The Rise and Combustion of Particles of Sewage Sludge and Petroleum Coke in a Slugging Fluidized Bed

Author(s):  
A. C. Rees ◽  
J. F. Davidson ◽  
J. S. Dennis ◽  
A. N. Hayhurst

The rise-times, from just above the base to the top of the bed, of single particles of dried sewage sludge and of two types of petroleum coke were measured in a slugging bed of sand fluidized by air. The sewage sludge and the petroleum cokes contained, on an as received basis, 49.5, 9.0 and 0.5 wt.% volatile matter, respectively. The bed (i.d. 25.5 mm; height 1300 mm) was electrically heated to a fixed temperature between 700 and 900°C. Two sizes of sand were fluidized: +212, −300 μm and +710, −850 μm. The expansion of the bed was held constant by keeping the excess gas velocity at (U − Umf) = 190 mm/s. In a bed of the coarser sand, it was found that the time of rise of single particles of sewage sludge (< 4 mm diam.) was large enough to allow devolatilization and char burn-out to be complete before the particle reached the upper surface of the bed. The measured times of rise are significantly longer than those found in bubbling beds [12, 13]. Thus, a slugging bed, of say 2 m in depth, would have significantly better heat retention and contact of the volatile material with the particulate phase than a bubbling bed of the same depth. With the finer sand, particles of sewage sludge and of petroleum coke containing volatile material rose rapidly to the top of the bed, well before combustion was complete. Published theory [6] was used to predict the rise-times of inert particles in a hot slugging bed. The predictions compare favourably with measurements using petroleum coke containing negligible amounts of volatile material and moisture. The use of a modified form of Stokes’s law to predict the velocity of rise of inert particles is shown to compare well with experiments. The experimental results suggest that once a minimum rate of gas evolution (from volatiles or moisture) is achieved a bubble forms which is large enough to lift a fuel particle to the surface. For particles meeting this criterion, the rise-time appears to be independent of the size of the fuel particle.

Energies ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2890 ◽  
Author(s):  
Fabio Merzari ◽  
Jillian Goldfarb ◽  
Gianni Andreottola ◽  
Tanja Mimmo ◽  
Maurizio Volpe ◽  
...  

Conventional activated sludge systems, still widely used to treat wastewater, produce large amounts of solid waste that is commonly landfilled or incinerated. This study addresses the potential use of Hydrothermal Carbonization (HTC) to valorize sewage sludge residues examining the properties of hydrochars depending on HTC process conditions and sewage sludge withdrawal point. With increasing HTC severity (process residence time and temperature), solid yield, total Chemical Oxygen Demand (COD) and solid pH decrease while ash content increases. Hydrochars produced from primary (thickened) and secondary (digested and dewatered) sludge show peculiar distinct properties. Hydrochars produced from thickened sludge show good fuel properties in terms of Higher Heating Value (HHV) and reduced ash content. However, relatively high volatile matter and O:C and H:C ratios result in thermal reactivity significantly higher than typical coals. Both series of carbonized secondary sludges show neutral pH, low COD, enhanced phosphorous content and low heavy metals concentration: as a whole, they show properties compatible with their use as soil amendments.


2012 ◽  
Vol 8 (3) ◽  
pp. 453-460 ◽  
Author(s):  
Xiuyuan Ma ◽  
Yufeng Duan ◽  
Meng Liu ◽  
Huafeng Li

2010 ◽  
Vol 658 ◽  
pp. 296-299
Author(s):  
Yeong Seok Yoo ◽  
Ho Jun Chae ◽  
Hyo Jin Ban ◽  
Eun Zoo Park

Natural soil would be used for planting on paved area ground, but it had been replaced by the light weighted artificial soil to minimize burden of the structure. But, the existing light weighted soil had nearly capacity of fertilizer adsorption due to its glassy surface. In this study, the artificial soil prepared by sewage sludge was manufactured, tested characteristics as soil and examined on planting. The developed soil was analyzed through specific gravity, pH, water content, volatile matter and was tested on adsorption capacity of Cu. In addition, planting examination analyzed the leaf growth of planting and mouseear cress plant's pollen. As the result, the developed artificial soil showed to be color yellowish brown, bulk density 0.6g/cm3, pH 8~9, volatile matter 0.3, CEC 10, pressure strength 25 ton/m2, hydrophilic and non-toxic, which was suitable for rooftop gardening. Also, periodic growth rate and development of leaves was satisfactory as natural soil and growth and numbers of pollens were good. Consequently, the developed artificial soil with porosity and capacity of fertilizer adsorption could be usefully applicable to planting on the paved area.


