbine combustor was developed to evaluate transient and steady state combustor performance. The combustor consisted of a multiple air-atomizing fuel injector, an opposed jet igniter, and a graded-cell monolithic reactor. System startup, including opposed jet ignition and catalyst stabilization, was achieved in 250 seconds. This time interval is comparable to conventional gas turbines. Steady state operation was performed at 0.505 MPa (5 atmospheres) pressure and 15.3 m/s (50 ft/s) reference velocities. Thermal NOx emissions were measured below 10 ppmv, while fuel NOx conversion ranged from 75 to 95 percent. At catalyst bed temperatures greater than 1422K (2100°F), total CO and UHC emissions were less than 50 ppmv indicating combustion efficiency greater than 99.9 percent. Compared with conventional gas turbine combustors, the catalytic reactor operates only within a relatively narrow range of fuel/air ratios. As a result, modified combustor air distribution or fuel staging will be required to achieve the wide turndown required in large stationary systems.


Author(s):  
D. P. Teixeira ◽  
D. J. White ◽  
M. E. Ward

Results of a series of tests on a prevaporized, premixed combustor to evaluate its emissions control potential while operating on No. 2 distillate oil are presented. The concept utilized the heat capacity of the combustor inlet air to absorb the heat of vaporization of the fuel. Tests were conducted at combustor inlet temperatures and pressures characteristic of current generation electric utility gas turbines (345 C and 10 atm). NOx emissions in excess of proposed EPA gas turbine standards (75 ppm at 15 percent O) were observed at the 10 atm pressure condition and are believed to be the result of incomplete evaporation of the fuel Attempts to increase vaporization rates by increasing inlet air temperature were limited by autoignition of the mixture in the fuel preparation ports.


Author(s):  
A. Okuto ◽  
T. Kimura ◽  
I. Takehara ◽  
T. Nakashima ◽  
Y. Ichikawa ◽  
...  

Research and development project of ceramic gas turbines (CGT) was started in 1988 promoted by the Ministry of International Trade and Industry (MITI) in Japan. The target of the CGT project is development of a 300kW-class ceramic gas turbine with a 42 % thermal efficiency and a turbine inlet temperature (TIT) of 1350°C. Three types of CGT engines are developed in this project. One of the CGT engines, which is called CGT302, is a recuperated two-shaft gas turbine for co-generation use. In this paper, we describe the research and development of a combustor for the CGT302. The project requires a combustor to exhaust lower pollutant emissions than the Japanese regulation level. In order to reduce NOx emissions and achieve high combustion efficiency, lean premixed combustion technology is adopted. Combustion rig tests were carried out using this combustor. In these tests we measured the combustor performance such as pollutant emissions, combustion efficiency, combustor inlet/outlet temperature, combustor inlet pressure and pressure loss through combustor. Of course air flow rate and fuel flow rate are controlled and measured, respectively. The targets for the combustor such as NOx emissions and combustion efficiency were accomplished with sufficient margin in these combustion rig tests. In addition, we report the results of the tests which were carried out to examine effects of inlet air pressure on NOx emissions here.


Author(s):  
Hu Li ◽  
Mohamed Altaher ◽  
Gordon E. Andrews

Biofuels offer reduced CO2 emissions for both industrial and aero gas turbines. Industrial applications are more practical due to low temperature waxing problems at altitude. Any use of biofuels in industrial gas turbines must also achieve low NOx and this paper investigates the use of biofuels in a low NOx radial swirler, as used in some industrial low NOx gas turbines. A waste cooking oil derived methyl ester biodiesel (WME) has been tested on a radial swirler industrial low NOx gas turbine combustor under atmospheric pressure and 600K. The pure WME and its blends with kerosene, B20 and B50 (WME:kerosene = 20:80 and 50:50 respectively), and pure kerosene were tested for gaseous emissions and lean extinction as a function of equivalence ratio. The co-firing with natural gas (NG) was tested for kerosene/biofuel blends B20 and B50. The central fuel injection was used for liquid fuels and wall injection was used for NG. The experiments were carried out at a reference Mach number of 0.017. The inlet air to the combustor was heated to 600K. The results show that B20 produced similar NOx at an equivalence ratio of ∼0.5 and a significant low NOx when the equivalence ratio was increased comparing with kerosene. B50 and B100 produced higher NOx compared to kerosene, which indicates deteriorated mixing due to the poor volatility of the biofuel component. The biodiesel lower hydrocarbon and CO emissions than kerosene in the lean combustion range. The lean extinction limit was lower for B50 and B100 than kerosene. It is demonstrated that B20 has the lowest overall emissions. The co-firing with NG using B20 and B50 significantly reduced NOx and CO emissions.


