Phosphor Based Temperature Indicating Paints

2012 ◽  
Author(s):  
A. L. Heyes ◽  
A. Rabhiou ◽  
J. P. Feist ◽  
A. M. Kempf
Keyword(s):  
Thermal History ◽  
Gas Turbines ◽  
Room Temperature ◽  
Extreme Environments ◽  
Thermal Barrier ◽  
Operation Analysis ◽  
Barrier Coating ◽  
Post Operation ◽  
On Line ◽  
Line Temperature

The ability to measure temperature in extreme environments such as the hot sections of gas turbines is critically important. Several on-line techniques exist but it is often not possible to measure in real-time the temperature of all surfaces of interest. Indeed, some surfaces are so inaccessible as to require complex, costly and intrusive instrumentation for on-line temperature measurement. Here, off-line sensors, also called thermal history sensors, can be used to record the temperatures to which they are exposed, in such a way that they can be extracted later off-line, at room temperature. Probably the best-known types of thermal history sensor are the colour changing thermal paints, that are widely used in gas turbine development. These have been valuable tools of engine developers for many years, but their use presents a number of challenges so that alternatives would be welcome. This paper reports the latest developments of a thermal history sensor based on phosphors that undergo permanent changes in their luminescence properties when exposed to high temperatures. Such thermal history sensors have several advantages over and address many of the shortcomings of existing sensors. The paper contains details of the application of a phosphor-based temperature indicating paint based on Y2SiO5:Tb suspended in a chemical binder. The binder was found to influence the optical properties of the phosphor but despite this, a viable sensor paint for temperatures in the range 400°C to 900°C was formed. A thermal history coating was installed using a thermal barrier coating architecture, applied on various components of a Royce-Rolls Viper 201 engine owned by STS and operated for a number of hours at Cranfield University. Post-operation analysis revealed a temperature distribution on the surfaces/components and enabled hotspots to be identified. Overall the results suggest that phosphor-based temperature indicating paints have the potential to surpass the capability of existing paints.

Off-Line Temperature Profiling Utilising Phosphorescent Thermal History Paints and Coatings

2014 ◽  
Author(s):  
J. P. Feist ◽  
S. Karmaker Biswas ◽  
C. Pilgrim ◽  
P. Y. Sollazzo ◽  
S. Berthier
Keyword(s):  
Thermal History ◽  
Gas Turbines ◽  
Elevated Temperatures ◽  
Life Time ◽  
Temperature Measurements ◽  
Host Material ◽  
Air Plasma ◽  
Spray Process ◽  
Barrier Coating ◽  
Line Temperature

Temperature profiling of components in gas turbines is of increasing importance as engineers drive to increase firing temperatures and optimise component’s cooling requirements in order to increase efficiency and lower CO2 emissions. However, on-line temperature measurements and, particularly, temperature profiling are difficult, sometimes impossible, to perform due to inaccessibility of the components. A desirable alternative would be to record the exposure temperature in such a way that it can be determined later, off-line. The commercially available Thermal Paints are toxic in nature and come with a range of technical disadvantages such as subjective readout and limited durability. This paper proposes a novel alternative measurement technique which the authors call Thermal History Paints and Thermal History Coatings. These can be particularly useful in the design process, but further could provide benefits in the maintenance area where hotspots which occurred during operation can be detected during maintenance intervals when the engine is at ambient temperature. This novel temperature profiling technique uses optical active ions in a ceramic host material. When these ions are excited by light they start to phosphoresce. The host material undergoes irreversible changes when exposed to elevated temperatures and since these changes are on the atomic level they influence the phosphorescent properties such as the life time decay of the phosphorescence. The changes in phosphorescence can be related to temperature through calibration such that in-situ analysis will return the temperature experienced by the coating. A major benefit of this technique is in the automated interpretation of the coatings. An electronic instrument is used to measure the phosphorescence signal eliminating the need for a specialist interpreter and thus increasing readout speed. This paper reviews results from temperature measurements made with a water based paint for the temperature range 100°C to 800°C in controlled conditions. Repeatability of the tests and errors will be discussed. Further, some measurements are carried out using an electronic hand-held interrogation device which can scan a component surface and provide a spatial resolution of below 3mm. The instrument enables mobile measurements outside of laboratory conditions. Further a robust Thermal History Coating is introduced demonstrating the capability of the coating to withstand long term exposures. The coating is based on Thermal Barrier Coating architecture with a high temperature bondcoat and deposited using an air plasma spray process to manufacture a reliable long lasting coating. Such a coating could be employed over the life of the component to provide critical temperature information at regular maintenance intervals for example indicating hot spots on engine parts.

