Comparing Flexible CO2 Capture in Gas- and Coal-Dominated Electricity Markets

Author(s):  
John R. Fyffe ◽  
Stuart M. Cohen ◽  
Michael E. Webber

Coal-fired power plants are a source of inexpensive, reliable electricity for many countries. Unfortunately, their high carbon dioxide (CO2) emissions rates contribute significantly to global climate change. With the likelihood of future policies limiting CO2 emissions, CO2 capture and sequestration (CCS) could allow for the continued use of coal while low- and zero-emission generation sources are developed and implemented. This work compares the potential impact of flexibly operating CO2 capture systems on the economic viability of using CCS in gas- and coal-dominated electricity markets. The comparison is made using a previously developed modeling framework to analyze two different markets: 1) a natural-gas dominated market (the Electric Reliability Council of Texas, or ERCOT) and 2) a coal-dominated market (the National Electricity Market, or NEM in Australia). The model uses performance and economic parameters for each power plant to determine the annual generation, CO2 emissions, and operating profits for each plant for specified input fuel prices and CO2 emissions costs. Previous studies of ERCOT found that flexible CO2 capture operation could improve the economic viability of coal-fired power plants with CO2 capture when there are opportunities to reduce CO2 capture load and increase electrical output when electricity prices are high. The model was used to compare the implications of using CO2 capture systems in the two electricity systems under CO2 emissions penalties from 0–100 US dollars per metric ton of CO2. Half the coal-fired power plants in each grid were selected to be considered for a CO2 capture retrofit based on plant efficiency, whether or not SO2 scrubbers are already installed on the plant, and the plant’s proximity to viable sequestration sites. Plants considered for CO2 capture systems are compared with and without inflexible CO2 capture as well as with two different flexible operation strategies. With more coal-fired power plants being dispatched as the marginal generator and setting the electricity price in the NEM, electricity prices increase faster due to CO2 prices than in ERCOT where natural gas-plants typically set the electricity price. The model showed moderate CO2 emissions reductions in ERCOT with CO2 capture and no CO2 price because increased costs at coal-fired power plants led to reduced generation. Without CO2 prices, installing CO2 capture on coal-fired power plants resulted in moderately reduced CO2 emissions in ERCOT as the coal-fired power plants became more expensive and were replaced with less expensive natural gas-fired generators. Without changing the makeup of the plant fleet in NEM, a CO2 price would not currently promote significant replacement of coal-fired power plants because there is minimal excess capacity with low CO2 emissions rates that can displace existing coal-fired power plants. Additionally, retrofitting CO2 capture onto half of the coal-based fleet in NEM did not reduce CO2 emissions significantly without CO2 costs being implemented because the plants with capture become more expensive and were replaced by the coal-fired power plants without CO2 capture. Operating profits at NEM capture plants increased as CO2 price increased much faster than capture plants in ERCOT. The higher rate of increasing profits for plants in NEM is due to the marginal generators in NEM being coal-based facilities with higher CO2 emissions penalties than the natural gas-fired facilities that set electricity prices in ERCOT. Overall, coal-fired power plants were more profitable with CO2 capture systems than without in both ERCOT and NEM when CO2 prices were higher than USD25/ton.

Author(s):  
John R. Fyffe ◽  
Stuart M. Cohen ◽  
Michael E. Webber ◽  
Gary T. Rochelle

Global focus on greenhouse gas emissions has led the United State’s legislature to discuss various strategies to reduce carbon dioxide (CO2) emissions. With coal-fired plants responsible for roughly half of United States (U.S.) electricity generation and approximately 30% of the nation’s CO2 emissions, coal-fired plants will be largely affected by any future CO2 emission regulations. However, coal-based generation could continue to meet our electricity demands while complying with future CO2 emissions restrictions with the addition of carbon dioxide capture and sequestration (CCS) technology. Most studies of CCS systems have demonstrated a permanent energy requirement of 11–40% of a plant’s output when operating continuously at a 90% CO2 removal rate. This study, however, used a dynamic model of the Electric Reliability Council of Texas (ERCOT) electric grid to consider post-combustion CO2 capture systems that can operate flexibly. Post-combustion CO2 capture systems using chemical absorption and stripping are particularly suited for retrofitting existing plants and operating in a flexible manner. Flexible carbon capture allows plant operators to vary the energy used for CO2 capture and compression in order to regain this generation capacity when desirable. Thus, flexibility can be used to choose the CO2 capture rate that allows the most economical combination of operating costs, electricity price, and output levels. Furthermore, operating at lower CO2 capture energy requirement levels and increasing output capacity during peak demand periods could dramatically reduce the amount of replacement capacity needed to replace potential output lost when CO2 capture systems are in operation. This research uses an existing modeling framework of a dynamic hourly dispatch system to study the economic, environmental, and performance implications of flexible CO2 capture over an investment lifetime. The effects of CO2 prices, natural gas fuel prices, and replacement capacity costs were analyzed along with various operating strategies. The fuel mixture behavior and emissions effects are presented, showing that large emissions reductions can be achieved using the current ERCOT plant fleet with the addition of flexible CO2 capture. An annual system-level cash-flow analysis is used to determine a net present value (NPV) for a group of CO2 capture plants under a range of possible replacement capacity costs. If replacement capacity costs are accounted for, flexibility can improve the NPV of a CO2 capture investment by substantially lowering the associated capital costs to replace output lost to CO2 capture energy requirements.


