Radical Overshoot Phenomena in Liquid Fueled Gas Turbine Combustors
A detailed analysis is presented of the processes involved in the production of NO during the combustion of liquid fuels in gas turbines. With O and OH concentrations in excess of the equilibrium values the NO production rate displays a temporary overshoot within the primary combustion zone residence time. The contributions of temperature and reaction kinetics to this overshoot are assessed. This overshoot is strongly dependent on equivalence ratio and on pressure, with the minimum overshoot occurring at ϕ = 0.9. It increases more strongly for richer than for leaner combustion. Increasing drop size at lean or stoichiometric conditions tends to retard and diminish the overshoot of the NO formation rate while increasing its duration. At rich conditions, however, increasing drop size can cause overshoot increases. Changing degrees of premixedness for a given drop size, produces a timewise shifting of this overshoot. An assessment is made of the influences and interrelation of drop size distribution, degree of premixedness and staged fuel addition.