Trends in COP for Adsorption Cooling Cycles With Thermal Regeneration and Finite Number of Beds

Author(s):  
Derek K. Baker ◽  
Bilgin Kaftanog˘lu

A thermodynamic model is developed to predict trends in limiting COP of an adsorption cooling cycle with thermal regeneration between n beds, where n is any even number and each bed is spatially isothermal. The results of the model indicate the optimum distribution of beds throughout the cycle to maximize thermal regeneration. Simulations were run for silica gel-water and zeolite-water adsorbent-refrigerant pairs as the maximum bed temperature and the bed’s sensible load were varied. For the silica gel-water pair, the exothermic adsorption process occurs at lower temperatures than the endothermic desorption process, which prevents the latent loads from being thermally regenerated. This inability to regenerate latent loads results in a relatively small opportunity to increase COP through thermal regeneration, and this opportunity decreases rapidly with increasing number of beds. Conversely, for the zeolite-water pair much of the exothermic adsorption process occurs over the same temperature range as the endothermic desorption process, which allows a significant portion of the latent loads to be thermally regenerated. This ability to regenerate latent loads results in a much larger opportunity to increase COP through thermal regeneration, and this opportunity decreases much more gradually with increasing number of beds.

2021 ◽  
Vol 348 ◽  
pp. 01016
Author(s):  
Rajaa Bassam ◽  
Marouane El Alouani ◽  
Nabila Jarmouni ◽  
Jabrane Maissara ◽  
Mohammed El Mahi Chbihi ◽  
...  

Heavy metals are the most dangerous inorganic pollutants Due to their bioaccumulation and their nonbiodegradability, for this, several studies have focused on the recovery of these metals from water using different techniques. In this context, our study consists of evaluating an efficient and eco-friendly pathway of competitive recovery of heavy metals (Cd, Cr and As) from aqueous solutions by adsorption using raw rock. This adsorbent was characterized before and after the adsorption process by several techniques. The multi-metals adsorption process in the batch mode was undertaken to evaluate the effect of adsorbent mass, contact time, pH, Temperature, and initial heavy metals concentration. The kinetic data were analyzed using the pseudo-first-order, pseudo-second-order and intra-particle diffusion kinetic models. According to the modeling of the experimental results, the adsorption kinetics of heavy metals were adapted to the pseudo-second-order model. The adsorption isotherms were evaluated by the Langmuir and Freundlich isotherm models. The experimental isotherm data of heavy metals were better fitted with the Langmuir model rather than Freundlich isotherm models. The maximum experimental adsorption capacities (Qmax) predicted by the Langmuir model are 15.23 mg/g for Cd (II), 17.54 mg/g for Cr (VI) and 16.36 mg/g for As (III). The values of thermodynamic parameters revealed that the heavy metals adsorption was exothermic, favorable, and spontaneous in nature. The desorption process of heavy metals showed that this raw rock had excellent recycling capacity. Based on the results, these untreated clays can be used as inexpensive and environmentally friendly adsorbents to treat water contaminated by heavy metals.


2010 ◽  
Vol 6 (3) ◽  
pp. 245-250 ◽  
Author(s):  
Buhani Buhani ◽  
Suharso Suharso ◽  
Zipora Sembiring

Sargassum duplicatum algae biomass is biological material which has a potency to be used as a biosorbent adsorb metal ions from industrial liquid waste, because it has effective functional group as a ligand. However, the ability of the algae biomass in adsorbing of heavy metal ions has some problem such as; tiny size, low density, and easy to be degradated by other microorganism. In addition, algae biomass can not be used directly in adsorption column for its application as the biosorbent. In order to improve physical and chemical prpperties of algae biomass, it needs to be immobilized on silica gel matrix. Series of experiment have been done, morphology analysis of adsorbent surface was performed by using Scanning Electron Microscopy (SEM) and adsorption process to examine the effectiveness of algae biomass immobilized in adsorbing Pb(II), Cu(II), and Cd(II) was performed using batch method at 27 °C. Concentration of metal was determined by using Atomic Absorption Spectrophotometer (AAS) and identification of functional group was conducted using Spectrophotometer Infrared (IR). Data obtained showed that interacting among metal ions with algae biomass is optimum at a range of 60 minutes. Adsorption energies of metal ions resulted from the interaction of metal ions with the functional group of -C=O group from carboxyl and amide on algae biomass and -Si-OH group from silica were at a range of 21.09-25.05 kJ/mole.   Keywords: biosorption, silica gel, Sargassum duplicatum, immobilization


Proceedings ◽  
2019 ◽  
Vol 48 (1) ◽  
pp. 10
Author(s):  
Fatima Sbait Wahshi ◽  
Maitha Dhaiman Alqahtani ◽  
Manhal Abdulla ◽  
Tholkappiyan Ramachandran ◽  
Fathalla Hamed ◽  
...  

Silica gel was used as an adsorbent for dyes in aqueous solutions. Afterwards, the silica gel with the adsorbed dye was heated to 600 °C, at which the dye combusted, leaving behind clean silica gel. This silica gel can be reused in the adsorption process. The operation leaves behind little waste products. It is an optimal procedure for educational and other research laboratories which are working with biological stains, food colorants and some non-commercial dyes.


