Initial Modeling of Material Phase Driven Localized Corrosion

Author(s):  
Stephanie A. Wimmer ◽  
Virginia G. DeGiorgi

Localized corrosion often occurs when regions of a single material demonstrate a difference in electrochemical potential. Cathodic and anodic regions can develop in a component comprised of a single material. This variation is one cause of localized corrosion damage. This phenomenon of localized anode and cathode regions is well documented but not well understood. In this work the authors are examining variations in electrochemical response of individual grains within a metallic material. The objective is to determine if the distinct electrochemical response associated with austenite and ferrite phases in steel are sufficient to create a localized electrochemical corrosion cell. In this paper the authors present the first of a series of models that capture localized electrochemical corrosion driven by variations in grain polarization response.

2005 ◽  
Vol 127 (3) ◽  
pp. 244-254 ◽  
Author(s):  
M. G. Lozev ◽  
R. W. Smith ◽  
B. B. Grimmett

Offshore pipeline failure statistics have been collected for more than 30 years now and illustrate that the riser predominantly fails as a result of corrosion. The consistent wetting and drying in the splash zone combined with defects in the coatings are the usual contributors to the problem. Risers are inspected at some determined frequency and can be done by internal and external methods. Inspecting by either means brings into account caveats and limitations from the technology used as well as human factors. For example, external inspections can be inefficient and inaccurate with some tools missing defects in areas of coating disbondment. In addition, internal inspections sometimes create false positives and can miss defects. These inaccuracies in the technologies or the techniques used may miss defects that eventually lead to failure. On the other hand, using corrosion mapping and fitness-for-service (FFS) assessment from the data collected, along with the inherent conservatism of this data from limited measurement accuracy, may result in the premature replacement of risers. A literature search is being conducted to review existing riser inspection methods and identify candidate nondestructive methods for riser inspection. These methods should be capable of detecting and monitoring general corrosion, localized corrosion pitting, and stress-corrosion cracking (sulfide or hydrogen induced) as external or internal corrosion damage. Thus far, this search has found that assessing the remaining service life of aging risers is largely dependent on the accuracy of analyzing corrosion damage to the riser surface in the atmospheric, splash (tidal), submerged, and buried environmental zones. The accuracy of each technology was analyzed. The capabilities and limitations of each method/technique used for riser inspection are summarized. The investigation is focused on long- and short-range ultrasonic techniques used for initial screening and corrosion mapping. These techniques can be deployed to detect a significant reduction in wall thickness using guided and torsional waves or to map accurately a corrosion damage using single/multiple transducers and phased-array probes in manual or automated mode. A pulsed eddy-current technique that uses a stepped or pulsed input signal for the detection of corrosion areas under insulation (CUI) is also being evaluated. This allows the detection of wall-thinning areas in the riser without removing the outside coatings. In addition, it is found that filmless, real-time, and digital radiography can be used to find internal and external corrosion defects in an insulated splash zone while the riser remains in service. A survey of nondestructive evaluation (NDE) manufacturing companies, NDE inspection companies, and operating companies was completed to collect information about current instrumentation and inspection/operators’ experience for riser inspection. Examples of advanced riser inspection instrumentation and field results are included. The ability of the candidate technologies to be adapted to riser variations, the stage of standardization, and costs are also discussed.


2013 ◽  
Vol 550 ◽  
pp. 127-134
Author(s):  
Nicoleta Radutoiu ◽  
Joël Alexis ◽  
Loïc Lacroix ◽  
Marioara Abrudeanu ◽  
Jacques Alain Petit

The 2xxx serie aluminum alloys are characterized by good mechanical performances and low density, however they are susceptible to different forms of localized corrosion: pitting corrosion, intergranular corrosion and stress corrosion cracking. The 2024-T351 aluminum alloy is used in the aircraft industry for numerous applications such as fuselage and door skin. Corrosion damage of the material is also very detrimental for the structural integrity of the aircraft. The presence of coarse intermetallic particles, with a heterogeneous size distribution was found to be responsible for the 2024 susceptibility to localized corrosion. These particles are generally the cause of initiation sites. Presence of micro-defects in the oxide film upon coarse intermetallic particles and the galvanic coupling with the matrix contribute to the development of pitting corrosion. The over-ageing treatment (T7) is supposed to stabilize the microstructure and the mechanical properties to improve the corrosion resistance. The 2024 alloy microstructure after the T7 heat treatment remains very complex. The 2024 alloy corrosion behavior was studied in the over-ageing state for three different temperatures (150, 175 and 190 °C). During the corrosion tests in chloride-containing environment, the behavior of coarse intermetallic particles was found to be different. Thus, the 2024 samples suffer a gradual attack upon S-Al2CuMg particles and finally Al (Cu,Mn,Fe,Si) particles. The corrosion damage was studied by Atomic Force Microscopy (AFM) and Kelvin probe Force Microscopy (KFM). This technique allows simultaneous topographical and electric potential mapping to be obtained. This latest potential was shown to be correlated to the corrosion potential of the 2024 alloy. This study focuses on the variation of the KFM potential of the coarse intermetallic particles and the matrix for the over-ageing conditions (T7). Observations using optical microscope and AFM were also performed to obtain the corrosion rate for each condition. The corrosion rate was correlated to the chemical composition variation of the particles obtained by scanning electron microscope observations and EDS analyses.


