Inter-Laboratory Dynamic Modeling of a Carbonate Fuel Cell for Hybrid Application

2003 ◽  
Author(s):  
Rory A. Roberts ◽  
Faryar Jabbari ◽  
Jacob Brouwer ◽  
Randall S. Gemmen ◽  
Eric A. Liese
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Dynamic Response ◽  
Gas Turbine ◽  
Hybrid System ◽  
Dynamic Models ◽  
Detailed Comparison ◽  
Simulation Software ◽  
Molten Carbonate ◽  
Carbonate Fuel Cell

A detailed comparison of dynamic models developed for carbonate fuel cells used in hybrid fuel cell gas turbine systems is presented. The two models are nearly similar in that both treat the bulk behavior of the system (e.g., through lumped or one-dimensional solutions of the fundamental equations. However, both models are implemented independently by different research groups using disparate simulation software programs. As a test case for the comparison, a generic molten carbonate hybrid fuel cell gas turbine system is identified. Such comparison-work benefits all parties by ensuring sub-model reliability prior to integration into a complete hybrid system model. Detailed results for the carbonate fuel cell models are presented. For a generic planar design, voltage and current behavior are shown following step changes in load resistance and fuel flow. The time scales for thermal dynamic response are much greater than those required for the initial electrochemical dynamic response as is expected. These results provide understanding of some of the operational characteristics of fuel cells and indicate the complexity of the dynamic response of fuel cell hybrid components. The results from the two models are not identical, but compare sufficiently well to provide confidence in each of the model’s reliability, enabling them to be integrated for hybrid system simulation. Results from the integrated simulations will provide guidance on future hybrid technology development needs.

Performance Evaluation of a Molten Carbonate Fuel Cell/Micro Gas Turbine Hybrid System With Oxy-Combustion Carbon Capture

2017 ◽  
Author(s):  
Ji Ho Ahn ◽  
Tong Seop Kim
Keyword(s):  
Carbon Dioxide ◽  
Fuel Cell ◽  
Gas Turbine ◽  
Hybrid System ◽  
Carbon Capture ◽  
Molten Carbonate Fuel Cell ◽  
Design Parameters ◽  
Molten Carbonate ◽  
Micro Gas Turbine ◽  
Carbonate Fuel Cell

Owing to the increasing consumption of fossil fuels and emission of greenhouse gases, interests in highly efficient and low carbon emitting power systems are growing fast. Several research groups have been suggesting advanced systems based on fuel cells and have also been applying carbon capture and storage technology to satisfy the demand for clean energy. In this study, the performance of a hybrid system, which is a combination of a molten carbonate fuel cell (MCFC) with oxy-combustion carbon capture and an indirectly fired micro gas turbine (MGT) was predicted. A 2.5MW MCFC system that is used in commercial applications was used as the reference system so that the results of the study could be applicable to practical situations. The ambient pressure type hybrid system was modeled by referring to the design parameters of an MGT that is currently being developed. A semi-closed type design characterized by flow recirculation was adopted for this hybrid system. A part of the recirculating gas is converted into liquefied carbon dioxide and captured for storage at the carbon separation unit. Almost 100% carbon dioxide capture is possible with this system. In these systems, the output power of the fuel cell is larger than in the normal hybrid system without carbon capture because the partial pressure of carbon dioxide increases. The increased cell power partially compensates for the power loss due to the carbon capture and MGT power reduction. The dependence of net system efficiency of the oxy-hybrid on compressor pressure ratio is marginal, especially beyond an optimal value.

Performance Evaluation of a Molten Carbonate Fuel Cell/Micro Gas Turbine Hybrid System With Oxy-Combustion Carbon Capture

2017 ◽  
Vol 140 (4) ◽  
Author(s):  
Ji Ho Ahn ◽  
Tong Seop Kim
Keyword(s):  
Carbon Dioxide ◽  
Fuel Cell ◽  
Gas Turbine ◽  
Hybrid System ◽  
Carbon Capture ◽  
Molten Carbonate Fuel Cell ◽  
Design Parameters ◽  
Molten Carbonate ◽  
Micro Gas Turbine ◽  
Carbonate Fuel Cell

