Development and Operation of a Pressurized Optically-Accessible Research Combustor for Simulation Validation and Fuel Variability Studies

Author(s):  
T. Sidwell ◽  
K. Casleton ◽  
D. Straub ◽  
D. Maloney ◽  
G. Richards ◽  
...  

The U.S. Department of Energy Turbines Program has established very stringent NOx emissions goals of less than 3 ppmv for future turbine power generation. These future turbine power plants may operate on hydrogen-rich fuels, such as coal-derived synthesis gas (syngas), or pure hydrogen derived from shifting the syngas. Achieving these goals is expected to require improved combustor concepts which may be dramatically different than current combustor designs. Significant and costly experimental testing is usually required to assess new combustor concepts. Ideally, new concepts could be evaluated with numeric simulations to reduce development time and cost. However, current simulation capabilities are not sufficient to reliably capture the effects of fuel variations on flame extinction, emissions levels, and dynamic stability. Furthermore, very little data with controlled boundary conditions are available to check numeric predictions at actual turbine engine conditions, or simply to assess combustor performance without ambiguous boundary conditions. This paper presents a description of the development and operation of an optically-accessible research combustor, which is designed to provide fundamental combustion data at elevated pressure and inlet air temperature, and with precisely determined thermal, acoustic, and flow boundary conditions. The effects of fuel composition variations are investigated by blending of controlled quantities of hydrogen with natural gas. Recent test results — emissions data, dynamics data, and heat losses for hydrogen addition from 0 to 40% by fuel volume at two combustor pressures — and a description of future testing are also presented. The results show that the addition of hydrogen to natural gas in percentages as low as 5% of total fuel volume can significantly decrease the lean extinction limit, and promote stable operation at lower equivalence ratios while promoting lower NOx emissions. Dynamic pressures were measured, but combustion dynamics were not present due to the combustor configuration. The effect of heat losses on flame temperature and emissions were quantified.

Author(s):  
Kam-Kei Lam ◽  
Philipp Geipel ◽  
Jenny Larfeldt

In order to further extend the turbine fuel flex capability, a test under atmospheric conditions of a full-scale SGT-400 burner was performed to study the combustion behavior when operating on hydrogen enriched natural gas. A high speed camera was installed in the rig to investigate the flame dynamics on different operation conditions. NOx emissions were measured for all presented conditions. The combustion system was instrumented with thermocouples on all the key locations to allow flame position monitoring and to avoid flame attachment on the hardware. Further measurements included static pressure probes to monitor combustor pressure drop. The test was conducted in a systematic matrix format to include the most important combustion parameters in order to identify their individual effects on the combustion behaviors. The quantity of hydrogen in natural gas, fuel split, air preheat temperature, air reference velocity and flame temperature were the combustion related variables studied in the presented test campaign. The volumetric hydrogen quantity could be increased to 30% maintaining stable operation for all measured conditions. Higher hydrogen contents up to 80 vol-% were reached without flash back tendency. A glowing spark igniter prevented testing at even higher hydrogen contents. Hydrogen enriched gas showed higher NOx emissions and improved blowout limit. Hydrogen blending in the fuel also reduced the combustor pressure drop, lowered the prechamber temperature and raised the pilot tip temperature.


Author(s):  
Bassam S. Mohammad ◽  
Preetham Balasubramanyam ◽  
Keith McManus ◽  
Jeffrey Ruszczyk ◽  
Ahmed M. Elkady ◽  
...  