Energies ◽  
2019 ◽  
Vol 12 (16) ◽  
pp. 3072 ◽  
Author(s):  
Ju-Hyoung Park ◽  
Min-Ho Jin ◽  
Young-Joo Lee ◽  
Gyu-Seob Song ◽  
Jong Won Choi ◽  
...  

Developing effective, economical, and environmentally sound approaches for sewage sludge management remains an important global issue. In this paper, we propose a bioethanol-lignin (nonfood biomass)-based sewage sludge upgrading process for enhancing the heating value and reducing air pollutants of hybrid sewage sludge fuel (HSF) for the effective management of sewage sludge. Sewage sludge paste with the lignin-CaO solution implies drying at 105 °C accompanied by torrefaction at 250 °C. During torrefaction, moisture and partly volatile matter begin to evaporate, and are almost vaporized out to the surface. In this study, the proposed process enhances the net caloric value (NCV) to 37%. The lignin-embedded HSF shows a two-in-one combustion peak regardless of the mixing ratio, resulting in a 70% reduction of unburned carbon (UBC) emissions, which is one of the particular matter (PM) sources of combustion flue gas. Other air pollutants, such as CO, hydrocarbon, NOx, and SOx, were also reduced by the proposed process. In particular, SOx emission remained at ~1 ppm (average value) regardless of the sulfur content of the fuel.


2001 ◽  
Vol 44 (10) ◽  
pp. 341-347 ◽  
Author(s):  
P. Ho ◽  
L. Shao ◽  
G. Gu ◽  
G. Li

The low-temperature thermo-chemical conversion process for sewage sludge is a prospective technology, through which the energy in the sludge can be recovered. With the help of elementary analysis of sewage sludge and its conversion products, thermal gravimetric analysis (TGA) of the sludge and GC/MS analysis of the derived oil, a study was carried out on element transfer, characteristic conversion temperature and conversion reaction mechanism of the process. The following results are obtained: 1) the predominant conversion reactions are distillation of aliphatic compounds, splitting of protein peptide bonds and group transfer; and 2) the main components involved in the conversion are aliphatic compounds and protein, with the lower reaction temperature for the former, the higher for the latter and the highest for saccharides. Based on the mechanism analyses, the simplified reaction model of the thermo-chemical conversion process for sewage sludge consists of two serial competitive reactions (producing volatile matter and char respectively). The estimated Arrhennius kinetic parameters of the reaction model based on TGA testing results are A1 = 4.15×106 1/s, n1 = 2, E1 = 98 kJ/mol; A2 = 1.42×105 1/s, n2 = 2, E2 = 85 kJ/mol; A3 = 1.01×1012 1/s, n3 = 4, E3 =190 kJ/mol; A4 = 1.33×109 1/s, n4 = 4,E4 = 146 kJ/mol.


2012 ◽  
Vol 550-553 ◽  
pp. 2315-2318
Author(s):  
Li Hong Wei ◽  
Na Zhang ◽  
Tian Hua Yang ◽  
Lei Wang

The effects of sewage sludge on combustion of loading alkali metal pulverized coal is carried out by thermogravimetric analysis (TGA). The result shows sewage sludge decreases initial release temperature and ignition temperature of volatile matter(VM) during the combustion of loading alkali metal pulverized coal. The combustion of fixed carbon in coal was promoted by the metal material in sludge when the sludge mixing ratio(SMA) was lower than 20% or inhibited because of the cover of sludge ash when SMA was higher than 40%. Comparison of stacking curves of sludge and measured curves of loading alkali metal coal, finds that: (1) there is no effect between sludge and coal, for the volatilization of water and small molecule substance, the combustion characteristic curves are superimposed in both experimental curves; (2) the co-combustion is interactional and interrestricted continuous change process, can't direct obtain from superimposition of curves, for the combustion of VM and fixed carbon. While SMA is lower than 20%, the samples have good combustion characteristic than pure coal.


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