Effect of Electromechanical Coupling on the Young’s Modulus of Zinc Oxide Nanowires

Author(s):  
A. V. Desai ◽  
M. A. Haque

The Young’s modulus of zinc oxide nanowires was measured to be significantly lower than bulk zinc oxide, which cannot be explained within the framework of existing theories. We propose that the strong electromechanical coupling in piezoelectric materials, such as zinc oxide, influences the measured mechanical properties. The asymmetric wurtzite crystal structure and the ionic nature of the molecular bonding result in internal electric fields during straining of the zinc oxide nanowire, which in turn lead to reduction in the measured modulus. In case of flexural deformation, additional electromechanical coupling is present due to the flexoelectric effect.

2008 ◽  
Vol 2008 ◽  
pp. 1-7 ◽  
Author(s):  
M. P. Manoharan ◽  
A. V. Desai ◽  
G. Neely ◽  
M. A. Haque

Zinc oxide nanowires, nanobelts, and nanoneedles were synthesized using the vapor-liquid-solid technique. Young's modulus of the nanowires was measured by performing cantilever bending experiments on individual nanowires in situ inside a scanning electron microscope. The nanowires tested had diameters in the range of 200–750 nm. The average Young's modulus, measured to be 40 GPa, is about 30% of that reported at the bulk scale. The experimental results are discussed in light of the pronounced electromechanical coupling due to the piezoelectric nature of the material.


Author(s):  
A. V. Desai ◽  
M. A. Haque

As the size of material decreases to nanoscale, fundamental material properties such as Young’s modulus are different from bulk values. In this paper, we propose a new mechanism to explain the difference in experimentally observed Young’s modulus values between zinc oxide nanowires and bulk zinc oxide. As a binary compound material (such as zinc oxide) is strained, the effective charge on the ionic constituents of the material changes (in this case zinc and oxygen). The strain induced charge redistribution effect is more significant in nanostructures (such as nanowires) because of their higher fracture strains compared to their bulk counterparts. Since the Young’s modulus of a material is related to the effective charge, we observe differences in modulus values between nanowires and their bulk equivalent. The strain induced charge redistribution phenomenon can also be used to explain variation in modulus values between bulk and nanoscale for other single crystal piezoelectric materials such as silicon carbide.


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Author(s):  
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Qingfeng Liu ◽  
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Dan Ewing ◽  
...  

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