Combustion dynamics have detrimental effects on hardware durability as well as combustor performance and emissions. This paper presents a detailed study on the impact of combustion dynamics on NOx and CO emissions generated from a prototype gas turbine combustor operating at a pressure of 180 psia (12.2 bars) with a pre-heat temperature of 720 F (655.3 K) (E-class machine operating conditions). Two unstable modes are discussed. The first is an intermittent mode, at 750 Hz, that emerges at flame temperatures near 2900°F (1866.5 K), resulting in high NOx and CO emissions. With increasing fuel flow, NOx and CO emissions continue to increase until the flame temperature reaches approximately 3250°F (2061 K), at which point the second acoustic mode begins to dominate. Flame images indicate that the intermittent mode is associated with flame motion which induces the high NOx and CO emissions. The second mode is also a 750 Hz, but of constant amplitude (no intermittency). Operation in this second 750 Hz mode results in significantly reduced NOx and CO emissions. At pressures higher than 180 psia (12.2 bars), the intermittent mode intensifies, leading to flashback at flame temperatures above 2850°F (1839 K). In order to mitigate the intermittent mode, a second configuration of the combustor included an exit area restriction. The exit area restriction eliminated the intermittent mode, resulting in stable operation and low emissions over a temperature range of 2700–3200°F (1755–2033 K). A comparison of the NOx emissions, as function of flame temperature, with previous published data for perfectly premixed indicates that, while the low amplitude 750 Hz oscillations have little effect, the intermittent mode significantly increases emissions. Mode shape analysis shows that the 750 Hz instability corresponds to the 1/4 wave axial mode. In the current research a ceramic liner is used while the previous published data was collected with a quartz liner. Typically, quartz is avoided due to reductions in effective flame temperature by radiation losses. Experiments showed that NOx emissions were not affected by the combustor liner type. This agreement between the quartz and ceramic liners data indicates limited effect from the radiation heat losses on NOx emissions.


Author(s):  
Kam-Kei Lam ◽  
Philipp Geipel ◽  
Jenny Larfeldt

In order to further extend the turbine fuel flex capability, a test under atmospheric conditions of a full-scale SGT-400 burner was performed to study the combustion behavior when operating on hydrogen enriched natural gas (NG). A high speed camera was installed in the rig to investigate the flame dynamics on different operation conditions. NOx emissions were measured for all presented conditions. The combustion system was instrumented with thermocouples on all the key locations to allow flame position monitoring and to avoid flame attachment on the hardware. Further measurements included static pressure probes to monitor combustor pressure drop. The test was conducted in a systematic matrix format to include the most important combustion parameters in order to identify their individual effects on the combustion behaviors. The quantity of hydrogen in natural gas, fuel split, air preheat temperature, air reference velocity and flame temperature were the combustion related variables studied in the presented test campaign. The volumetric hydrogen quantity could be increased to 30% maintaining stable operation for all measured conditions. Higher hydrogen contents up to 80 vol. % were reached without flash back tendency. A glowing spark igniter prevented testing at even higher hydrogen contents. Hydrogen enriched gas showed higher NOx emissions and improved blowout limit. Hydrogen blending in the fuel also reduced the combustor pressure drop, lowered the prechamber temperature and raised the pilot tip temperature.


Author(s):  
Brian Hollon ◽  
Erlendur Steinthorsson ◽  
Adel Mansour ◽  
Vincent McDonell ◽  
Howard Lee

This paper discusses the development and testing of a full-scale micro-mixing lean-premix injector for hydrogen and syngas fuels that demonstrated ultra-low emissions and stable operation without flashback for high-hydrogen fuels at representative full-scale operating conditions. The injector was fabricated using Macrolamination technology, which is a process by which injectors are manufactured from bonded layers. The injector utilizes sixteen micro-mixing cups for effective and rapid mixing of fuel and air in a compact package. The full scale injector is rated at 1.3 MWth when operating on natural gas at 12.4 bar (180 psi) combustor pressure. The injector operated without flash back on fuel mixtures ranging from 100% natural gas to 100% hydrogen and emissions were shown to be insensitive to operating pressure. Ultra-low NOx emissions of 3 ppm were achieved at a flame temperature of 1750 K (2690 °F) using a fuel mixture containing 50% hydrogen and 50% natural gas by volume with 40% nitrogen dilution added to the fuel stream. NOx emissions of 1.5 ppm were demonstrated at a flame temperature over 1680 K (2564 °F) using the same fuel mixture with only 10% nitrogen dilution, and NOx emissions of 3.5 ppm were demonstrated at a flame temperature of 1730 K (2650 °F) with only 10% carbon dioxide dilution. Finally, using 100% hydrogen with 30% carbon dioxide dilution, 3.6 ppm NOx emissions were demonstrated at a flame temperature over 1600 K (2420 °F). Superior operability was achieved with the injector operating at temperatures below 1470 K (2186 °F) on a fuel mixture containing 87% hydrogen and 13% natural gas. The tests validated the micro-mixing fuel injector technology and the injectors show great promise for use in future gas turbine engines operating on hydrogen, syngas or other fuel mixtures of various compositions.


