Status of Silicon Nitride Component Fabrication Processes, Material Properties, and Applications

Author(s):  
John P. Pollinger

Silicon nitride monolithic structural ceramic components have recently been introduced as production parts in commercial aircraft turbomachinery pump and seal applications to take advantage of their unique thermomechanical properties. Additionally, extensive efforts are in progress to develop, evaluate, and productionize silicon nitride components for commercial aircraft turbomachinery hot sections, industrial power generation turbines, and automotive hybrid vehicle turbogenerators. AlliedSignal Ceramic Components has developed a family of in-situ reinforced silicon nitride materials for these applications and is developing and implementing a suite of component fabrication processes to achieve production-viable manufacturing of complex shaped components, including turbine seals, blades, nozzles, wheels, and combustors. A key focus of the manufacturing process development is the need to achieve low cost fabrication of components in order to meet cost targets required for commercial introduction. Finally, the status and plans for a number of aerospace, industrial, and automotive turbomachinery applications are discussed, including commercial aircraft turbomachinery production components (pump and seal parts) and development components (auxiliary power unit turbine blades and nozzles, and propulsion engine wheels and starter wheels), nozzle, blade, wheel and combustor components for automotive hybrid vehicle turbogenerators, and turbine blades and nozzles for industrial power generation gas turbines.

Author(s):  
Danielle D. Newson ◽  
John P. Pollinger ◽  
Douglas J. Twait

Extensive progress has been made in the development of high performance silicon nitride structural ceramics and component fabrication. This has in turn led to a number of successful applications in small turbines, including commercial aircraft production components and a number of successful tests and continuing field tests in aircraft auxiliary power units, air turbine starters, and stationary power generation engines. The current status, capabilities, limitations, and material refinement efforts for silicon nitride at AlliedSignal Ceramic Components (ASCC) will be presented, including environmental durability and environmental barrier coating investigations. Two key issues in the implementation of silicon nitride turbine components have been the ability to fabricate engine quality hardware, and fabrication at low-enough costs to allow commercialization. The current status of production forming processes will be presented and the development of new low cost forming and advanced technologies including gelcasting and solid freeform fabrication will be discussed, both in regards to component fabrication capability and production cost potential. Finally, the status of a number of commercial and development applications such as propulsion turbine engine seals, APU hot section wheels, blades, and nozzles, industrial turbine nozzles, and power generation microturbine components will be discussed.


Author(s):  
B. J. Busovne ◽  
J. P. Pollinger

The development and fabrication of reliable high temperature-high strength silicon nitride components by Garrett Ceramic Components Division for the Advanced Turbine Technology Applications Project (ATTAP) is discussed. Garrett Ceramic Components’ advanced turbine component process development philosophy and practices will be presented, including implementation of statistically designed experiments, in-process controls, extensive NDE, and mechanical properties characterization. The current status of material, process, and part properties of specific components being developed by Garrett Ceramic Components are compared with the properties required for their implementation and the successful operation of advanced gas turbines with ceramic components at 1370°C.


Author(s):  
Keisuke Makino ◽  
Ken-Ichi Mizuno ◽  
Toru Shimamori

NGK Spark Plug Co., Ltd. has been developing various silicon nitride materials, and the technology for fabricating components for ceramic gas turbines (CGT) using theses materials. We are supplying silicon nitride material components for the project to develop 300 kW class CGT for co-generation in Japan. EC-152 was developed for components that require high strength at high temperature, such as turbine blades and turbine nozzles. In order to adapt the increasing of the turbine inlet temperature (TIT) up to 1,350 °C in accordance with the project goals, we developed two silicon nitride materials with further unproved properties: ST-1 and ST-2. ST-1 has a higher strength than EC-152 and is suitable for first stage turbine blades and power turbine blades. ST-2 has higher oxidation resistance than EC-152 and is suitable for power turbine nozzles. In this paper, we report on the properties of these materials, and present the results of evaluations of these materials when they are actually used for CGT components such as first stage turbine blades and power turbine nozzles.


Author(s):  
Yasushi Hara ◽  
Katsura Matsubara ◽  
Ken-ichi Mizuno ◽  
Toru Shimamori ◽  
Hiro Yoshida

NGK Spark Plug Co., Ltd. has been developing various silicon nitride materials, and the technology for fabricating components for ceramic gas turbines (CGT) using theses materials. We are supplying silicon nitride material components for the project to develop 300 kW class CGT for co-generation in Japan. EC-152 was developed for components that require high strength at high temperature, such as turbine blades and turbine nozzles. In order to adapt the increasing of the turbine inlet temperature (TIT) up to 1350 °C in accordance with the project goals, we developed two silicon nitride materials with further improved properties: ST-1 and ST-2. ST-1 has a higher strength than EC-152 and is suitable for first stage turbine blades and power turbine blades. ST-2 has higher oxidation resistance than EC-152 and is suitable for power turbine nozzles. On applying these silicon nitride ceramics to CGT engine, we evaluated various properties of silicon nitride materials considering the environment in CGT engine. Particle impact testing is one of those evaluations. Materials used in CGT engine are exposed in high speed gas flow, and impact damage of these materials is considered to be a concern. We tested ST-1 in the particle impact test. In this test, we observed fracture modes, and estimated the critical impact velocity. This paper summarizes the development of silicon nitride components, and the result of evaluations of these silicon nitride materials.