2013 ◽  
Vol 758 ◽  
pp. 65-76 ◽  
Author(s):  
Matherson L. da Silva ◽  
Heraldo da Costa Mattos

The goal of the present paper is to propose a simple methodology to estimate the failure pressure of thin-walled metallic pipelines with arbitrary localized corrosion damage. This methodology is conceived as a preliminary tool for a quick analysis of the structural integrity of real corroded pipelines. Due to the different possible geometries of the corroded region, the exact analysis of this kind of problem can be very complex (in general using an elasto-plastic finite element simulation). The idea is to obtain an approximate exact analytical solution of the problem for any arbitrary geometry of the corroded region considering elasto-plastic constitutive equations and a factor that accounts for the stress concentration due to the metal loss caused by corrosion. With a simple expression, a reasonable lower limit for the failure pressure can be obtained.


Author(s):  
Tatyana MECHKAROVA ◽  
Yaroslav ARGIROV ◽  
Daniela SPASOVA ◽  
Aneliya STOYANOVA

This paper aims to determine the extent of aging of nitrogen ferrite at temperatures below 100 °C and the structural and strength changes that occur in the process. The tests are carried out on samples of technically pure iron (Armco). The specimens are pre-deformed by tension and re-crystallisation heating to achieve a large-grain ferrite structure. A large-grained structure has been chosen to more accurately track the change in micro-hardness of the individual grains during the aging process. Nitric ferrite results from gas carbonitriding and subsequent hardening. Upon hardening, the samples are stored in a refrigerator, and then the surface layer formed is removed through electrochemical corrosion. Afterwards, aging heat treatment at temperatures below 100 °C is undertaken. After the aging process, micro-hardness of the individual grains is examined and X-ray structural analysis is performed.


CORROSION ◽  
10.5006/3257 ◽  
2019 ◽  
Vol 75 (10) ◽  
pp. 1216-1229 ◽  
Author(s):  
L.H. Guilherme ◽  
P. Reccagni ◽  
A.V. Benedetti ◽  
C.S. Fugivara ◽  
D.L. Engelberg

ASME qualified welding procedures do not guarantee suitable corrosion and passivation properties for lean duplex stainless steel welds. An evaluation of two ASME qualified welding procedures to optimize the corrosion performance of tungsten inert gas (TIG) welded grade 2101 duplex stainless steel using ER2209 weld consumable was conducted. The evolution of the microstructure was examined by optical and electron microscopy, ferrite-scope measurements, and scanning Kelvin probe force microscopy. An electrochemical mini-cell was then used to characterize the electrochemical behavior of different weld regions using the techniques such as the double loop electrochemical potentiokinetic reactivation test, standard potentiodynamic polarization tests, and cyclic potentiodynamic polarization. The fusion line was the most critical zone for localized corrosion for both welding procedures, due to the formation of Cr- and Mo-depleted zones, resulting in the highest degree of sensitization. The best performance was attributed to the weld face, due to the presence of higher Cr and Mo contents, highlighting the pitting corrosion resistance. A heat input range of 1.6 kJ/mm to 1.9 kJ/mm and low current density (WPS 1) indicated better corrosion performance of all weld regions. The electrochemical corrosion response was in all cases related to microstructural characteristics of the weld regions. The influence of weld parameters on microstructure development and corrosion performance is discussed.


2017 ◽  
Vol 3 (4) ◽  
pp. 285 ◽  
Author(s):  
A. Benmoussat ◽  
H. Hadjiat ◽  
M. Hadjel

Under degraded coatings and inadequate cathodic protection (CP) steel gas pipelines exposed to environmentally assisted multiple corrosion. In  electrochemical process corrosion, dissolution of the iron is an anodic reaction. The nature of the cathodic process depends on the availability of oxygen and implies aerobics or anaerobics conditions. The most severe corrosion process is that of microbiologically influenced corrosion. Damage can be a localized corrosion or SCC corrosion (Stress corrosion cracking). Microstructural damage is intergranular type at low stress intensity and implies the interaction of the material with the corrosive environment characterized by the apparition of corrosion microcracks.


2001 ◽  
Author(s):  
Mohammad Khobaib ◽  
Jochen Hoffmann ◽  
Shamachary Sathish ◽  
Michael S. Donley

Abstract Polymer coatings provide an excellent corrosion barrier for Al-skinned military aircraft. However, the degradation and damage of the coatings in their service life over time leads to the initiation of corrosion damage at the substrate level. Early detection and negation of such activity can provide extensive cost savings. Several Electrochemical techniques and Non Destructive Evaluation (NDE) show promise in detecting the onset of corrosion under such coatings. Current accelerated testing of aircraft coating systems for corrosion protection relies heavily on salt spray methods. Electrochemical techniques such as Electrochemical Impedance Spectroscopy (EIS) and Electrochemical Noise Methods (ENM) provide insight into the global properties of a coating system, and both techniques are being used on a limited basis. However, there is a need to investigate corrosion events with greater spatial resolution under coatings at the metal/coating interface. Such corrosion activity may be related to coating defects and variations in the surface chemistry of the underlying metal. The Scanning Vibrating Electrode Technique (SVET) has been developed to allow the investigation of localized corrosion activity with high spatial resolution. Such activity may be associated with coating defects or galvanic coupled regions of the metal surface. Electrochemical and NDE techniques were used to investigate the early stage of corrosion activity under protective coatings. Coatings in this investigation ranged from a simple epoxy amine to commercially used military aircraft polyurethane coatings. SVET testing of panels with intact high-resistance barrier coatings could not reveal corrosion damage under normal testing conditions because of little or no corrosion activity within the limited exposure time. Chemical, mechanical, and electrochemical means of accelerating the corrosion damage were utilized to obtain results in a reasonable time frame. Corrosion initiation and its progress under the coating were studied in detail and the results are discussed here. Complimentary high-resolution NDE techniques, such as Scanning Acoustic Microscopy (SAM) and Fan Thermography measurements were used to identify the corrosion sites. The overall objective of this investigation is to establish a correlation between the electrochemical and NDE techniques.


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