Author(s):  
Jesu´s M. Escosa ◽  
Cristo´bal Cortes ◽  
Luis M. Romeo

Fossil fuel power plants account for about a third of global carbon dioxide emissions. Coal is the major power-generation fuel, being used twice as extensively as natural gas (IEA, 2003). Moreover, on a global scale, coal demand is expected to double over the period to 2030; IEA estimates that 4500 GWe of new installed power will be required. Coal is expected to provide 40% of this figure. It is thus obvious that coal power plants must be operative to provide such amount of energy in the short term, at the same time reducing their CO2 emissions in a feasible manner and increasing their efficiency and capacity. However, the main technologies currently considered to effect CO2 capture, both post-and pre-combustion, introduce a great economic penalty and largely reduce the capacity and efficiency. One of these technologies involves the separation of CO2 from high temperature flue gases using the reversible carbonation reaction of CaO and the calcination of CaCO3. The process is able to simultaneously capture sulfur dioxide. The major disadvantage of this well-known concept is the great amount of energy consumption in the calcinator and auxiliary equipment. This paper proposes a new, feasible approach to supply this energy which leads to an optimal integration of the process within a conventional coal power plant. Calcination is accomplished in a kiln fired by natural gas, whereas a gas turbine is used to supply all the auxiliary power. Flue gases from the kiln and the gas turbine can substitute a significant part of the heat duty of the steam cycle heaters, thus accomplishing feed water repowering of the steam turbine. This novel CO2-capture cycle is proposed to be integrated with aging coal-fired power plants. The paper shows that an optimal integration of both elements represents one of the best methods to simultaneously achieve: a) an increase of specific generating capacity in a very short period of time, b) a significant abatement of CO2 emissions, and c) an increase of plant efficiency in a cost-effective way.


Author(s):  
Stuart M. Cohen ◽  
Michael E. Webber ◽  
Gary T. Rochelle

Carbon dioxide (CO2) capture with amine scrubbing at coal-fired power plants can remove 90% of the CO2 from flue gas, but operational energy requirements reduce net electrical output by 20–30%. Temporarily reducing the load on energy intensive components of the amine scrubbing process could temporarily increase power output and allow additional electricity sales when prices are high. Doing so could entail additional CO2 emissions, or amine solvent storage can be utilized to allow increased power output without additional CO2 emissions. Price-responsive flexible capture is studied for $0–200/tCO2 and $2–11/MMBTU natural gas using a nominal 500 MW coal-fired facility in the 2010 Electric Reliability Council of Texas (ERCOT) grid. CO2 capture systems use a 7 molal monoethanolamine (MEA) solvent. Venting additional CO2 while increasing electrical output provides significant benefit only at $30–60/tCO2 and when natural gas prices exceed $4/MMBTU. Solvent storage can improve profitability with CO2 capture at higher CO2 emissions penalties, but primarily at low-to-moderate natural gas prices when power plant capacity factor is less than 90%.