2005 ◽  
Vol 287 ◽  
pp. 367-380 ◽  
Author(s):  
Mattison K. Ferber ◽  
Hua Tay Lin

Over the last 30 years, a number of programs in Russia, Europe, Japan, and the United States have sought to introduce monolithic ceramic components into gas turbines with the goals of increasing efficiency and lowering emissions. High performance silicon nitride and silicon carbide ceramics typically have been leading candidates for use in these applications. Recent field tests involving silicon nitride vanes and blades have shown that these materials can experience significant recession due to the loss of the normally protective silica scale. This paper first summarizes key findings from these field tests and then describes a relatively simple method for evaluating environmental effects in a laboratory environment.


Author(s):  
Steven J. Bossart

The Morgantown Energy Technology Center (METC) of the U.S. Department of Energy (DOE) is actively sponsoring research to develop coal-based power generation systems that use coal more efficiently and economically and with lower emissions than conventional pulverized-coal power plants. Some of the more promising of the advanced coal-based power generation systems are shown in Figure 1: pressurized fluidized-bed combustion combined-cycle (PFBC), integrated gasification combined-cycle (IGCC), and direct coal-fueled turbine (DCFT). These systems rely on gas turbines to produce all or a portion of the electrical power generation. An essential feature of each of these systems is the control of particles at high-temperature and high-pressure (HTHP) conditions. Particle control is needed in all advanced power generation systems to meet environmental regulations and to protect the gas turbine and other major system components. Particles can play a significant role in damaging the gas turbine by erosion, deposition, and corrosion. Erosion is caused by the high-speed impaction of particles on the turbine blades. Particle deposition on the turbine blades can impede gas flow and block cooling air. Particle deposition also contributes to corrosive attack when alkali metal compounds adsorbed on the particles react with the gas turbine blades. Incorporation of HTHP particle control technologies into the advanced power generation systems can reduce gas turbine maintenance requirements, increase plant efficiency, reduce plant capital cost, lower the cost of electricity, reduce wastewater treatment requirements, and eliminate the need for post-turbine particle control to meet New Source Performance Standards (NSPS) for particle emissions.


Author(s):  
Oscar Jimenez ◽  
Hamid Bagheri ◽  
John McClain ◽  
Ken Ridler ◽  
Tibor Bornemisza

The Ceramic Stationary Gas Turbine (CSGT) Development Program was performed under the sponsorship of the United States Department of Energy (DOE), Office of Industrial Technologies (OIT). The goal was to improve the performance (fuel efficiency, output power, and exhaust emissions) of stationary gas turbines in cogeneration through the selective replacement of hot section metallic components with ceramic components. The team was headed by Solar Turbines Incorporated and supported by ceramic component suppliers and national research institutes. The team performed a detailed engine and component design, fabrication, and field-testing of ceramic components. This program culminated in an engine test at 1121°C (2050°F) TRIT. This was a major challenge in that the engine ran with a continuous fiber reinforced ceramic composite liner (CFCC) and with silicon nitride (Si3N4) stage one ceramic blades and nozzles. The design and testing of all three components will be discussed in this paper, with emphasis on the ceramic nozzles. Another test that will be discussed in this paper is a heavily instrumented engine test that took place prior to the test mentioned above. This instrumented engine test was performed in order to better understand the temperature effects between the ceramic and metallic component interfaces. The results from this were then used to correlate the analytical model with test data. This led to additional design changes to the outer and inner shroud ceramic / metallic interfaces, as well as ceramic nozzles, fabricated from Kyocera SN 282 silicon nitride material. These nozzle changes were then engine tested successfully for a total of 100 hours at full load [1010°C (1850°F) TRIT and 100% speed]. During the engine test, the firing temperature was increased to 1121°C (2050°F) TRIT for an adequate duration to ensure meaningful performance data were gathered.


Author(s):  
K. Hagemeister ◽  
E. Tiefenbacher ◽  
P. Walzer

In 1974 in Germany a research program was initiated under sponsorship of the Ministry of Research and Technology for developing ceramic components for vehicular gas turbines. Participants were Daimler-Benz, Motoren- and Turbinen-Union and Volkswagen and a number of ceramic companies and research institutes. The paper gives the achieved development-status of the following components: combustion-chamber, nozzles and two types of rotors. Furtheron some results of investigations in regard of durability of silicon nitride and silicon carbide are presented.


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