Off-Line Temperature Profiling Utilizing Phosphorescent Thermal History Paints and Coatings

2015 ◽  
Vol 137 (10) ◽  
Author(s):  
J. P. Feist ◽  
S. Karmakar Biswas ◽  
C. C. Pilgrim ◽  
P. Y. Sollazzo ◽  
S. Berthier
Keyword(s):  
Thermal History ◽  
Gas Turbines ◽  
Elevated Temperatures ◽  
Life Time ◽  
Temperature Measurements ◽  
Host Material ◽  
Air Plasma ◽  
Spray Process ◽  
Barrier Coating ◽  
Line Temperature

Temperature profiling of components in gas turbines is of increasing importance as engineers drive to increase firing temperatures and optimize component’s cooling requirements in order to increase efficiency and lower CO2 emissions. However, on-line temperature measurements and, particularly, temperature profiling are difficult, sometimes impossible, to perform due to inaccessibility of the components. A desirable alternative would be to record the exposure temperature in such a way that it can be determined later, off-line. The commercially available thermal paints are toxic in nature and come with a range of technical disadvantages such as subjective readout and limited durability. This paper proposes a novel alternative measurement technique which the authors call thermal history paints and thermal history coatings. These can be particularly useful in the design process, but further could provide benefits in the maintenance area where hotspots which occurred during operation can be detected during maintenance intervals when the engine is at ambient temperature. This novel temperature profiling technique uses optical active ions in a ceramic host material. When these ions are excited by light they start to phosphoresce. The host material undergoes irreversible changes when exposed to elevated temperatures and since these changes are on the atomic level they influence the phosphorescent properties such as the life time decay of the phosphorescence. The changes in phosphorescence can be related to temperature through calibration such that in situ analysis will return the temperature experienced by the coating. A major benefit of this technique is in the automated interpretation of the coatings. An electronic instrument is used to measure the phosphorescence signal eliminating the need for a specialist interpreter, and thus increasing readout speed. This paper reviews results from temperature measurements made with a water-based paint for the temperature range 100–800 °C in controlled conditions. Repeatability of the tests and errors are discussed. Further, some measurements are carried out using an electronic hand-held interrogation device which can scan a component surface and provide a spatial resolution of below 3 mm. The instrument enables mobile measurements outside of laboratory conditions. Further, a robust thermal history coating is introduced demonstrating the capability of the coating to withstand long term exposures. The coating is based on thermal barrier coating (TBC) architecture with a high temperature bondcoat and deposited using an air plasma spray process to manufacture a reliable long lasting coating. Such a coating could be employed over the life of the component to provide critical temperature information at regular maintenance intervals for example indicating hot spots on engine parts.

scholarly journals Progress in Novel Electrodeposited Bond Coats for Thermal Barrier Coating Systems

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4214
Author(s):  
Kranthi Kumar Maniam ◽  
Shiladitya Paul
Keyword(s):  
Gas Turbine ◽  
Thermal Barrier Coating ◽  
Gas Turbines ◽  
High Performance ◽  
Turbine Engines ◽  
Thermal Barrier ◽  
Gas Turbine Engines ◽  
Potential Cost ◽  
Bond Coats ◽  
Barrier Coating

The increased demand for high performance gas turbine engines has resulted in a continuous search for new base materials and coatings. With the significant developments in nickel-based superalloys, the quest for developments related to thermal barrier coating (TBC) systems is increasing rapidly and is considered a key area of research. Of key importance are the processing routes that can provide the required coating properties when applied on engine components with complex shapes, such as turbine vanes, blades, etc. Despite significant research and development in the coating systems, the scope of electrodeposition as a potential alternative to the conventional methods of producing bond coats has only been realised to a limited extent. Additionally, their effectiveness in prolonging the alloys’ lifetime is not well understood. This review summarises the work on electrodeposition as a coating development method for application in high temperature alloys for gas turbine engines and discusses the progress in the coatings that combine electrodeposition and other processes to achieve desired bond coats. The overall aim of this review is to emphasise the role of electrodeposition as a potential cost-effective alternative to produce bond coats. Besides, the developments in the electrodeposition of aluminium from ionic liquids for potential applications in gas turbines and the nuclear sector, as well as cost considerations and future challenges, are reviewed with the crucial raw materials’ current and future savings scenarios in mind.