Owing to the increasing consumption of fossil fuels and emission of greenhouse gases, interests in highly efficient and low carbon emitting power systems are growing fast. Several research groups have been suggesting advanced systems based on fuel cells and have also been applying carbon capture and storage technology to satisfy the demand for clean energy. In this study, the performance of a hybrid system, which is a combination of a molten carbonate fuel cell (MCFC) with oxy-combustion carbon capture and an indirectly fired micro gas turbine (MGT), was predicted. A 2.5 MW MCFC system that is used in commercial applications was used as the reference system so that the results of the study could be applied to practical situations. The ambient pressure type hybrid system was modeled by referring to the design parameters of an MGT that is currently being developed. A semi-closed type design characterized by flow recirculation was adopted for this hybrid system. A part of the recirculating gas is converted into liquefied carbon dioxide and captured for storage at the carbon separation unit (CSU). Almost 100% carbon dioxide capture is possible with this system. In these systems, the output power of the fuel cell is larger than in the normal hybrid system without carbon capture because the partial pressure of carbon dioxide increases. The increased cell power partially compensates for the power loss due to the carbon capture and MGT power reduction. The dependence of net system efficiency of the oxy-hybrid on compressor pressure ratio is marginal, especially beyond an optimal value.

Performance Enhancement of a Molten Carbonate Fuel Cell/Micro Gas Turbine Hybrid System With Carbon Capture by Off-Gas Recirculation

2018 ◽  
Author(s):  
Ji Ho Ahn ◽  
Ji Hun Jeong ◽  
Tong Seop Kim
Keyword(s):  
Fuel Cell ◽  
Gas Turbine ◽  
Hybrid System ◽  
Carbon Capture ◽  
Molten Carbonate Fuel Cell ◽  
Human Society ◽  
Molten Carbonate ◽  
Micro Gas Turbine ◽  
Gas Recirculation ◽  
Carbonate Fuel Cell

The demand for clean energy continues to increase as the human society becomes more aware of environmental challenges such as global warming. Various power systems based on high-temperature fuel cells have been proposed, especially hybrid systems combining a fuel cell with a gas turbine, and research on carbon capture and storage technology to prevent the emission of greenhouse gases is already underway. This study suggests a new method to innovatively enhance the efficiency of a molten carbonate fuel cell/micro gas turbine hybrid system including carbon capture. The key technology adopted to improve the net cycle efficiency is off-gas recirculation. The hybrid system incorporating oxy-combustion capture was devised, and its performance was compared with that of a post-combustion system based on a hybrid system. A molten carbonate fuel cell system based on a commercial unit was modeled. Externally supplied water for reforming was not needed as a result of the presence of the water vapor in the recirculated anode off-gas. The analyses confirmed that the thermal efficiencies of all the systems (MCFC stand-alone, hybrid, hybrid with oxy-combustion capture, hybrid with post-combustion capture) were significantly improved by introducing the off-gas recirculation. In particular, the largest efficiency improvement was observed for the oxy-combustion hybrid system. Its efficiency is over 57% and is even higher than that of the post-combustion hybrid system.

Heat Exchangers for Fuel Cell and Hybrid System Applications

2005 ◽  
Author(s):  
L. Magistri ◽  
A. Traverso ◽  
A. F. Massardo ◽  
R. K. Shah
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Gas Turbine ◽  
Hybrid System ◽  
Heat Exchangers ◽  
Renewable Energy Sources ◽  
Critical Role ◽  
Proton Exchange ◽  
Molten Carbonate ◽  
The Impact

The fuel cell system and fuel cell gas turbine hybrid system represent an emerging technology for power generation because of its higher energy conversion efficiency, extremely low environmental pollution and potential use of some renewable energy sources as fuels. Depending upon the type and size of applications, from domestic heating to industrial cogeneration, there are different types of fuel cell technologies to be employed. The fuel cells considered in this paper are the proton exchange membrane (PEMFC), the molten carbonate (MCFC) and the solid oxide (SOFC) fuel cells. In all these systems, heat exchangers play an important and critical role in the thermal management of the fuel cell itself and the boundary components, such as the fuel reformer (when methane or natural gas is used), the air preheating and the fuel cell cooling. In this paper, the impact of heat exchangers on the performance of PEMFC systems and SOFC-MCFC gas turbine hybrid systems is investigated. Several options in terms of cycle layout and heat exchanger technology are discussed from the on-design, off-design and control perspectives. A general overview of the main issues related to heat exchangers performance, cost and durability is presented and the most promising configurations identified.