2016 ◽  
Vol 139 (3) ◽  
Author(s):  
Bilal Hassan ◽  
Oghare Victor Ogidiama ◽  
Mohammed N. Khan ◽  
Tariq Shamim

A thermodynamic model and parametric analysis of a natural gas-fired power plant with carbon dioxide (CO2) capture using multistage chemical looping combustion (CLC) are presented. CLC is an innovative concept and an attractive option to capture CO2 with a significantly lower energy penalty than other carbon-capture technologies. The principal idea behind CLC is to split the combustion process into two separate steps (redox reactions) carried out in two separate reactors: an oxidation reaction and a reduction reaction, by introducing a suitable metal oxide which acts as an oxygen carrier (OC) that circulates between the two reactors. In this study, an Aspen Plus model was developed by employing the conservation of mass and energy for all components of the CLC system. In the analysis, equilibrium-based thermodynamic reactions with no OC deactivation were considered. The model was employed to investigate the effect of various key operating parameters such as air, fuel, and OC mass flow rates, operating pressure, and waste heat recovery on the performance of a natural gas-fired power plant with multistage CLC. The results of these parameters on the plant's thermal and exergetic efficiencies are presented. Based on the lower heating value, the analysis shows a thermal efficiency gain of more than 6 percentage points for CLC-integrated natural gas power plants compared to similar power plants with pre- or post-combustion CO2 capture technologies.


Energies ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 543 ◽  
Author(s):  
Manuele Gatti ◽  
Emanuele Martelli ◽  
Daniele Di Bona ◽  
Marco Gabba ◽  
Roberto Scaccabarozzi ◽  
...  

The objective of this study is to assess the technical and economic potential of four alternative processes suitable for post-combustion CO2 capture from natural gas-fired power plants. These include: CO2 permeable membranes; molten carbonate fuel cells (MCFCs); pressurized CO2 absorption integrated with a multi-shaft gas turbine and heat recovery steam cycle; and supersonic flow-driven CO2 anti-sublimation and inertial separation. A common technical and economic framework is defined, and the performance and costs of the systems are evaluated based on process simulations and preliminary sizing. A state-of-the-art natural gas combined cycle (NGCC) without CO2 capture is taken as the reference case, whereas the same NGCC designed with CO2 capture (using chemical absorption with aqueous monoethanolamine solvent) is used as a base case. In an additional benchmarking case, the same NGCC is equipped with aqueous piperazine (PZ) CO2 absorption, to assess the techno-economic perspective of an advanced amine solvent. The comparison highlights that a combined cycle integrated with MCFCs looks the most attractive technology, both in terms of energy penalty and economics, i.e., CO2 avoided cost of 49 $/tCO2 avoided, and the specific primary energy consumption per unit of CO2 avoided (SPECCA) equal to 0.31 MJLHV/kgCO2 avoided. The second-best capture technology is PZ scrubbing (SPECCA = 2.73 MJLHV/kgCO2 avoided and cost of CO2 avoided = 68 $/tCO2 avoided), followed by the monoethanolamine (MEA) base case (SPECCA = 3.34 MJLHV/kgCO2 avoided and cost of CO2 avoided = 75 $/tCO2 avoided), and the supersonic flow driven CO2 anti-sublimation and inertial separation system and CO2 permeable membranes. The analysis shows that the integrated MCFC–NGCC systems allow the capture of CO2 with considerable reductions in energy penalty and costs.


Author(s):  
Stuart M. Cohen ◽  
John Fyffe ◽  
Gary T. Rochelle ◽  
Michael E. Webber

Coal consumption for electricity generation produces over 30% of U.S. carbon dioxide (CO2) emissions, but coal is also an available, secure, and low cost fuel that is currently utilized to meet roughly half of America’s electricity demand. While the world transitions from the existing fossil fuel-based energy infrastructure to a sustainable energy system, carbon dioxide capture and sequestration (CCS) will be a critical technology that will allow continued use of coal in an environmentally acceptable manner. Techno-economic analyses are useful in understanding the costs and benefits of CCS. However, typical techno-economic analyses of post-combustion CO2 capture systems assume continuous operation at a high CO2 removal, which could use 30% of pre-capture electricity output and require new capacity installation to replace the output lost to CO2 capture energy requirements. This study, however, considers the inherent flexibility in post-combustion CO2 capture systems by modeling power plants that vary CO2 capture energy requirements in order to increase electricity output when economical under electricity market conditions. A first-order model of electricity dispatch and a competitive electricity market is used to investigate flexible CO2 capture in response to hourly electricity demand variations. The Electric Reliability Council of Texas (ERCOT) electric grid is used as a case study to compare plant and grid performance, economics, and CO2 emissions in scenarios without CO2 capture to those with flexible or inflexible CO2 capture systems. Flexible CO2 capture systems can choose how much CO2 to capture based on the competition between CO2 and electricity prices and a desire to either minimize operating costs or maximize operating profits. Coal and natural gas prices have varying degrees of predictability and volatility, and the relative prices of these fuels have a major impact on power plant operating costs and the resulting plant dispatch sequence. Because the chosen operating point in a flexible CO2 capture system affects net power plant efficiency, fuel prices also influence which CO2 capture operating point may be the most economical and the resulting dispatch of power plants with CO2 capture. Several coal and natural gas price combinations are investigated to determine their impact on flexible CO2 capture operation and the resulting economic and environmental impacts at the power plant and electric grid levels. This study investigates the costs and benefits of flexible CO2 capture in a framework of a carbon-constrained future where the effects of major energy infrastructure changes on fuel prices are not entirely clear.