Author(s):  
Jochen R. Kalb ◽  
Thomas Sattelmayer

The technological objective of this work is the development of a lean-premixed burner for natural gas. Sub-ppm NOx emissions can be accomplished by shifting the lean blowout limit (LBO) to slightly lower adiabatic flame temperatures than the LBO of current standard burners. This can be achieved with a novel burner concept utilizing periodic flue gas recirculation: Hot flue gas is admixed to the injected premixed fresh mixture with a mass flow rate of comparable magnitude, in order to achieve self-ignition. The subsequent combustion of the diluted mixture again delivers flue gas. A fraction of the combustion products is then admixed to the next stream of fresh mixture. This process pattern is to be continued in a cyclically closed topology, in order to achieve stable combustion of e.g. natural gas in a temperature regime of very low NOx production. The principal ignition behavior and NOx production characteristics of one sequence of the periodic process was modeled by an idealized adiabatic system with instantaneous admixture of partially or completely burnt flue gas to one stream of fresh reactants. With the CHEMKIN-II package a reactor network consisting of one perfectly stirred reactor (PSR, providing ignition in the first place) and two plug flow reactors (PFR) has been used. The effect of varying burnout and the influence of the fraction of admixed flue gas have been evaluated. The simulations have been conducted with the reaction mechanism of Miller and Bowman and the GRI-Mech 3.0 mechanism. The results show that the high radical content of partially combusted products leads to a massive decrease of the time required for the formation of the radical pool. As a consequence, self-ignition times of 1 ms are achieved even at adiabatic flame temperatures of 1600 K and less, if the flue gas content is about 50%–60% of the reacting flow after mixing is complete. Interestingly, the effect of radicals on ignition is strong, outweighs the temperature deficiency and thus allows stable operation at very low NOx emissions.


Author(s):  
Don Ferguson ◽  
Geo. A. Richard ◽  
Doug Straub

In response to environmental concerns of NOx emissions, gas turbine manufacturers have developed engines that operate under lean, pre-mixed fuel and air conditions. While this has proven to reduce NOx emissions by lowering peak flame temperatures, it is not without its limitations as engines utilizing this technology are more susceptible to combustion dynamics. Although dependent on a number of mechanisms, changes in fuel composition can alter the dynamic response of a given combustion system. This is of particular interest as increases in demand of domestic natural gas have fueled efforts to utilize alternatives such as coal derived syngas, imported liquefied natural gas and hydrogen or hydrogen augmented fuels. However, prior to changing the fuel supply end-users need to understand how their system will respond. A variety of historical parameters have been utilized to determine fuel interchangeability such as Wobbe and Weaver Indices, however these parameters were never optimized for today’s engines operating under lean pre-mixed combustion. This paper provides a discussion of currently available parameters to describe fuel interchangeability. Through the analysis of the dynamic response of a lab-scale Rijke tube combustor operating on various fuel blends, it is shown that commonly used indices are inadequate for describing combustion specific phenomena.