Development of Dynamic Modeling Tools for Solid Oxide and Molten Carbonate Hybrid Fuel Cell Gas Turbine Systems

2000 ◽  
Author(s):  
Randall S. Gemmen ◽  
Eric Liese ◽  
Jose G. Rivera ◽  
Faryar Jabbari ◽  
Jacob Brouwer
Keyword(s):  
Fuel Cell ◽  
Gas Turbine ◽  
Dynamic Modeling ◽  
Hybrid System ◽  
Dynamic Models ◽  
Load Resistance ◽  
Solid Oxide ◽  
Molten Carbonate Fuel Cell ◽  
Molten Carbonate ◽  
Modeling Tools

This paper describes some generic solid oxide and molten carbonate hybrid fuel cell gas turbine systems and dynamic modeling tools that are being developed to simulate the performance of these and other hybrid fuel cell systems. The generic hybrid systems are presented to introduce issues and technical development challenges that hybrid fuel cell gas turbine systems must address and to provide a platform for the development of the dynamic modeling tools. The present goals are to develop dynamic models for the basic components of solid oxide and molten carbonate fuel cell gas turbine hybrids, ensure their reliability, and obtain a basic understanding of their performance prior to integration into a complete hybrid system model. Preliminary results for molten carbonate and solid oxide fuel cell types are presented. These results provide understanding of some of the operational characteristics of fuel cells, and indicate the complexity of the dynamic response of fuel cell hybrid components. For the fuel cell models, generic planar designs are analyzed showing voltage and current behavior following step changes in load resistance and steady state performance curves. The results provide confidence in each of the model’s reliability, enabling them to be integrated for hybrid system simulation. Results from the integrated simulations will provide guidance on future hybrid technology development needs.

Part-Load Performance Analysis of Pressurized Molten Carbonate Fuel Cell/Micro-Gas Turbine Hybrid System Using a Commercially Available Micro-Gas Turbine

2009 ◽  
Author(s):  
Ai-guo Liu ◽  
Yi-wu Weng
Keyword(s):  
Fuel Cell ◽  
Gas Turbine ◽  
Hybrid System ◽  
Control Strategies ◽  
Molten Carbonate Fuel Cell ◽  
Inlet Temperature ◽  
Molten Carbonate ◽  
Part Load ◽  
Micro Gas Turbine ◽  
Carbonate Fuel Cell

This paper presented the work on the design and part-load operation of a power generation system composed of a pressurized molten carbonate fuel cell and a micro-gas turbine (MCFC/MGT). The gas turbine was based on the commercially available one and the MCFC was assumed to be newly designed for the hybrid system. The effect of different control strategies on the performance of system during part-load operation has been analyzed. Performance of system and gas turbine was compared at the same part-load considering the different control strategies. The results show that the system efficiency is lower compared with the same systems analyzed by the other authors. The system has good performance when both the turbine inlet temperature and cell temperature are maintained close to the design-point condition, but it is difficult for gas turbine to obtain the original power.

Part Load Strategies of a Multi-MW Molten Carbonate Fuel Cell Gas Turbine Hybrid System

2007 ◽  
Author(s):  
Georgia C. Karvountzi ◽  
Paul F. Duby
Keyword(s):  
Fuel Cell ◽  
Gas Turbine ◽  
Hybrid System ◽  
Cell Voltage ◽  
Combined Cycle ◽  
Molten Carbonate Fuel Cell ◽  
Molten Carbonate ◽  
Part Load ◽  
Full Load ◽  
Carbonate Fuel Cell

The goal of this study is to define the operating envelope of a 20MW molten carbonate fuel cell (MCFC)-gas turbine hybrid system, under part load conditions. The first part of the paper reviews our baseline fuel cell hybrid system model that predicts overall system LHV efficiency around 69% at full load. The second part of the paper consider several strategies: 1/ run fuel cell at full load and bypass gas turbine; 2 /run fuel cell at full load and gas turbine at part load; 3/ run fuel cell at OCV and gas turbine at full load; 4/ run fuel cell at part load and gas turbine at full load; and 5/run both fuel cell and gas turbine at part load. The best system part-load performance was achieved when the fuel cell operates at part load while the gas turbine is at full load. The highest operational flexibility is achieved when we part load both the fuel cell and the gas turbine. Depending on system targets and deliverables such as fuel cell voltage and fuel utilization or gas turbine firing temperature some of these modes may not be economical. A comparison with the performance of a conventional combined cycle 20MW power plant under part load was performed. The MCFC hybrid system showed better efficiency and better cost of electricity (COE) under part load operation than the gas turbine combined cycle part loaded.

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