1997 ◽  
Vol 119 (4) ◽  
pp. 844-851 ◽  
Author(s):  
R. A. Dalla Betta ◽  
J. C. Schlatter ◽  
S. G. Nickolas ◽  
M. B. Cutrone ◽  
K. W. Beebe ◽  
...  

The most effective technologies currently available for controlling NOx emissions from heavy-duty industrial gas turbines are diluent injection in the combustor reaction zone, and lean premixed Dry Low NOx (DLN) combustion. For ultralow emissions requirements, these must be combined with selective catalytic reduction (SCR) DeNOx systems in the gas turbine exhaust. An alternative technology for achieving comparable emissions levels with the potential for lower capital investment and operating cost is catalytic combustion of lean premixed fuel and air within the gas turbine. The design of a catalytic combustion system using natural gas fuel has been prepared for the GE model MS9OO1E gas turbine. This machine has a turbine inlet temperature to the first rotating stage of over 1100°C and produces approximately 105 MW electrical output in simple cycle operation. The 508-mm-dia catalytic combustor designed for this gas turbine was operated at full-scale conditions in tests conducted in 1992 and 1994. The combustor was operated for twelve hours during the 1994 test and demonstrated very low NOx emissions from the catalytic reactor. The total exhaust NOx level was approximately 12–15 ppmv and was produced almost entirely in the preburner ahead of the reactor. A small quantity of steam injected into the preburner reduced the NOx emissions to 5–6 ppmv. Development of the combustion system has continued with the objectives of reducing CO and UHC emissions, understanding the parameters affecting reactor stability and spatial nonuniformities that were observed at low inlet temperature, and improving the structural integrity of the reactor system to a level required for commercial operation of gas turbines. Design modifications were completed and combustion hardware was fabricated for additional full-scale tests of the catalytic combustion system in March 1995 and January 1996. This paper presents a discussion of the combustor design, the catalytic reactor design, and the results of full-scale testing of the improved combustor at MS9OO1E cycle conditions in the March 1995 and January 1996 tests. Major improvements in performance were achieved with CO and UHC emissions of 10 ppmv and 0 ppmv at baseload conditions. This ongoing program will lead to two additional full-scale combustion system tests in 1996. The results of these tests will be available for discussion at the June 1996 Conference in Birmingham.


Author(s):  
Géza Vermes

Based on a simplified description of the combustion process in the primary zone of a can type gas turbine combustor, a generalized NOx versus fuel flow relationship is proposed. Using this relationship and considerations based on chemical kinetics, the effect of combustor inlet pressure, inlet temperature and air residence time on NOx formation is investigated in industrial and automotive type combustion chambers. Data reported in the literature and original test work is cited to substantiate the validity of the assumptions. Based on the findings, a simple method is presented to predict NOx emissions of a gas turbine combustor under conditions which differ substantially from those of the test run. The assumptions may be used to assemble a model for a priori prediction of NOx emissions in a given combustion geometry.


Author(s):  
Oliver Lammel ◽  
Harald Schu¨tz ◽  
Guido Schmitz ◽  
Rainer Lu¨ckerath ◽  
Michael Sto¨hr ◽  
...  

In this contribution, an overview of the progress in the design of an enhanced FLOX® burner is given. A fuel flexible burner concept was developed to fulfill the requirements of modern gas turbines: high specific power density, high turbine inlet temperature, and low NOx emissions. The basis for the research work is numerical simulation. With the focus on pollutant emissions a detailed chemical kinetic mechanism is used in the calculations. A novel mixing control concept, called HiPerMix®, and its application in the FLOX® burner is presented. In view of the desired operational conditions in a gas turbine combustor this enhanced FLOX® burner was manufactured and experimentally investigated at the DLR test facility. In the present work experimental and computational results are presented for natural gas and natural gas + hydrogen combustion at gas turbine relevant conditions and high adiabatic flame temperatures (up to Tad = 2000 K). The respective power densities are PA = 13.3 MW/m2/bar (NG) and PA = 14.8 MW/m2/bar (NG + H2) satisfying the demands of a gas turbine combustor. It is demonstrated that the combustion is complete and stable and that the pollutant emissions are very low.


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