scholarly journals Research on Thermal Stability and Properties of Ca3ZrSi2O9 as Potential T/EBC Materials

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 583
Author(s):  
Yangyang Pan ◽  
Bo Liang ◽  
Yaran Niu ◽  
Dijuan Han ◽  
Dongdong Liu ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Stability ◽  
Fracture Toughness ◽  
Room Temperature ◽  
Coefficient Of Thermal Expansion ◽  
Atmospheric Plasma ◽  
Thermal Barrier ◽  
Mechanical And Thermal Properties ◽  
Self Healing ◽  
Barrier Coating

In this study, a new coating material for thermal barrier coating (TBC) or environment barrier coating (EBC) application, Ca3ZrSi2O9 (CZSO), was synthesized and prepared by atmospheric plasma spray (APS) technology. The evolution of the phases and microstructures of the coatings with different thermal-aged were characterized by XRD, XRF, EDS and SEM, respectively. The thermal stability was measured by TG-DTA and DSC. The mechanical and thermal properties, including Vickers hardness (HV), fracture toughness (KIC), thermal conductivity () and coefficient of thermal expansion (CTE) were focused on. It was found that the as-sprayed CZSO coating contained amorphous phase. Crystalline transformation happened at 900–960 ∘C and no mass changes took place from room temperature (RT) to 1300 ∘C. The phenomena of microcrack self-healing and composition uniformity were observed during thermal aging. The of coating was very low at about 0.57–0.80 Wm−1K−1 in 200–1200 ∘C. The combined properties indicated that the CZSO coating might be a potential T/EBC material.

Mechanical Properties of Thermal Barrier Coatings at Room Temperature

2005 ◽  
Vol 290 ◽  
pp. 336-339 ◽  
Author(s):  
G. Guidoni ◽  
Y. Torres Hernández ◽  
Marc Anglada
Keyword(s):  
Mechanical Properties ◽  
Thermal Barrier Coatings ◽  
Room Temperature ◽  
Inconel 625 ◽  
Thermal Barrier ◽  
Barrier Coatings ◽  
Bending Tests ◽  
Four Point Bending ◽  
Barrier Coating ◽  
Plasma Sprayed

Four point bending tests have been carried out on a thermal barrier coating (TBC) system, at room temperature. The TBC system consisted of a plasma sprayed Y-TZP top coat with 8 % in weight of Yttria, a bond coat of NiCrAlY and a Ni-based superalloy Inconel 625 as substrate. The TBC coating was deposited on both sides of the prismatic specimens. Efforts have been done in detecting the damage of the coating by means of Maltzbender et al [1] model.

Effects of Powder Morphology, Microstructure, and Residual Stresses on Thermal Barrier Coating Thermal Shock Performance

1996 ◽  
Author(s):  
J. Wigren ◽  
J.-F. de Vries ◽  
D. Greving
Keyword(s):  
Residual Stresses ◽  
Thermal Shock ◽  
Thermal Barrier Coating ◽  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
Thermal Barrier ◽  
Spray Parameters ◽  
Powder Morphology ◽  
Barrier Coatings ◽  
Barrier Coating

Abstract Thermal barrier coatings are used in the aerospace industry for thermal insulation in hot sections of gas turbines. Improved coating reliability is a common goal among jet engine designers. In-service failures, such as coating cracking and spallation, result in decreased engine performance and costly maintenance time. A research program was conducted to evaluate residual stresses, microstructure, and thermal shock life of thermal barrier coatings produced from different powder types and spray parameters. Sixteen coatings were ranked according to their performance relative to the other coatings in each evaluation category. Comparisons of residual stresses, powder morphology, and microstructure to thermal shock life indicate a strong correlation to thermal barrier coating performance. Results from these evaluations will aid in the selection of an optimum thermal barrier coating system for turbine engine applications.