2018 ◽  
Vol 762 ◽  
pp. 81-86 ◽  
Author(s):  
Hakim Aguedal ◽  
Abdelkader Iddou ◽  
Janis Locs

A design of experiments based on the Taguchi method was used to evaluate the main parameters affecting the removal of textile dyes from aqueous solution. By using the adsorption capacity of textile dye as target response, several experiments were carried out using L27 orthogonal array, and the higher-the-better as quality characteristics was applied. The controlling factors, including initial dye concentration, contact time and pH of solution were assessed. Analysis of variance (ANOVA) was used to determine the effects of each factor on the adsorption capacity. The optimum adsorption conditions giving higher adsorption capacity were selected as initial dye concentration of 500 mg.L-1, contact time of 180 min and pH of solution of 2. The analysis results revealed that the most relevant factors affecting the adsorption process of textile dye are the initial dye concentration and pH of solution. After 3 cycles of thermal regeneration, the diatomite behavior did not change and more than 60 % of dye was eliminated from solution after regeneration at 600°C. From the obtained results, the Taguchi method was very successful to optimize of the adsorption parameters for maximum removal rate, and gives more credibility for industrial application.


2021 ◽  
Author(s):  
Mohamad Hossein Bakhshandeh ◽  
Taleb Zarei ◽  
Jamshid Khorshidi

Abstract One of the critical elements of an adsorption desalination system is the adsorption bed. System dynamics of a 2-bed single-stage silica gel plus water-based AD system was analyzed. A great pattern is expanded using energy conservation and mass connected with the kinetics of the ad- sorption/desorption process. Computational fluid dynamics (CFD) modeling was handled for simulation of the adsorption process for a rectangular finned tube-based adsorption bed featured with silica gel adsorbent substance. For the simulation, the adsorbents were considered as a solid volume with defined porosity based on Darcy equation. The adsorption and desorption mode of the adsorption bed was simulated. The CFD techniques were then applied to study fin thickness and fin height. The results showed that decreasing the fin thickness increased the water uptake by up to 8% and decreased the fin height from 30mm to 20mm, which resulted in an increase of the water uptake up to 17%. The CFD technique was also used to investigate the effect of plate type on the adsorption bed performance. The results showed that the copper plate improved the water uptake up to 9%. The copper plate decreased the temperature of the adsorption bed up to 11% more than the aluminum plate.


2019 ◽  
Vol 141 (3) ◽  
pp. 1243-1250 ◽  
Author(s):  
K. I. Hnatiuk ◽  
R. V. Dinzhos ◽  
M. S. Simeonov ◽  
A. N. Alekseev ◽  
S. A. Alekseev ◽  
...  

Konversi ◽  
2018 ◽  
Vol 6 (2) ◽  
pp. 21 ◽  
Author(s):  
Muhammad Prasanto Bimantio

Abstract - Zeolites can be used as adsorbent, ion exchange, catalyst, or catalyst carrier. Application of fertilizer use in the zeolite also be one of the interesting topic. Zeolites in a mixture of fertilizer can use to control the release of nutrients. The purpose of this research is to study the effect of grain size and time of the activation of zeolite to adsorption and desorption of NH4OH and KCl as modeling of ZA and KCl fertilizer, to obtain the value of adsorption rate constant (ka) and desorption rate constant (kd). This research procedure include: the process of adsorption by adding zeolite with various size and time of activation into a sealed beaker glass and let the adsorption process occurs for 24 hours. After 24 hours, the solution was filtered, the zeolite then put in 100 ml of aquadest into a sealed beaker glass and let the desorption process happened for another 24 hours. Three samples with the largest difference solution concentrations looked for the value of the ka and kd. Zeolite configuration with the largest ka is trialed with fertilizer and compared with the value of ka obtained from modeling. The result for NH4OH adsorbate, -50+60 mesh 2 hours configuration zeolite give the largest ka. For KCl adsorbate, -30+40 mesh 4 hours configuration zeolite give the largest ka. The value between modeling and trials with fertilizers are not much different. Keywords: zeolite, ZA fertilizer, KCl fertilizer, mathematical modelling.


2013 ◽  
Vol 664 ◽  
pp. 609-613
Author(s):  
Xue Chuan Wang ◽  
Xiao Li Hao ◽  
Tao Tao Qiang

A novel microspheres adsorbent was prepared by the emulsion-congealed crosslinking method. The gelatin was as raw material and glutaraldehyde was as the crosslinking agent. The product was characterized by AFM, Zeta Potential Tester and SEM. These results showed that there were some irregular protuberances and grooves on the surface of gelatin microspheres. The relative surface roughness namely Ra was equal to 2.469E+01nm. The isoelectric point of gelatin microspheres was 3.2. Their morphology was almost not affected by treatment of the acid and alkali, and the performance of the acid and alkali resistance was superior. The result of desorption experiment showed that the regeneration ability of gelatin microspheres was stronger in the alkali solution than that in the distilled water. The optimum desorption temperature was 30°C. The desorption process got to balance for 80min. The desorption rate got to 88% in the alkali solution and regeneration effect was obvious. The result of the second-adsorption experiment showed that the desorbed adsorbent which was used in the second-adsorption experienced the same as the first-adsorption process. And the saturated adsorption capacity changed a little. So the gelatin microspheres can be recycled.


2014 ◽  
Vol 48 (3) ◽  
pp. 190-197
Author(s):  
Chen-Bo Cai ◽  
Yong-Yuan Tao ◽  
Bo Wang ◽  
Mei-Qiong Wen ◽  
Hong-Wei Yang ◽  
...  

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