2004 ◽  
Vol 128 (2) ◽  
pp. 247-254 ◽  
Author(s):  
Jochen R. Kalb ◽  
Thomas Sattelmayer

The technological objective of this work is the development of a lean-premixed burner for natural gas. Sub-ppm NOx emissions can be accomplished by shifting the lean blowout limit (LBO) to slightly lower adiabatic flame temperatures than the LBO of current standard burners. This can be achieved with a novel burner concept utilizing spatially periodic recirculation of combustion products: Hot combustion products are admixed to the injected premixed fresh mixture with a mass flow rate of comparable magnitude, in order to achieve self-ignition. The subsequent combustion of the diluted mixture again delivers products. A fraction of these combustion products is then admixed to the next stream of fresh mixture. This process pattern is to be continued in a cyclically closed topology, in order to achieve stable combustion of, for example, natural gas in a temperature regime of very low NOx production. The principal ignition behavior and NOx production characteristics of one sequence of the periodic process was modeled by an idealized adiabatic system with instantaneous admixture of partially or completely burnt combustion products to one stream of fresh reactants. With the CHEMKIN-II package, a reactor network consisting of one perfectly stirred reactor (PSR, providing ignition in the first place) and two plug flow reactors (PFR) has been used. The effect of varying burnout and the influence of the fraction of admixed flue gas has been evaluated. The simulations have been conducted with the reaction mechanism of Miller and Bowman and the GRI-Mech 3.0 mechanism. The results show that the high radical content of partially combusted products leads to a massive decrease of the time required for the formation of the radical pool. As a consequence, self-ignition times of 1 ms are achieved even at adiabatic flame temperatures of 1600 K and less, if the flue gas content is about 50–60% of the reacting flow after mixing is complete. Interestingly, the effect of radicals on ignition is strong, outweighs the temperature deficiency and thus allows stable operation at very low NOx emissions.


Author(s):  
Hui Wu ◽  
Wenxing Zhang ◽  
Kejin Mu ◽  
Yue Wang ◽  
Yunhan Xiao

As the development and increasingly widespread use of IGCC and zero emission energy system, the development of advanced combustion capabilities for gaseous hydrogen and hydrogen rich fuels in gas turbine applications is becoming an area of much great concern. The combustion characteristics of hydrogen rich fuel is very different from nature gas in aspects such as flame stability, flame temperature, combustor acoustics, pollutant emissions, combustor efficiency, and some other important quantities. However, few of these issues are clearly understood by far. The purpose of this paper is to compare in detail the combustion performance of hydrogen-methane hybrid fuels with various volumetric H2 fractions ranging from 0% to 100%. Meanwhile, the comparison of pure H2, pure CH4, and 80%H2+20%CH4 was the emphasis. 80%H2+20%CH4 hybrid gas is selected expressly because its component is approximately equal to the outcome of a hydrogen production test bed of our laboratory, and it is considered by the team to be a potential transition fuel of gas turbines between nature gas and pure hydrogen. Detailed experimental measurements and numerical simulations were conducted using a coflow jet diffusion burner. It was found that in the extent of experiments, when under equal general power, the flame length of hydrogen contained fuels wasn’t much shorter than methane, and didn’t get shorter with the increase of H2 fraction as expected. That was because the shortening tendency caused by the increase of H2 fraction was counteracted partially by the increase of fuel velocity, results of which was the extending of flame length. Maximum temperature of H2 flame was 1733K, which was 30K higher than 80%H2+20%CH4 and 120K higher than CH4. All of the highest temperatures of the three fuels were presented at the recirculation zone of the flame. Although it seemed that the flame of CH4 had the longest dimension compared with H2 contained fuels when observed through photos, the high temperature region of flames was getting longer when increasing H2 fractions. Curves of temperature distribution predicted by all the four combustion models in FLUENT investigated here had a departure away from the experimental data. Among the models, Flamelet model was the one whose prediction was comparatively close to the experimental results. Flame of H2 and 80%H2+20%CH4 had a much better stability than flame of CH4, they could reach a so called recirculating flame phase and never been blew out in the extent of experiments. On the contrary, CH4 flames were blew out easily soon after they were lifted up. Distribution of OH concentration at the root of flames showed that the flame boundary of H2 and 80%H2+20%CH4 was more clearly than CH4. That is to say, at the root of the flame, combustion of H2 was the most intensive one, 80%H2+20%CH4 took the second place, while CH4 was the least. NOx emissions didn’t show a linear relationship with the volumetric fraction of H2, but showed an exponential uptrend instead. It presented a fairly consistent tendency with flame temperature, which proved again there was a strong relationship between flame temperature and NOx emissions in the combustion of hydrogen contained fuels. If adding CH4 into pure H2, NOx concentration would have a 17.2ppm reduction with the first 20% accession, but only 11.1ppm with the later 80% accession. Hence, if NOx emission was the only aspect to be considered, 80%H2+20%CH4 seemed to be a better choice of transition fuel from pure CH4 to pure H2.