Effects of Surface Deposition, Hole Blockage, and Thermal Barrier Coating Spallation on Vane Endwall Film Cooling

2006 ◽  
Vol 129 (3) ◽  
pp. 599-607 ◽  
Author(s):  
N. Sundaram ◽  
K. A. Thole
Keyword(s):  
Thermal Barrier Coating ◽  
Film Cooling ◽  
Gas Turbines ◽  
Large Scale ◽  
Leading Edge ◽  
Thermal Barrier ◽  
Cooling Effectiveness ◽  
Barrier Coating ◽  
Cooling Hole ◽  
Alternate Fuels

With the increase in usage of gas turbines for power generation and given that natural gas resources continue to be depleted, it has become increasingly important to search for alternate fuels. One source of alternate fuels is coal derived synthetic fuels. Coal derived fuels, however, contain traces of ash and other contaminants that can deposit on vane and turbine surfaces affecting their heat transfer through reduced film cooling. The endwall of a first stage vane is one such region that can be susceptible to depositions from these contaminants. This study uses a large-scale turbine vane cascade in which the following effects on film cooling adiabatic effectiveness were investigated in the endwall region: the effect of near-hole deposition, the effect of partial film cooling hole blockage, and the effect of spallation of a thermal barrier coating. The results indicated that deposits near the hole exit can sometimes improve the cooling effectiveness at the leading edge, but with increased deposition heights the cooling deteriorates. Partial hole blockage studies revealed that the cooling effectiveness deteriorates with increases in the number of blocked holes. Spallation studies showed that for a spalled endwall surface downstream of the leading edge cooling row, cooling effectiveness worsened with an increase in blowing ratio.

R&D Status and Needs for Improved EB-PVD Thermal Barrier Coating Performance

2000 ◽  
Vol 645 ◽  
Author(s):  
C. Leyens ◽  
U. Schulz ◽  
M. Bartsch ◽  
M. Peters
Keyword(s):  
Thermal Barrier Coating ◽  
Bond Coat ◽  
Gas Turbines ◽  
Systems Approach ◽  
Thermally Grown Oxide ◽  
Thermal Barrier ◽  
Factors Affecting ◽  
Performance Improvements ◽  
Barrier Coating ◽  
Temperature Capability

ABSTRACTThe key issues for thermal barrier coating development are high temperature capability and durability under thermal cyclic conditions as experienced in the hot section of gas turbines. Due to the complexity of the system and the interaction of the constituents, performance improvements require a systems approach. However, there are issues closely related to the ceramic top coating and the bond coat, respectively. Reduced thermal conductivity, sintering, and stresses within the ceramic coating are addressed in the paper as well as factors affecting failure of the TBC by spallation. The latter is primarily governed by the formation and growth of the thermally grown oxide scale and therefore related to the bond coat. A strategy for lifetime assessment of TBCs is discussed.

STUDY FOR BLADE CERAMIC COATING DELAMINATION DETECTION FOR GAS TURBINE

2008 ◽  
Vol 22 (31n32) ◽  
pp. 5699-5704 ◽  
Author(s):  
CHOUL-JUN CHOI ◽  
SEUNG HYUN CHOI ◽  
JAE-YEOL KIM
Keyword(s):  
Thermal Barrier Coating ◽  
Gas Turbines ◽  
Life Assessment ◽  
Thermal Barrier ◽  
Large Area ◽  
Pulsed Thermography ◽  
Barrier Coating ◽  
Reliable Assessment ◽  
Coating Delamination ◽  
Remedial Actions

The component of the hot gas path in gas turbines can survive to very high temperatures because they are protected by ceramic Thermal Barrier Coating (TBC); the failure of such coating can dramatically reduce the component life. A reliable assessment of the Coating integrity and/or an Incipient TBC Damage Detection can help both in optimizing the inspection intervals and in finding the appropriate remedial actions. This study gives the TBC integrity; so other methods are required, like thermography to obtain indications of TBC delamination. Pulsed Thermography detects coating detachments and interface defects, with a large area of view but a spatial resolution of few mm. The mentioned techniques as a whole constitute a powerful tool for the life assessment of thermal barrier coating.

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