Author(s):  
Hannah Chalmers ◽  
Jon Gibbins ◽  
Mathieu Lucquiaud

Carbon capture and storage (CCS) is often identified as an important technology for mitigating global carbon dioxide (CO2) emissions. For example, the IEA currently suggests that 160GW of CCS may need to be installed globally by 2030 as part of action to limit greenhouse gas concentrations to 550ppm-CO2eq, with a further 190GW CCS capacity required if a 450ppm-CO2eq target is to be achieved. Since global rollout of proven CCS technologies is not expected to commence until 2020 at the earliest this represents a very challenging build rate. In these circumstances retrofitting CO2 capture to existing plants, probably particularly post-combustion capture on pulverized coal-fired plants, could play an important role in the deployment of CCS as a global strategy for implementing CO2 emissions reductions. Retrofitting obviously reduces the construction activity required for CCS deployment, since fewer additional new power plants are required. Retrofitting CCS to an existing fleet is also an effective way to significantly reduce CO2 emissions from this sector of the electricity generation mix; it is obviously not possible to effect an absolute reduction in coal power sector CO2 emissions simply by adding new plants with CCS to the existing fleet. Although it has been proposed that plants constructed now and in the future can be ‘capture ready’, much of the existing fleet will not have been designed to be suitable for retrofit of CO2 capture. Some particular challenges that may be faced by utilities and investors considering a retrofit project are discussed. Since it is expected that post-combustion capture retrofits to pulverized coal plants will be the most widely applied option for retrofit to the existing fleet (probably regardless of whether base plants were designed to be capture ready or not), a review of the technical and potential economic performance of this option is presented. Power cycle performance penalties when capture is retrofitted need to be addressed, but satisfactory options appear to exist. It also seems likely that the economic performance of post-combustion capture retrofit could be competitive when compared to other options requiring more significant capital expenditure. Further work is, however, required both to develop a generally accepted methodology for assessing retrofit economics (including consideration of the implications of lost output after retrofit under different electricity selling price assumptions) and to apply general technical principles to case studies where site-specific constraints are considered in detail. The overall conclusion from the screening-level analysis reported in this paper is that, depending on project-specific and market-specific conditions, retrofit could be an attractive option, especially for fast track initial demonstration and deployment of CCS. Any unnecessary regulatory or funding barriers to retrofit of existing plants and to their effective operation with CCS should, therefore, be avoided.


2019 ◽  
Vol 12 (7) ◽  
pp. 2161-2173 ◽  
Author(s):  
Rebecca L. Siegelman ◽  
Phillip J. Milner ◽  
Eugene J. Kim ◽  
Simon C. Weston ◽  
Jeffrey R. Long

As natural gas supplies a growing share of global primary energy, new research efforts are needed to develop adsorbents for carbon capture from gas-fired power plants alongside efforts targeting emissions from coal-fired plants.


2019 ◽  
Vol 46 (2) ◽  
pp. 356-371 ◽  
Author(s):  
Bruno Bernal ◽  
Juan Carlos Molero ◽  
Fernando Perez De Gracia

Purpose The purpose of this paper is to examine the impact of fossil fuel prices – crude oil, natural gas and coal – on different electricity prices in Mexico. The use of alternative variables for electricity price helps to increase the robustness of the analysis in comparison to previous empirical studies. Design/methodology/approach The authors use an unrestricted vector autoregressive model and the sample covers the period January 2006 to January 2016. Findings Empirical findings suggest that crude oil, natural gas and coal prices have a significant positive impact on electricity prices – domestic electricity rates – in Mexico in the short run. Furthermore, crude oil and natural gas prices have also a significant positive impact on electricity prices – commercial and industrial electricity rates. Originality/value Two are the main contributions. First, this paper explores the nexus among crude oil, natural gas, coal and electricity prices in Mexico, while previous studies focus on the US, UK and some European economies. Second, instead of using one electricity price as a reference of national or domestic electricity sector, the analysis considers alternative Mexican electricity prices.


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