Author(s):  
Bernd Prade ◽  
Ju¨rgen Meisl ◽  
Peter Berenbrink ◽  
Holger Streb ◽  
Stefan Hoffmann

The newest Siemens gas turbine family has already been well received by the market. Nevertheless, the market drives continuing development of the family and the combustion system. Central focus is put on further increasing reliability and component lifetime and on increased inspection cycles, as well as increasing the engine power output and efficiency, which is directly linked to higher turbine inlet temperatures. Increasing attention, however, is given to the flexibility concerning fuel quality and according fluctuations. Additionally, more and more strict emission requirements must be considered. This paper especially reports on demonstration of the capability of the Siemens gas turbines with an annular combustion system to fulfil the requirements for the highest operational flexibility. Thus, the combustion system has been tested and qualified for the highest operating flexibility with special fuel requirements such as burning Naphtha, Light Oil #2 and Natural gas with an extremely wide range of heating values as well. Also special operation modes such as fuel changeover, fastest load changes for island grid operation, frequency response and load rejection require this highly flexible combustion system without any hardware exchange. In different frames when fired with natural gas, base load is reached with the NOx emissions ranging well below 25 ppmvd, confirming the high potential of this advanced hybrid burner. In liquid fuel operation, dry NOx emissions of 75ppmvd were demonstrated but by injecting fuel / water emulsion NOx emissions were reduced to below 42 ppmvd with different liquid fuel qualities. Combustion dynamics, unburned Hydrocarbons, CO and soot emissions remained always below the required limits.


Author(s):  
Torsten Wind ◽  
Felix Güthe ◽  
Khawar Syed

Addition of hydrogen (H2), produced from excess renewable electricity, to natural gas has become a new fuel type of interest for gas turbines. The addition of hydrogen extends the existing requirements to widen the fuel flexibility of gas turbine combustion systems to accommodate natural gases of varying content of higher hydrocarbons (C2+). The present paper examines the performance of the EV and SEV burners used in the sequential combustion system of Alstom’s reheat engines, which are fired with natural gas containing varying amounts of hydrogen and higher hydrocarbons. The performance is evaluated by means of single burner high pressure testing at full scale and at engine-relevant conditions. The fuel blends studied introduce variations in Wobbe index and reactivity. The latter influences, for example, laminar and turbulent burning velocities, which are significant parameters for conventional lean premixed burners such as the EV, and auto-ignition delay times, which is a significant parameter for reheat burners, such as the SEV. An increase in fuel reactivity can lead to increased NOx emissions, flashback sensitivity and flame dynamics. The impact of the fuel blends and operating parameters, such as flame temperature, on the combustion performance is studied. Results indicate that variation of flame temperature of the first burner is an effective parameter to maintain low NOx emissions as well as offsetting the impact of fuel reactivity on the auto-ignition delay time of the downstream reheat burner. The relative impact of hydrogen and higher hydrocarbons is in agreement with results from simple reactor and 1D flame analyses. The changes in combustion behaviour can be compensated by a slightly extended operation concept of the engine following the guidelines of the existing C2+ operation concept and will lead to a widened, safe operational range of Alstom reheat engines with respect to fuel flexibility without hardware modifications.


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