Energy Generators Driven by Nonlinear Transport Phenomena

Volume 1 ◽  
2004 ◽  
Author(s):  
Stanislaw Sieniutycz
Keyword(s):  
Chemical Reactions ◽  
Thermal Energy ◽  
Heat Pumps ◽  
Heat Fluxes ◽  
Nonlinear Transport ◽  
Contemporary Theory ◽  
Recent Approach ◽  
Rate Processes ◽  
Unidirectional Fluxes ◽  
Kinetics Of

We describe quantitatively effects of nonlinear transfer phenomena that drive energy generators (thermal engines) and heat pumps. It is shown that these transports can be treated either in a standard way or as peculiar rate processes (chemical reactions governed by appropriate affinities). An approach to nonlinear transports links heat fluxes with differences of temperature in certain power Ta. A more recent approach distinguishes in each elementary transfer step two competitive (unidirectional) fluxes and the resulting flux as their difference. We show how the kinetics of this sort can be implemented into the contemporary theory of thermal energy generators.

New highly efficient coulometric cell with homogenous potential distribution on the working electrode

1986 ◽  
Vol 51 (3) ◽  
pp. 636-642
Author(s):  
Michal Németh ◽  
Ján Mocák
Keyword(s):  
Chemical Reactions ◽  
Potential Distribution ◽  
Anaerobic Conditions ◽  
Highly Efficient ◽  
Working Electrode ◽  
Constant Potential ◽  
Quantitative Analyses ◽  
Mechanism And Kinetics ◽  
Kinetics Of

A highly efficient coulometric cell was designed and constructed, ensuring a constant potential over the whole surface of the working electrode and suitable for very rapid electrolysis. It consists of concentric cylindrical Teflon parts; also the working and auxiliary electrodes are cylindrical and concentric. Electrolysis can be carried out under anaerobic conditions. Functioning of the cell was tested on the oxidation of hexacyanoferrate(II) and chlorpromazine and reduction of hexacyanoferrate(III). The new cell is suitable for routine quantitative analyses and in studying the mechanism and kinetics of moderately rapid chemical reactions.

scholarly journals Prospect for the using of heat pumps for heating of buildings in enterprise

2020 ◽  
Author(s):  
Z. Sirkо ◽  
◽  
V. Korenda ◽  
I. Vyshnyakov ◽  
O. Protasov ◽  
...  
Keyword(s):  
Water Supply ◽  
Heat Pump ◽  
Thermal Energy ◽  
Alternative Energy ◽  
Thermodynamic Cycle ◽  
Heat Pumps ◽  
The State ◽  
Hot Water ◽  
Alternative Energy Sources ◽  
Hot Water Supply

Heat pump - a device for transferring thermal energy from a source of low potential thermal energy to a consumer with a higher temperature. The thermodynamic cycle of a heat pump is similar to a refrigerating machine. Depending on the principle of operation, heat pumps are divided into compression and absorption. The most commonly used compression heat pumps. In recent years, numerous publications on the use of heat pump technology in heating and hot water supply facilities of various spheres - from individual homes to residential neighborhoods have appeared in various media. The authors of the publication have many years of experience in joint scientific and technical cooperation with leading technical universities and industrial organizations in the field of development and practical use of heat pump technology. The authors analyze the possibilities of introducing heat pumps at enterprises and organizations of the State Reserve System of Ukraine. It has been shown that the amount of expenses in comparison with central heating or operation of gas and electric boilers of similar power is several times smaller. It is noted that the implementation of heat pumps is a promising direction in the use of alternative energy sources to meet the heating, ventilation and hot water supply needs of buildings. The payback period from the introduction of heat pumps at enterprises is 4-9 years, depending on the location of the object and the type of source of low-temperature heat. The article meets the requirements of the State Tax Code of Ukraine and can be recommended for publication.

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